• Title/Summary/Keyword: W-Ni

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Piezoelectric Characteristics of Low-temperature Sintered PSN-PZT Ceramics as a Function of Zr/Ti Ratio (저온소결한 PSN-PZT 세라믹스의 Zr/Ti 비에 따른 압전특성)

  • 류주현;우원희;오동언;정영호;정광현;류성림
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12S
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    • pp.1195-1199
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    • 2003
  • In this study, in order to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, dielectric and piezoelectric properties of PSN-PZT[0.91Pb(Sb$\sub$1/2/Nb$\sub$1/2/)$\sub$0.03/(Zr$\sub$0.495/Ti$\sub$0.505/)$\sub$0.97/O$_3$-0.04Pb(Ni$\sub$1/2/W$\sub$1/2/)O$_3$+0.05BiFeO$_3$+0.3wt%MnO$_2$+0.6wt%CuO〕 ceramics were investigated according to Zr/Ti ratio. As Zr/Ti ratio is increased, electromechanical coupling factor(k$\sub$p/) and dielectric constant increased and then decreased after the ratio of Zr/Ti=50/50. Also, mechanical qualify factor(Q$\sub$m/) decreased and then increased after the ratio of Zr/Ti=50/50.

Analysis of Over-current Characteristics in YBCO Coated Conductor (YBCO Coated Conductor의 과전류 특성해석)

  • Lee, C.;Nam, K.;Kang, H.;Ko, T.K.;Seok, B.Y.
    • Proceedings of the KIEE Conference
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    • 2006.07b
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    • pp.693-694
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    • 2006
  • In order to develop a high temperature superconducting(HTS) coil for the fault current limiter(FCL), the over-current characteristics in YBCO coated conductor(CC) with Ni-W alloy substrate are analyzed. The HTS wire is wound by bifilar winding method for resistive current limitation and it is operated in 65K sub-cooled nitrogen. In order to analyze the resistance and the temperature characteristics of the CC wire, an analysis program is developed considering all the composition materials except the buffer layer. Using this program, the temperature rise, the resistance development and the current limitation of CC are calculated depending on the applied voltage and the stabilizer materials. According to the analysis results, under the temperature restriction of 300K, the maximum voltage per meter is determined as 40V/m if the stabilizer is $25{\mu}m$ thick stainless steel at each side. Finally, the wire length needed for the distribution level HTS FCL is estimated.

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Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle using CeO2/ZrO2 Foam Device (CeO2/ZrO2 Foam Device를 이용한 고온 태양열 열화학 싸이클의 수소 생산)

  • Lee, Jin-Gyu;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
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    • v.34 no.6
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    • pp.11-18
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    • 2014
  • Two-step water splitting thermochemical cycle with $CeO_2$ foam device was investigated by using a solar simulator composed of 2.5 kW Xe-Arc lamp and mirror reflector. The hydrogen production of $CeO_2$ foam device depending on reaction temperature of Thermal-Reduction step and Water-Decomposition step was analyzed, and the hydrogen production of $CeO_2$ and $NiFe_2O_4/ZrO_2$ foam devices was compared. As a result, the amount of reduced $CeO_2$ considerably varies according to the reaction temperature of Thermal-Reduction step. and hydrogen production was not much when the amount of reduced $CeO_2$ decreased even if the reaction temperature of Water-Decomposition step was high. Therefore, it is very important to keep the reaction temperature of Thermal-Reduction step high in two-step thermochemical cycle with $CeO_2$.

Mode Propagation in X-Ray Waveguides

  • Choi, J.;Jung, J.;Kwon, T.
    • Journal of the Optical Society of Korea
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    • v.12 no.2
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    • pp.112-117
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    • 2008
  • Single-mode propagation conditions of X-ray waveguides are investigated by numerical calculations in order to understand the importance of waveguide design parameters, such as core thickness and the optical constants of waveguide materials, on the transmission and coherence properties of the waveguide. The simulation code for mode analyzing is developed based on a numerical solution of the parabolic wave equation. The initial boundary value problem is solved numerically using a finite-difference scheme based on the Crank-Nicolson scheme. The E-field intensities in a core layer are calculated at an X-ray energy of 8.0 keV for air and beryllium(Be) core waveguides with different cladding layers such as Pt, Au, W, Ni and Si to determine the dependence on waveguide materials. The highest E-field intensity radiated at the exit of the waveguide is obtained from the Pt cladded beryllium core with a thickness of 20 nm. However, the intensity from the air core waveguide with Pt cladding reaches 64% of the Be-Pt waveguide. The dependence on the core thickness, which is the major parameter used to generate a single mode in the waveguide, is investigated for the air-Pt, and Be-Pt waveguides at an X-ray energy of 8.0 keV. The mode profiles at the exit are shown for the single mode at a thickness of up to 20 nm for the air-Pt and the Be-Pt waveguides.

Electrochemical Performances of Lithium-air Cell with Carbon Materials

  • Park, C.K.;Park, S.B.;Lee, S.Y.;Lee, H.;Jang, H.;Cho, W.I.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3221-3224
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    • 2010
  • This study investigates the requirements of lithium-air cathodes, which directly influence discharge capacity. The cathodes of Li-air cell are made by using five different carbon materials, such as Ketjen black EC600JD, Super P, Ketjen black EC300JD, Denka black, and Ensaco 250G. The Ketjen black EC600JD provides discharge capacity of 2600 mAh/g per carbon weight, while that of Ensaco 250G shows only 579 mAh/g. To figure out the differences of discharge capacity from carbon materials, their surface area and pore volume are analyzed. These are found out to be the critical factors in determining discharge capacity. Furthermore, carbon loading on Ni foam and amounts of electrolyte are significant factors that affect discharge capacity. In order to investigate catalyst effect, electrolytic manganese dioxide (EMD) is incorporated and delivered 4307 mAh/g per carbon weight. This infers that EMD facilitates to break $O_2$ interactions and leads to enhance discharge capacity.

Syngas and Hydrogen Production from $CeO_2/ZrO_2$ coated foam device under concentrated solar radiation (고온 태양열을 이용한 합성가스 및 수소 생산에서 $CeO_2/ZrO_2$가 코팅된 다공성 폼의 영향)

  • Jang, Jong-Tak;Yoon, Ki-June;Han, Gui-Young
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.307-313
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    • 2011
  • 금속산화물을 이용한 2단계 산화/환원 반응은 GTL, CTL 의 반응원료인 합성가스 및 수소 생산기술이다. 이 기술은 메탄을 환원제로 사용함으로써 비교적 저온에서 산화/환원 반응을 할 수 있는 장점이 있다. 하지만 반복 사이클의 시연에서 금속산화물의 소결현상으로 인한 활성저하가 이 기술의 문제점 중의 하나이다. 본 연구에서는 2.5 kW Xenon arc lamp 가 설치된 solar simulator를 사용 하였으며, 무기물 다공성 폼 (SiC foam)및 유기물 다공성 폼 (Ni, Cufoam)에 $CeO_2/ZrO_2$ 를 코팅하여 연속적인 합성가스 및 수소 생산 가능성을 알아보았다. 반응 전 후의 $CeO_2/ZrO_2$ 의 결정 구조를 SEM 과 XRD 를 통해 분석하였다.

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TWO-STEP THERMOCHEMICAL CYCLES FOR HYDROGEN PRODUCTION WITH DISH TYPE SOLAR THERMAL SYSTEM (접시형 태양열 집광 시스템을 이용한 열화학 사이클의 수소생산)

  • Kwon, Hae-Sung;Oh, Sang-June;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.169-176
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    • 2011
  • The two-step water splitting thermochemical cycle is composed of the T-R (Thermal Reduction)and W-D (Water Decomposition)steps. The mechanism of this cycle is oxidation-reduction, which produces hydrogen. The reaction temperature necessary for this thermochemical cycle can be achieved by a dish-type solar thermal collector (Inha University, Korea). The purpose of this study is to validate a water splitting device in the field. The device is studied and fabricated by Kodama et al (2010, 2011). The validation results show that the foam device, when loaded with $NiFe_2O_4/m-ZrO_2$powder, was successfully achieved hydrogen production with 9 (10 with a Xe-light solar simulator, 2009, Kodama et al.) repeated cycles under field conditions. Two foam device used in this study were tested for validation before an experiment was performed. The lab scale ferrite-conversion rate was in the range of 24~76%. Two foam devices were designed to for structural stability in this study. In the results of the experiments, the hydrogen percentage of the weight of each foam device was 7.194 and $9.954{\mu}mol\;g^{-1}$ onaverage, and the conversion rates 4.49~29.97 and 2.55~58.83%, respectively.

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Fabrication of a Micro Die by LIGA Process and Hybrid Powder Extrusion Process of Micro-spur Gear (LIGA 공정을 이용한 초소형 스퍼기어 금형 제작 및 하이브리드 분말 압출성형)

  • Lee, K.H.;Hwang, D.W.;Kim, J.H.;Jang, S.S.;Kim, B.M.
    • Transactions of Materials Processing
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    • v.19 no.6
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    • pp.352-356
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    • 2010
  • This paper was designed to fabricate the micro-spur gear by the LIGA and hybrid powder extrusion process. It is important to manufacture a micro-die with a high aspect ratio and determine appropriate extrusion conditions for a microforming. Ni has been used to fabricate micro-dies. LIGA process was capable to produce micro-extrusion dies with close tolerance, longer bearing length and adequate surface quality. Superplastic Al-78Zn powders have the great advantage in achieving deformation under low stresses and exhibiting good micro-formability with average strain rate raging from $10^{-3}$ to $10^{-2} s^{-1}$ and constant temperature ranging from 503 to 563K. Al-78Zn powders were compacted into a cylindrical shape ($\Phi3\times$h10mm) under compressive force of 10kN and, subsequently, the compacted powders were extruded by the hybrid powder extrusion process controlling of the temperature holing time for a improvement on formability of Al-22Zn powder. Micro-extrusion has succeeded in forming micro-gear shafts.

Fabrication and Performance Analysis of Environment Friendly Double Core Bullets for Small Arms (2중 코어 구조의 소화기용 친환경 탄자 제조 및 특성 분석)

  • Hong, Jun-Hee;Jang, Tak-Soon;Song, Chang-Bin;Kang, Dae-Wha
    • Journal of the Korea Institute of Military Science and Technology
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    • v.14 no.3
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    • pp.345-352
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    • 2011
  • This paper focuses on the properties analysis of 9mm bullet dual structure core to substitute current lead core by environment-friendly combination of W-Cu-Ni system high density composite materials. So the four combination samples were made of dual core with the different center of gravity location backward or forward compare to that of lead type bullet, and we experimented about the performance of 9mm bullet dual structure core. In the experimental results, the outer shape of core of four environment friendly samples on the target maintain marginally, while the current lead core bullets are completely crushed after hitting the target. The penetration depth of environment friendly samples excel seven times to lead type bullet and the three out of four samples with forward adjusted center of gravity penetrate deep as twice as ones backward. The impact tolerance of all four samples satisfies military specification, however, more firing tests are required to improve reliability of scattering distribution.

An accurate substructural synthesis approach to random responses

  • Ying, Z.G.;Zhu, W.Q.;Ye, S.Q.;Ni, Y.Q.
    • Structural Engineering and Mechanics
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    • v.39 no.1
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    • pp.47-75
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    • 2011
  • An accurate substructural synthesis method including random responses synthesis, frequency-response functions synthesis and mid-order modes synthesis is developed based on rigorous substructure description, dynamic condensation and coupling. An entire structure can firstly be divided into several substructures according to different functions, geometric and dynamic characteristics. Substructural displacements are expressed exactly by retained mid-order fixed-interfacial normal modes and residual constraint modes. Substructural interfacial degree-of-freedoms are eliminated by interfacial displacements compatibility and forces equilibrium between adjacent substructures. Then substructural mode vibration equations are coupled to form an exact-condensed synthesized structure equation, from which structural mid-order modes are calculated accurately. Furthermore, substructural frequency-response function equations are coupled to yield an exact-condensed synthesized structure vibration equation in frequency domain, from which the generalized structural frequency-response functions are obtained. Substructural frequency-response functions are calculated separately by using the generalized frequency-response functions, which can be assembled into an entire-structural frequency-response function matrix. Substructural power spectral density functions are expressed by the exact-synthesized substructural frequency-response functions, and substructural random responses such as correlation functions and mean-square responses can be calculated separately. The accuracy and capacity of the proposed substructure synthesis method is verified by numerical examples.