• Journal of the Korean Chemical Society
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• v.36 no.5
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• pp.697-708
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• 1992

Liquid Chromatographic behavior of Ni(II) in Isonitrosoethylacetoacetate Imine(IEAA-NR), Ni(IEAA-NH)(IEAA-NR)(R = H, CH_3, C-2H_5, n-C_4H_9, C_6H_5-CH_2) chelates were investigated by reversed-phase HPLC on Micropak MCH-5 column using methanol/water as mobile phase. The optimum conditions for the separation of Ni(IEAA-NH)(IEAA-NR) chelates were examined with respect to the effect of the flow rate, sample solvent, mobile phase strength and column temperature. It was fo$und that metal chelates were properly eluted in an acceptable range of capacity factor value(0{\le}logk'{\le}1). The dependence of the logarithm of capacity factor (k') on the volume fraction of water in the binary mobile phase as well as on the liquid-liquid extraction distribution ratio (Dc) in methanol-water/n-alkane extraction system showed the good linearties, and the dependence of the logarithm of capacity factor (k') on the column temperature and on the enthalpy exhibited the good linearties, and the compensation temperature ({\beta}) from the slope was 773.47{\circ}K. It was suggested that the retention of metal chelates was largely affected by the hydrophobic effect.

• Journal of Korean Society for Geospatial Information Science
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• v.5 no.2 s.10
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• pp.131-144
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• 1997

Traffic jam densified day by day is phenomenon to occur lack of the road capacity in comparison with traffic density, but lack of the road cannot be concluded by main cause of traffic ism. Because the central function of a city would be concentrated upon the downtown and traffic demand would not be evenly distributed by the classification of an hour. Therefore, this study based on the fact that each driver will select the route generating traffic delay very low when path choice from origin to destination in travel plan estimating the quality of passage could be maintained the speed he want will approach to a characteristic grasp of a road, traffic, driver changing every moment by traffic-demand of road increased as a geometrical series with analysis a classification of a street, a intersection along the path on traffic density and highway capacity analysis the path using GIS techniques about complex street network, also will get the path of actual optimum for traffic delay trend creating under various condition the classification per a hour, a day of week and an incident through network such as analysis for traffic generation zone adjacent about street, intersection, afterward will expect the result increasing efficiency of the road-use through a good distribution of traffic by optimum-path choice, accordingly will prepare the scientific, objective, appropriate basis to decide the reasonable time of a road-widen and expansion through section analysis along a rate of traffic volume vs. road capacity.

• Clean Technology
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• v.29 no.4
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• pp.272-278
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• 2023

There is a lot of interest in methods for pollutants using adsorption, and recent research is being conducted to show that biochar can be used to remove organic and inorganic pollutants. In particular, wood waste as waste biomass requires a biomass recycling method, and a method to increase the adsorption capacity of biochar produced using wood waste is needed. Biochar is created by Hydrothermal carbonization (HTC) using, which uses low temperature and high pressure, has low energy consumption and does not require moisture removal pretreatment, and biochar is created through chemical activation using KOH, NaOH, and ZnCl₂ chemicals. The adsorption characteristics of biochar were determined by analyzing iodine adsorptivity, specific surface area, pore diameter, pore volume, pore distribution, and SEM according to the activation. The results of analyzing the selecting biochar by activating the biochar produced at HTC 300℃, 4 hr by KOH, NaOH, and ZnCl₂ chemicals, the specific surface area was 774~1.387 m²/g, showing a high specific surface area similar to activated carbon, and it was confirmed that micropores with an average pore diameter in the range of 21~24 Å were formed. As a result of SEM observation, the surface was uniform with a certain shape depending on activation. It was confirmed that one pore was developed and the number of pores increased.

• Journal of the Korean Geographical Society
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• v.49 no.5
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• pp.761-778
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• 2014

There has been relatively little study to model price for commercial property because of its low transaction volume in the market. Despite of this thin market character, this paper tried to estimate prices for commercial lots as accurate as possible. We constructed a model whose components consist of mean structure(global trend), exponential covariance function and a pure error term, and applied it to actual sales price data of Seoul. We explicitly took account of spatial autocorrelation of land price by utilizing a kriging technique, a representative method of spatial interpolation, because the land price of commercial lots has feature of differential price forming pattern depending on submarkets they belong to. In addition, we chose to apply a bayesian kriging to overcome data scarcity by incorporating experts' knowledge into prior probability distribution. The chosen model's excellent performance was verified by the result from validation data. We confirmed that the excellence of the model is attributed to incorporating both autocorexperts' knowledge and spatial autocorrelation in the model construction. This paper is differentiated from previous studies in the sense that it applied the bayesian kriging technique to estimate price for commercial lots and explicitly combined experts' knowledge with data. It is expected that the result of this paper would provide a useful guide for the circumstances under which property price has to be estimated reliably based on sparse transaction data.

• Journal of Embryo Transfer
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• v.24 no.3
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• pp.189-197
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• 2009

Two-pore domain $K^+(K_{2P})$ channels contribute to setting the resting membrane potential in excitable and nonexcitable cells. However, the cellular or tissue distribution and function of $K_{2P}$ channels expressed in mammalian germ cells and reproductive organs have not yet been reviewed by researchers. In this review, we focus on expression, localization and expected properties of $K_{2P}$ channels in germ cells and reproductive organs. The $K_{2P}$ channels are expressed in human cytotrophoblast cells, myometrium, placental vascular system, uterine smooth muscle, and pregnant term tissue, suggesting that $K_{2P}$ channels might be involved in the processes of pregnance. The $K_{2P}$ channels are also expressed in mouse zygotes, monkey sperm, ovary, testis, germ cells, and embryos of Korean cattle. Interestingly, $K_{2P}$ channels are modulated by changes in temperature and oxygen concentration which play an important role in embryonic development. Also, $K_{2P}$ channels are responsible for $K^+$ efflux during apoptotic volume decreases in mouse zygotes. These expression patterns and properties of the $K_{2P}$ channels in reproductive organs and germ cells are likely to help the understanding of ion channel-related function in reproductive physiology.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.8 no.1
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• pp.127-140
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• 1988

The management of sewage and rainfall runoff becomes an emerging problem with the growth of urban communities. From the uncontrollable excess intensity or amount of rainfall, the conditions of sewer surcharge or manhole overflow could be generated in the combined sewer network where municipal or industrial wastewaters and rainfall runoff flow. The predictive model far the prevention of property and human life losses from this inundation was studied in this research. In the development of a mathematical flow model for the combined sewer surcharge and overflow, the Preissmann Slot concept and the four-point implicit method of finite difference were utilized. For the usage in personal computer, the overlapping segment method that required less memory storage was adopted. Through the simulation of hypothetical sewer network, the conservation of discharge volume was checked, and the usefulness of the Preissmann Slot was assured from the temporal distribution of discharge and depth along the sewer network. Also the possible field application for the correction of sewer diameters and slopes in the design of sewer network which has no surcharge/overflow condition was suggested.

• Journal of Digital Contents Society
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• v.11 no.3
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• pp.315-322
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• 2010

This study focused on mobile trend in diffusion of smart phone. Presently, it has been evolved from digital nomad to smart nomad. Smart nomad era is based on digital technology with mobility and being smart. Smart nomad that is made up high-end device and intellectual content has changed structure of industry and life style. Smart phone is a core key in smart nomad era. In 2010 smart phone has been distributed about 2.5 hundreds million which is 20% of whole mobile phone sales and the volume of smart phone sales will be getting bigger and bigger in near future. Although, there are various reasons for success of smart phone market, this research focused 4 reasons: first, development of mobile device, second, evolution of mobile content distribution, third, support of government system, fourth, success of Docomo i-mode and Apple i phone. Smart phone will grow up more rapidly. Smart phone eco-system will be more competitive in the world. In Korea, smart phone eco-system also will be very competitive. For success in the middle of this competitive environment, Korea should lead the competitive phase with development of ability of creation software and content, construction of various partnership and evolution of next generation technology and service.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.9
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• pp.3176-3183
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• 2010

A multi-scale fatigue life prediction methodology of composite pressure vessels subjected to multi-axial loading has been proposed in this paper. The multi-scale approach starts from the constituents, fiber, matrix and interface, leading to predict behavior of ply, laminates and eventually the composite structures. The multi-scale fatigue life prediction methodology is composed of two steps: macro stress analysis and micro mechanics of failure based on fatigue analysis. In the macro stress analysis, multi-axial fatigue loading acting at laminate is determined from finite element analysis of composite pressure vessel, and ply stresses are computed using a classical laminate theory. The micro stresses are calculated in each constituent from ply stresses using a micromechanical model. Three methods are employed in predicting fatigue life of each constituent, i.e. a maximum stress method for fiber, an equivalent stress method for multi-axially loaded matrix, and a critical plane method for the interface. A modified Goodman diagram is used to take into account the generic mean stresses. Damages from each loading cycle are accumulated using Miner's rule. Monte Carlo simulation has been performed to predict the overall fatigue life of a composite pressure vessel considering statistical distribution of material properties of each constituent, fiber volume fraction and manufacturing winding angle.

• Environmental Analysis Health and Toxicology
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• v.15 no.4
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• pp.123-130
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• 2000

2-Bromopropane, important industrial chemical, specially in electronic industry at Yangsan in Korea has been reported to cause amenorrhea for female and azoospermia, oligozoospermia or reduced sperm motility for male. 2-BP was investigated through 21 days of repeated dose in male Sprague-Dawley rats. The dose levels per body weight were 0 (control), 250,500 and 1,000 mg/kg. 2-BP dissolved in vehicle olive oil was injected into the intraperitoneum 6 times per week for 3 weeks, but 1,000 mg/kg dose group was 2 weeks because of serious illness. Male rats showed significant decreases in body weight and right and left testis showed typical weight losses depending on the 2-BP. The number of white blood cell and red blood cell , percentage of monocytes, and hemoglobin decreased significantly in high dose (P< 0.05). Red cell volume distribution width increased significantly in the high dose (P< 0.05). Histopathological findings of testes showed a decrease of spermatogenic cells, exfoliation of spermatid and spermatocyte, vacuolization of Sertoli cells and hyperplasia of Leydig cells. Protein band density between 113,000 dalton ($\beta$-galactosidase) and 53,900 dalton (ovalbumin) has decreased in 250 mg/kg dose group, but it has gradually increased to the higher density in 1,000 mg/kg dose group than in control group.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.3
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• pp.144-149
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• 2016

The metal-impregnated activated carbon was produced from bamboo activated carbon by soaking method of metal nitrate solution. The carbonization and activation of raw material was conducted at $900^{\circ}C$. The specific surface area and pore size distribution of the prepared activated carbons were measured. Also, NO and activated carbon reaction were conducted in a thermogravimetric analyzer in order to use as de-NOx agents of used activated carbon. Carbon-NO reactions were carried out with respect to reaction temperature ($20^{\circ}C{\sim}850^{\circ}C$) and NO gas partial pressure (0.1 kPa~1.8 kPa). As results, the specific volume and surface area of bamboo activated carbon impregnated with copper were decreased with increasing Cu amounts of activated carbon. In NO reaction, the reaction rate of Cu impregnated bamboo activated carbon[BA(Cu)] was promoted to compare with that of bamboo activated carbon[BA]. But the reaction rate of Ag impregnated bamboo activated carbon[BA(Ag)] was retarded. Measured reaction orders of NO concentration and activation energy were 0.63[BA], 0.92[BA(Cu)], and 80.5 kJ/mol[BA], 48.5 kJ/mol[BA(Cu)], 66.4 kJ/mol[BA(Ag)], respectively.