• Bulletin of the Korean Chemical Society
• /
• 제27권10호
• /
• pp.1641-1647
• /
• 2006

Vibrational relaxation and competitive C-$H_{methyl}$ and C-$H_{ring}$ bond dissociations in vibrationally excited methylpyrazine in the collision with HF have been studied by use of classical trajectory procedures. The energy lost by the vibrationally excited methylpyrazine upon collision is not large and it increases slowly with increasing total vibrational energy content between 20,000 and 45,000 $cm^{-1}$. Above the energy content of 45,000 $cm^{-1}$, however, energy loss decreases. The temperature dependence of energy loss is negligible between 200 and 400 K, but above 45,000 $cm^{-1}$ the energy loss increases as the temperature is raised. Energy transfer to or from the excited methyl C-H bond occurs in strong collisions with HF, that is, relatively large amount of translational energy is transferred in a single step. On the other hand, energy transfer to the ring C-H bond occurs in a series of small steps. When the total energy content ET of methylpyrazine is sufficiently high, either or both C-H bonds can dissociate. The C-$H_{methyl}$ dissociation probability is higher than the C-$H_{ring}$ dissociation probability. The dissociation of the ring C-H bond is not the result of the direct intermolecular energy flow from the direct collision between the ring C-H and HF but the result of the intramolecular flow of energy from the methyl group to the ring C-H stretch.

• 한국소음진동공학회논문집
• /
• 제20권11호
• /
• pp.1097-1102
• /
• 2010

In this paper, the energy flow analysis(EFA) of the body-in-white door of a real automotive was performed using the energy flow finite element method(EFFEM) to effectively predict the vibrational responses of built-up structures in the medium to high frequency range. To increase the validity of EFA results, the structural hysteresis damping loss factor was measured by the experiment using the concept of statistical energy analysis(SEA). As the excitation frequency increases, the predicted results simulated with EFFEM generally agree with the experimental results.

• Bulletin of the Korean Chemical Society
• /
• 제24권8호
• /
• pp.1091-1096
• /
• 2003

The effects of different polarization conditions on vibrational echo signals are systematically explored for the rigid cyclic dipeptide 2,5-diazabicyclo[2,2,2]octane-3,6-dione. An anharmonic vibrational Hamiltonian is constructed by computing energy derivatives to fourth order using density functional theory. Molecular frame transition dipole orientations are then used to calculate polarization dependent orientational factors corresponding to various Liouville space pathways. Enhancement and elimination of specific peaks in twodimensional correlation plots is accomplished by identifying appropriate pulse configurations.

• Bulletin of the Korean Chemical Society
• /
• 제25권9호
• /
• pp.1397-1402
• /
• 2004

The vibrational predissociation of triatomic, i.e., atom-diatom, van der Waals complexes in transient electronic excited state has been widely investigated. The predissociation rates or lifetimes are major concerns of the previous studies. Experimentally rotational state distributions of diatomic product are hardly investigated and few theoretical stuides on rotational state distributions have appeared in literature. In this work, choosing the frequently studied $I_2(B)-Ne$ complex as an example, we investigate the change of rotational state distributions of $I_2(B)-Ne$ produced from predissociation of the various initial states of $I_2(B)-Ne$. The present study on the rotational distributions indicates that rotational state distributions depend significantly on the predissociation energy and the van der Waals vibrational modes of $I_2(B)-Ne$. That is, the initial state dependency of rotational state distributions is extensively discussed.

• Structural Engineering and Mechanics
• /
• 제43권3호
• /
• pp.395-410
• /
• 2012

The visualizing energy flow and control in vibrating stiffened plates with a cutout are studied using finite element method. The vibration intensity, vibration energy and strain energy distribution of stiffened plates with cutout at different excitation frequencies are calculated respectively and visualized for the various cases. The cases of different size and boundaries conditions of cutouts are also investigated. It is found that the cutout or opening completely changes the paths and distributions of the energy flow in stiffened plate. The magnitude of energy flow is significantly larger at the edges near the cutout boundary. The position of maximum strain energy distribution is not corresponding to the position of maximum vibrational energy. Furthermore, the energy-based control using constrained damping layer (CDL) for vibration suppression is also analyzed. According to the energy distribution maps, the CDL patches are applied to the locations that have higher energy distribution at the targeted mode of vibration. The energy-based CDL treatments have produced significant attenuation of the vibration energy and strain energy. The present energy visualization technique and energy-based CDL treatments can be extended to the vibration control of vehicles structures.

• 신재생에너지
• /
• 제2권3호
• /
• pp.5-9
• /
• 2006

We have fabricated a micro power generator which changes vibrational energy into useful energy. With vibrating a magnet on the surface of a winding coil, the micro power generator produce alternating voltage. We have changed the vibrational frequency from 0.5Hz to 10Hz. AC voltage of $20{\sim}25mV$ was generated at the frequency of 1Hz. When the vibration was 3Hz, AC voltage of 80mV was obtained. We have rectified and stepped up the input voltage using a quadrupler circuit. The voltage was stepped up to 130mV.

• 한국광학회:학술대회논문집
• /
• 한국광학회 1990년도 광학 및 양자전자학 워크샵
• /
• pp.94-100
• /
• 1990

The rapid quenching dynamics of the F-center excitation by CN- defects in CsCl crystals were investigated by monitoring the ground state bleach recovery kinetics of F-centers, using a picosecond streak camera absorption spectrometer. The F-centers in CN- doped quenched samples show two bleach recovery components. Optical aggregation converts the slow component to the fast component. The slow one is due to the normal relaxation of the F*-centers as found in CN_ free crystals. The fast one is due to the energy transfer of the F-center electronic excitation to the vibrational energy levels of CN_ molecualr defects. The energy transfer occurs only in the F-center-CN_ defect pairs, FH(CN_)-centers.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 2000년도 춘계학술대회논문집
• /
• pp.301-308
• /
• 2000

The power flow analysis(PFA) has been performed to analyze the vibration of coupled plates excited by a point force in an arbitrry direction. The energy governing equations for longitudinal, shear and flexural waves were solved to predict the vibrational energy density and intensity. The wave transmission approach was used to consider the mode conversion at the joints of the coupled plates. Numerical results for energy density and intensity on the coupled plates were presented. Comparison of the results by PFA with exact results showed that PFA can be an effective tool to predict the spatial variation of the vibrational energy and intensity on the coupled plates at high frequencies.

• 한국정보통신학회:학술대회논문집
• /
• 한국정보통신학회 2017년도 추계학술대회
• /
• pp.425-428
• /
• 2017

본 논문에서는 진동 에너지를 이용하여 에너지를 수확하는 전파 정류 하베스팅 회로를 설계하였다. 설계된 회로는 저전압에서도 전력효율이 우수하도록 Beta-Multiplier를 이용하여 Body-Bias technique을 Negative Voltage Converter에 적용하였으며, Comparator를 Bulk-Driven type으로 설계하였다. 제안된 회로는 $0.35{\mu}m$ CMOS 공정으로 설계하였으며, 설계된 회로의 칩 면적은 $931{\mu}m{\times}785{\mu}m$이다.

• Bulletin of the Korean Chemical Society
• /
• 제18권9호
• /
• pp.985-994
• /
• 1997

The reaction of gas-phase atomic hydrogen with hydrogen atoms chemisorbed on Fe(110) surface is studied by use of classical trajectory procedures. Flow of energy between the reaction zone and bulk solid phase has been treated in the generalized Langevin equation approach. A London-Eyring-Polanyi-Sato energy surface is used for the reaction zone interaction. Most reactive events are found to occur in strong single-impact collisions on a subpicosecond scale via the Eley-Rideal mechanism. The extent of reaction is large and a major fraction of the available energy goes into the vibrational excitation of H2, exhibiting a vibrational population inversion. Dissipation of reaction energy to the heat bath can be adequately described using a seven-atom chain with the chain end bound to the rest of solid. The extent of reaction is not sensitive to the variation of surface temperature in the range of Ts=0-300 K in the fixed gas temperature, but it shows a minimum near 1000 K over the Tg=300-2500 K.