• Title/Summary/Keyword: Volume Efficiency

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Development of Biomass-Derived Anode Material for Lithium-Ion Battery (리튬이온 전지용 바이오매스 기반 음극재 개발)

  • Jeong, Jae Yoon;Lee, Dong Jun;Heo, Jungwon;Lim, Du-Hyun;Seo, Yang-Gon;Ahn, Jou-Hyeon;Choi, Chang-Ho
    • Clean Technology
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    • v.26 no.2
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    • pp.131-136
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    • 2020
  • Biomass bamboo charcoal is utilized as anode for lithium-ion battery in an effort to find an alternative to conventional resources such as cokes and petroleum pitches. The amorphous phase of the bamboo charcoal is partially converted to graphite through a low temperature graphitization process with iron oxide nanoparticle catalyst impregnated into the bamboo charcoal. An optimum catalysis amount for the graphitization is determined based on the characterization results of TEM, Raman spectroscopy, and XRD. It is found that the graphitization occurs surrounding the surface of the catalysis, and large pores are formed after the removal of the catalysis. The formation of the large pores increases the pore volume and, as a result, reduces the surface area of the graphitized bamboo charcoal. The partial graphitization of the pristine bamboo charcoal improves the discharge capacity and coulombic efficiency compared to the pristine counterpart. However, the discharge capacity of the graphitized charcoal at elevated current density is decreased due to the reduced surface area. These results indicate that the size of the catalysis formed in in-situ graphitization is a critical parameter to determine the battery performance and thus should be tuned as small as one of the pristine charcoal to retain the surface area and eventually improve the discharge capacity at high current density.

Establishment of Foliar Application Assays for Developing Natural Herbicides (천연물 제초제 개발을 위한 전식물체 수준의 경엽처리 검정법 확립)

  • Kim, Jae-Deog;Jang, Hyun-Woo;Seo, Bo-Ram;Hwang, Hyun-Jin;Choi, Jung-Sup;Kim, Jin-Seog
    • Korean Journal of Weed Science
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    • v.30 no.2
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    • pp.153-163
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    • 2010
  • This study was carried out to establish an improved bioassay system, whole-plant bioassay which is more effective in developing natural herbicides for foliar treatment such as herbicidal essential oils. Two bioassay systems using four weed species (Echinochloa crus-galli, Digitaria sanguinalis, Aeschynomene indica, and Abutilon theophrasti), spraying method and spotting method, were established. Spraying method is applicable if the amount of test compounds is enough, while spotting method is useful for the small amount of test compounds. The initial application rate was desirable at $2,500{\sim}5,000\;{\mu}g\;mL^{-1}$. Herbicidal activities were higher in the NOP treatment when compared to the Tween 20 treatment. To efficiently evaluate volatile compounds such as essential oils, if the compound-treated pots were incubated in dew chamber for about 10hrs, better results were obtained in the degree and stability of herbicidal responses. When the efficiency of bioassay systems established in this study was compared, the spraying method was minimized four times to the conventional method that has beed used for screening of synthetic compounds in KRICT. On the other hand, in the spotting method, screening for development of a natural herbicides was possible even in level of 1/100 test volume and 1/200 amounts of test compound compared to the spraying method.

Yield Variation in Different Harvest Time of Coix lachryma L. var. Ma-yuen STAPF (율무의 기계수확(機械收穫) 시기(時期)에 따른 수량성(收量性))

  • Yi, Eun-Sub;Lee, Jun-Seok;Kim, Ki-Jung;Lee, Hyo-Seung
    • Korean Journal of Medicinal Crop Science
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    • v.5 no.4
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    • pp.284-288
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    • 1997
  • In order to study on suitable harvest time of adlay utilizing self-feeding combine harvester with four rows, which is originally designed for rice harvest, harvesting were carried out at four different times (40, 50, 60 and 70 days after anthesis) . For efficient operation, appropriate working rows were 2 rows at 50 days after anthesis and working speed was 0.26m/sec at 60 days after anthesis. Theoretical working capability was 11.23a/hr at 60 days after anthesis. As the harvesting was delayed, water content of adlay decreased. Water content of culm+leaf was $69.7{\sim}55.3%$ and water content of grain was 34.2% at 60 days after anthesis. The later adlay was harvested. the higher the percent of ripened grain was. But the immature grain was decreased. Remnants was less than 1.8% at 60 days after anthesis. The later adlay was harvested, the heavier volume weight was. Yield was the highest at 60 days after anthesis. When utilizing self-feeding combine harvester with four rows, which was originally designed for rice harvest, suitable harvesting time was 60 days after anthesis. Therefore, theoretically suitable harvest time was 68 days after anthesis.

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Advanced Water Treatment of High Turbidity Source by Hybrid Process of Ceramic Ultrafiltration and Photocatalyst: 3. Effect of Organic Matters at $N_2$ Back-flushing (세라믹 한외여과 및 광촉매 혼성공정에 의한 고탁도 원수의 고도정수처리: 3. 질소 역세척 시 유기물의 영향)

  • Park, Jin Yong;Han, Ji Soo
    • Membrane Journal
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    • v.22 no.3
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    • pp.171-177
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    • 2012
  • Effect of humic acid (HA), photo-oxidation and adsorption with periodic $N_2$ back-flushing was investigated in hybrid process of ceramic ultrafiltration and photocatalyst for drinking water treatment. It was compared and investigated with the previous result at water back-flushing in viewpoints of membrane fouling resistance ($R_f$), permeate flux (J), and total permeate volume ($V_T$). As decreasing HA, $R_f$ decreased dramatically and J increased, and finally $V_T$ was the highest at HA 2 mg/L. As HA concentration increased from 2 to 10 mg/L, the membrane fouling resistance after 180 mins' operation ($R_{f,180}$) improved 0.8 times more than that of water back-flushing. Therefore, HA concentration should affect on the membrane fouling at $N_2$ back-flushing than water back-flushing. Turbidity treatment efficiencies were almost constant independent of HA concentration, but HA treatment efficiency was the maximum at HA 2 mg/L. This means that adsorption and photo-oxidation of photocatalyst beads could removed HA at HA 2 mg/L, but it was not enough at 4 mg/L. Beyond HA 6 mg/L, UF could effectively treat HA by thick cake layer on membrane surface and severe inner membrane fouling.

Private Procurement for Constructions and Operation of Buman Road in Daegu (도시 인프라 시설을 위한 민자 유치 -대구시 범안로 민자도로의 운영 실태와 대책-)

  • Choi, Byung-Doo
    • Journal of the Korean association of regional geographers
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    • v.13 no.6
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    • pp.674-694
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    • 2007
  • Recently private procurement projects for urban infrastructure have been emphasized and introduced by government(both central and local) as an important method to supplement public budget shortage and to improve creativity and efficiency in its construction and operation, and hence to promote regional development. But these private procurement projects seem to be implemented under the neoliberal condition of urban policy for private capital to extend its sphere of investment and to ensure its opportunity of profit. Such private procurement projects for urban infrastructure have been legislated and widely applied since 1994 in S. Korea, but in recent years they have triggered out a variety of serious problems. In results of this study on the private procurement for construction and operation of Burnan Road in Daegu, it can be pointed out, it has led serious problems such as overestimation of traffic volume in plan, over-appropriation of construction cost and appurtenant business, irYational operation and account of the operating firm, problem in refinancing and change in contents of practical agreement, and over-compensation of minimum operation revenue. Some measures that can be considered as alternatives to resolve those problems and to operate more rationally the Buman Road include those of increasing traffic revenues, of reducing supports of public financing, and withdrawal of (part or whole of) operational right from the private firm.

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Investigation of Water-Washing Process Parameters for Removal of Alkali Metals and Chlorides from Electric Arc Furnace Dust (EAFD) (전기 제강로 분진(EAFD)으로부터 알칼리 금속 및 염화물 제거를 위한 수 세척 공정 운영인자 조사)

  • Lee, Han Saem;Park, Da so mi;Ha, Jong Gil;Shin, Hyun Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.11
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    • pp.626-633
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    • 2017
  • The present study investigated the effect of a water-washing process, which is part of the acid hydrometallurgical process for recovery of high purity of zinc, on the removal of alkali metals and chlorides (Na, K, Ca, Cl) from Electric arc furnace dust (EAFD). Two EAFD samples with different properties were characterized by particle size, XRD and element analysis, and their washing efficiencies (%) on alkali metals and chlorides were compared according to pH, washing time, liquid to solid (L/S) ratio and number of washings. The results show that the alkali metals and chlorides could be effectively removed by the washing (at L/S ration of 3 for more than 30 min., pH 10~11) while minimizing loss of zinc (<0.1%), in which the washing efficiency was Na-78%, K-76%, Cl >99%, respectively. Na and K could be removed up to 97% and 89% respectively by 3 times of repeated washings. With increased sample volume (10 times) of the mixed (1:1, w/w) sample with two types of EAFD, it was confirmed that the pH(10~11) can be used as the main process control parameter for the washing of the alkali metals regardless of EAFD properties.

DETERMINATION OF CADMIUM, COPPER, LEAD, ZINC AND MERCURY IN SEA WATER BY ATOMIC ABSORPTION SPECTROPHOTOMETRY (해수중 카드뮴, 구리, 납, 아연 및 수은의 원자흡광정량법)

  • WON Jong Hun;PARK Chung Kil;YANG Han Serb
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.9 no.3
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    • pp.169-175
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    • 1976
  • A solvent extraction-atomic absorption spectrophotometry for determination of trace amount of cadmium, copper, lead and zinc and a flameless atomic absorption spectrophotometry for mercury in sea water were studied. The optimum pH range for solvent extraction was pH 4-7. A better solvent extraction efficiency was obtained with MIBK solvent than nitrobenzene, benzene, isoamylalcohol, n-buthylacetate. DDTC was more advantageous than APDC as chelating agent. The metals, chelated with DDTC and concentrated into MIBK by solvent extraction with a volume of $1\iota$ of sea water for cadmium, copper and lead, and 200m1 for zinc, were determined simultaneously by atomic absorption spectrophotometry. For mercury determination, 500ml of sea water was digested with permanganate-sulfuric acid and mercury( II ) was reduced by stannous chloride and aerated the solution with air pump until the absorbance reached a constant value. The precisions, in standard deviation, of these methods were 0.058ppb for cadmium, 0.084 ppb for copper, 0.44ppb for lead, 2.49ppb for zinc and 0.08 ppb for mercury. The sensitivities, expressed in $ppb/1\%$ absorption, were 0.058 ppb cadmium, 0. 15 ppb copper, 0.6 ppb lead, 1.2 ppb zinc and 0.01 ppb mercury respectively. No significant adsorption on the wall of polyethylene sample bottle occurred during 30 days of storing by acidification to pH 1.5 with nitric acid except zinc. Poor reproducibility was found for zinc with this method.

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Fracture Characteristics of Ductile Fiber Reinforced Cement based Composites by Collision of Steel Projectile (비상체의 충돌에 의한 고인성 섬유보강 시멘트복합체의 파괴특성)

  • Nam, Jeong-Soo;Kim, Gyu-Yong;Kim, Hong-Seop;Kim, Jung-Hyun;Han, Sang-Hyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.4
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    • pp.92-100
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    • 2015
  • The aim of this study is to evaluate the fracture characteristics of ductile fiber reinforced cement based composites with 1.5 volume ratio of polyvinyl alcohol and steel fiber by high velocity impact of steel projectile. We used gunpowder impact facility to evaluate the fracture characteristics of ductile fiber reinforced cement based composites by collision of steel projectile, and the impact velocity was from about 150 to 1,000m/s. The results of evaluation on the fracture characteristics of ductile fiber reinforced cement based composites were penetration grade, which is the kinetic energy more than three times of no-fiber reinforced specimen (Plain). In addition, ductile fiber reinforced cement based composites did not occurred critical damage other than the debris. In the case of mass loss, Plain specimen was proportional to kinetic energy of steel projectile, while ductile fiber reinforced cement based composites was not significantly affected by kinetic energy of steel projectile. In particular, this tendency had a close relationship with the fracture characteristics of back side of specimens, and the scabbing inhibiting efficiency of PVA specimen was higher than S specimen. In the results of verifying relationship between front and back side calculated by local damage, scabbing occurred at the region close to the back side in the ductile fiber reinforced cement based composites unlike Plain specimen. Thus, in this study, we examined principal fracture behaviors of ductile fiber reinforced cement based composites under collision of steel projectile, and verified that impact resistance performance was improved as compared to Plain specimen.

Application and Comparison of Dynamic Artificial Neural Networks for Urban Inundation Analysis (도시침수 해석을 위한 동적 인공신경망의 적용 및 비교)

  • Kim, Hyun Il;Keum, Ho Jun;Han, Kun Yeun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.38 no.5
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    • pp.671-683
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    • 2018
  • The flood damage caused by heavy rains in urban watershed is increasing, and, as evidenced by many previous studies, urban flooding usually exceeds the water capacity of drainage networks. The flood on the area which considerably urbanized and densely populated cause serious social and economic damage. To solve this problem, deterministic and probabilistic studies have been conducted for the prediction flooding in urban areas. However, it is insufficient to obtain lead times and to derive the prediction results for the flood volume in a short period of time. In this study, IDNN, TDNN and NARX were compared for real-time flood prediction based on urban runoff analysis to present the optimal real-time urban flood prediction technique. As a result of the flood prediction with rainfall event of 2010 and 2011 in Gangnam area, the Nash efficiency coefficient of the input delay artificial neural network, the time delay neural network and nonlinear autoregressive network with exogenous inputs are 0.86, 0.92, 0.99 and 0.53, 0.41, 0.98 respectively. Comparing with the result of the error analysis on the predicted result, it is revealed that the use of nonlinear autoregressive network with exogenous inputs must be appropriate for the establishment of urban flood response system in the future.

The Productivity and Cost of Yarding Operations Using a Tractor-attached Winch in Pinus densiflora Stands (소나무 임분에서의 트랙터윈치를 이용한 집재작업 생산성 및 비용분석)

  • Jeong, Eung-Jin;Cho, Min-Jae;Park, Jeong-Mook;Cho, Koo-Hyun;Yoo, Young-Min;Cha, Du-Song
    • Journal of Korean Society of Forest Science
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    • v.108 no.4
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    • pp.574-581
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    • 2019
  • The present study analyzed the productivity and cost of winching operations for evaluating the efficiency of a tractor-attached winch in a Pinus densiflora thinning site located in the Yangyang County of Gangwon-do. The mean yarding distance and mean timber volume were 29 m and 0.15 ㎥, respectively. In the 95 cycles of yarding operations, the uphill and downhill yarding operations constituted 51% and 49%, respectively, of the total yarding operations. The productivity of the uphill yarding operation was 2.28 ㎥/h, and the productivity of the downhill yarding operation was 1.89 ㎥/h. The findings of this study revealedthat productivity would increase by 0.5 ㎥/h when the rate of utilization of the machine is increased to 80% by reducing the operational delay time. The cost of the downhill yarding operation was 44,116 KRW/㎥, whereas that of the uphill yarding operation was 53,369 KRW/㎥. The difference in cost resulted from the difference in the number of yarding stems (stems/cycle). Furthermore, the results of the multiple linear regression equation developed for predicting the yarding operation times showed that productivity was significantly affected by working conditions such as yarding distance (m), the number of stems per cycle (stems/cycle), and the terrain slope (%) in the uphill and downhill yarding operations. Further research is required for developing an accurate prediction model equation according to a yarding direction.