• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2008년도 춘계학술대회논문집
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• pp.286-289
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• 2008

Damping materials are widely used to reduce vibration or noise generation of structures. To understand their damping capability and for use in numerical simulations, their viscoelastic properties should be measured in the frequency range of interest. In this study, experimental setup is proposed to measure materials properties of very compliant polymer materials. The polymer materials used in this study are difficult to form into rod shapes, and typical resonance methods are not applicable. In the proposed measurement setup, the damping materials were modeled as a simple viscoelastic support at one end of the beam. Their properties were measured through analysis of their effects on the wave propagation characteristics of the beam structure.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 The Korea-Japan Plastics Processing Joint Seminar
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• pp.1-6
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• 2003

In injection molding of an optical disk, a toric lens, etc., their performance depends on the transcription preciseness of fine surface structure of a mold. However, transcription behavior has not been made clear yet, because transcription is made in very short time and the structure is very small. In this paper, transcription properties have been examined, by using V-grooves of various sizes. machined on mold surfaces, and the following results are obtained. (1) Transcription properties have been made clear experimentally and it was found that the mold temperature $T_D$ makes great influence on the transcription property and that compression applying time $t_c$ should be taken more than 2.0s for fine transcription. (2) A mechanical model of transcription process, in consideration with strain recovery due to viscoelastic property of polymer. is proposed. (3) Simulation results agree with experimental ones fairly well. It means that the transcription model is useful for estimation of transcription property in advance of an actual. injection molding.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2002년도 금형가공 심포지엄
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• pp.125-131
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• 2002

Surface defects in injection molded parts are due to the unsteady flow of polymer melt which are related to the geometries of cavity and gate, the operational conditions of injection and the rheological properties of polymer. In this study we have examined jetting phenomena in injection molding process for three kinds of PCs which have different molecular weight and structure, PBT and PC/ABS alloy with several injection speeds. We have used various cavity shapes that are tensile, flexural and impact test specimens with various gate and cavity thicknesses. Through this study we have observed that the formation of surface defect associated with jetting during filling stage in injection molding is strongly related to die swell. This means that the jetting is strongly affected by the elastic property rather than the viscous property in viscoelastic characteristics of molten polymer. Large die swell would eliminate jetting however, the retardation of die swell would stimulate jetting. In the point of mold design, reducing the thickness ratio of cavity to gate can reduce or eliminate jetting and associated surface defects regardless of magnitude of elastic property. It also enlarges process window that can produce steady flow of polymer melt in injection molding.

• 한국정밀공학회지
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• 제22권2호
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• pp.180-187
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• 2005

This paper is focused on the development of the flexible electrode for disc-type polymer actuators using Segmented Polyurethane(SPU). This paper consists of two parts. The one is about the mechanical property such as elastic modulus. these parameters mainly affect behaviors of polymer actuators and the other is about the electro-chemical property such as the surface resistance of the composite electrode affects the strength of electrostatic force, results in the deformation of polymer actuators. The Young's modulus was measured by UTM. As result, by increasing the modulus of a body of polymer actuators, the maximum displacement of polymer actuators are decreased. The surface resistance of the electrode was measured by 4 point probe system. Compared with the conductive silver grease, the displacement of polymer actuators using carbon black(CB) composite electrodes is comparably small but CB composite electrode should be the practical approach for the improvement of the performance of all-solid actuators, compared with another types of electrode materials.

• 폴리머
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• 제34권3호
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• pp.226-236
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• 2010

UV조사에 의한 공중합반응을 통해 PDP의 방열패드용 무용제형 아크릴계 점착제를 제조하고 이때 도입되는 공단량체의 곁사슬의 화학적 구조와 가교제의 종류에 따른 점착제의 젖음성을 온도별로 조사하였다. 또한, 동일 조건에서 점착제의 초기 접착력 및 박리강도와 주파수 변화에 따른 점착제의 점탄성 거동 간의 상관관계를 확인하였다. 공단량체의 곁사슬의 길이가 짧을수록 넓은 온도범위에서 우수한 젖음성과 점착 물성을 보였으며 경화제로는 di(ethylene glycol) dimethylacrylate(DEGDMA)를 사용한 계가 우수한 박리 에너지를 보였는데, 이것은 유리전이온도와 점탄성거동의 차이에 기인하는 것으로 판단된다.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2009년도 춘계학술대회 논문집
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• pp.70-73
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• 2009

The aim of this research is to obtain a numerical material model for an amorphous glassy polymer, polycarbonate (PC), which can be used in finite element analysis (FEA) of the micro thermal imprint process near the glass transition temperature. An understanding of the deformation behavior of the PC specimens was acquired by performing tensile stress relaxation tests. The viscoelastic material model based on generalized Maxwell model was introduced for the material near Tg to establish the FE model based on the commercial FEA code ABAQUS/Standard with a suitable set of parameters obtained for this material model from the test data. Further validation of the model and parameters was performed by comparing the analysis of FE model results to the experimental data.

• 소성∙가공
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• 제12권1호
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• pp.3-10
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• 2003

The formation of surface defects associated with Jotting in injection molding is related to the geometries of cavity and fate, operational conditions and the rheological properties of polymer. In this study we have examined jetting phenomena in injection molding process for the throe kinds of PCs which have different molecular weights and structures, PBT and PC/ABS alloy with several injection speeds. We have used various cavity shapes those are tensile, flexural and impact test specimens with various gates and cavity thicknesses. Through this study we have observed that the jetting is related to the dic swell of material. This means that the jotting is strongly affected by the elastic flow property rather than the viscous flow property in viscoelastic characteristics of molten polymer. Different resins have different elastic properties, and elastic flow behavior depends on the shear rate of flow, i.e. injection speed. Large die swell would eliminate jetting however, the retardation of die swell would stimulate jetting. In the point of mole design, reducing the thickness ratio of cavity to gate can reduce or eliminate jetting regardless of amount of elasticity of polymer melt.

• 폴리머
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• 제26권5호
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• pp.559-567
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• 2002

Poly (vinyl chloride) (PVC)와 vinyl chloride(VC)/acrylonitrile(AN) 함량비에 따른 poly-(VC-co-AN)와의 블렌드 필름을 제조하여 morphology, 점도, 동적 점탄성 및 기계적 물성을 고찰하였다. 블렌드의 morphology는 전반적으로 matrix-domain 형태의 비상용계로 공중합체에서 VC 함량이 증가할수록 morphology는 다소 균일하였다. 특히 VC 함량이 77.21%인 MO-01 블렌드의 경우 PVC가 많은 영역에서 상용성은 우수하였다. 블렌드 용액의 점도는 전반적으로 비상용성으로 인하여 negative deviation을 보이나, MO-01 블렌드에서 PVC 함량이 90%일 때 급격한 점도의 증가를 보였으며, 저장탄성율 및 T$_{g}$ 거동에서 MO-01 블렌드의 경우 상용성 블렌드의 T$_{g}$ 변화와 경향이 유사하였으나 MO-02 및 MO-03의 경우 비상용성 블렌드의 경향을 나타내었다. PVC와 poly(VC-co-AN)의 블렌드에서 VC의 함량이 가장 높은 MO-01와 90:10인 조건에서의 상용성이 가장 뛰어났으며, 블렌드 필름의 기계적 물성의 향상은 발견할수 없었다.

• 폴리머
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• 제29권4호
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• pp.375-379
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• 2005

생분해성 고분자인 poly(L-lactic acid) (PLLA)에 판상구조의 몬모릴로나이트(montmorillonite, MMT)를 첨가하여 필름형태의 나노복합재료를 제조하고, 무기나노입자의 첨가유무와 가수분해 전후의 열적 특성, 점탄성 특성, 모폴로지 등을 조사하였다. PLLA/MMT 나노복합재료의 XRD 분석결과와 TEM 사진으로부터 MMT 입자가 PLLA에 박리 및 분산되어 있음을 확인하였으며, 가수분해가 진행됨에 따라 U 결정 영역의 상대적인 양이 증가하므로 용융에너지 (${\Delta}H_m$가 더 필요함을 알 수 있었다. MMT를 첨가한 경우에 MMT가 강화제 역할을 하기 때문에 저장탄성률이 더 높은 값을 가졌는데, 이는 PLLA를 나노복합화하였을 때 인장강도, 충격강도 등의 기계적 물성이 증가한다는 이전의 연구와도 잘 일치하였다. 또한. 가수분해 전/후의 SEM사진으로부터, 표면에 스피노달(spinodal) 분해에 의한 거칠고 원형의 구멍들이 생겼음을 관찰할 수 있었으며, 가수분해가 진행됨에 따라 나노복합재료는 원형의 구멍들의 크기가 가수분해전보다 더 커졌을 뿐 원래의 형상을 유지하였다. 본 연구를 통하여 PLLA/MMT나노복합재료의 생분해 속도와 열적, 기계적 특성의 조절 가능성을 제시하였다.

• 폴리머
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• 제39권1호
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• pp.107-113
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• 2015

클로로부틸(CIIR) 방진고무 복합소재 내에서 실리카-실란이 기계적 물성과 점탄성에 미치는 영향을 평가하였다. 실리카-실란이 첨가된 경우, 방진고무의 핵심물성 중 하나인 인열강도는 13%, 파단 신장률은 14%씩 각각 증가하였다. 그 외 인장강도 및 경도 등은 비슷한 값을 보였다. 점탄성 관찰로부터 인열강도 및 파단 신장률의 증가는 실리카-실란의 첨가에 의한 복합소재 내 실리카와 클로로부틸간 3차원 사슬구조의 형성에 따른 것으로 판단되었다. 인열강도 및 파단 신장률의 향상에 관한 메커니즘을 논의하였다.