• Title/Summary/Keyword: Valorization

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Eosin Biosorption from Aqueous Solution on Two Types of Activated Sludge

  • Cherifa, Farsi;Hakima, Cherifi;Radhia, Yous;Salah, Hanini;Razika, Khalladi
    • Korean Chemical Engineering Research
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    • v.60 no.1
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    • pp.80-85
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    • 2022
  • In wastewater treatment processes huge quantities of sludge are produced continuously each year. This work investigated the reuse of two types of sludge as biosorbents of a toxic dye. The potential of granular and filamentous fungus dried sludge for the elimination of eosin from aqueous solution was studied in batch system. The effect of initial concentration and temperature was examined. Maximum uptake was observed at 100 mg l-1 and 30 ℃. The maximum removal rate was 92% for the granular sludge and 90% for the filamentous one. Equilibrium was attained after 30 min for the studied dye concentrations. The equilibrium uptake increased with the initial eosin concentration. The Freundlich and Langmuir adsorption models were also investigated. The reuse of disposed sludge as adsorbent could be a solution for the valorization of such dangerous waste to resolve two environmental problems at the same time.

Bioactive peptides-derived from marine by-products: development, health benefits and potential application in biomedicine

  • Pratama, Idham Sumarto;Putra, Yanuariska;Pangestuti, Ratih;Kim, Se-Kwon;Siahaan, Evi Amelia
    • Fisheries and Aquatic Sciences
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    • v.25 no.7
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    • pp.357-379
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    • 2022
  • Increased fisheries products have raised by-products that are discarded due to low economic value. In addition, marine by-products are still rich in protein and nutritional value that have biological activities and give benefits to human health. Meanwhile, there is raised pressure for sustainability practices in marine industries to reduce waste and minimize the detrimental effect on the environment. Thus, valorization by-products through bioactive peptide mining are crucial. This review focus on various ways to obtain bioactive peptides from marine by-products through protein hydrolysis, for instance chemical hydrolysis (acid and based), biochemical hydrolysis (autolysis and enzymatic hydrolysis), microbial fermentation, and subcritical water hydrolysis. Nevertheless, these processes have benefits and drawbacks which need to be considered. This review also addresses various biological activities that are favorable in pharmaceutical industries, including antioxidant, antihypertensive, anticancer, anti-obesity, and other beneficial bioactivities. In addition, some potential marine resources of Indonesia for the marine biopeptide from their by-product or undesired marine commodities would be addressed as well.

Evaluation of the Effects of Carbon Dioxide on the Production of Engineered Biochar (기능성 바이오차 생산을 위한 이산화탄소의 영향 평가)

  • Lee, Sangyoon;Lee, Taewoo;Kwon, E. Eilhann
    • Journal of Soil and Groundwater Environment
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    • v.27 no.2
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    • pp.41-49
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    • 2022
  • To abate the environmental burdens arising from CO2 emissions, biochar offers a strategic means to sequester carbons due to its recalcitrant nature. Also, biochar has a great potential for the use as carbon-based adsorbent because it is a porous material. As such, developing the surface properties of biochar increases a chance to produce biochar with great adsorption performance. Given that biochar is a byproduct in biomass pyrolysis, characteristics of biochar are contingent on pyrolysis operating parameters. In this respect, this work focused on the investigation of surface properties of biochar by controlling temperature and reaction medium in pyrolysis of pine sawdust as case study. In particular, CO2 was used as reaction medium in pyrolysis process. According to pyrolytic temperature, the surface properties of biochar were indeed developed by CO2. The biochar engineered by CO2 showed the improved capability on CO2 sorption. In addition, CO2 has an effect on energy recovery by enhancing syngas production. Thus, this study offers the functionality of CO2 for converting biomass into engineered biochar as carbon-based adsorbent for CO2 sorption while recovering energy as syngas.

Valorization of Cork Waste to Improve the Anti-Corrosion Properties of Concrete Reinforcements

  • Belkhir, S.;Bensabra, H.;Chopart, J.P.
    • Corrosion Science and Technology
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    • v.21 no.2
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    • pp.100-110
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    • 2022
  • Corrosion of steel reinforcement is the most important mode of concrete structures damages. It strongly depends on the composition and physicochemical properties of the cementitious medium. The use of waste materials as lightweight aggregates in concrete is environmentally recommended in polluted environments such as marine and/or industrial atmospheres in order to reduce its porosity and ensure the requested protection of reinforcing steel. The present study investigated the effect of waste cork addition on corrosion resistance of steel rebar in mortar specimen prepared in the laboratory. The main objective of this study was to improve the corrosion resistance of reinforcing steel. Another objective of this study was to valorize this ecological product and preserve the environment. Results obtained from various electrochemical tests indicated that the presence of a fine cork powder substantially improved the corrosion resistance of steel in the mortar contaminated by chloride ions. This improvement was reflected by a notable decrease in corrosion current density and a shift of corrosion potential of the steel towards more noble values. Moreover, the presence of a fine cork powder in the mortar had no adverse effect on its mechanical properties.

Twain's Contestation of Emersonian Transcendental Manhood in Huckleberry Finn

  • Park, Joon Hyung
    • Journal of English Language & Literature
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    • v.58 no.6
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    • pp.1193-1213
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    • 2012
  • This essay "Twain's Contestation of Emersonian Transcendental Manhood in Huckleberry Finn" explores how Mark Twain's Adventures of Huckleberry Finn (1884) manifests his postwar contestation of Ralph Waldo Emerson's transcendental manhood that endorses the dogmatic, egocentric, and decorporealized position of the Cartesian subject, who believes his being's unity, elevation, and centrality through his fantasy of possessing direct access to divine truth. The connection between Emerson and Twain is based not on Emerson's influence on Twain but on their common interest in American landscape as a site for the redefinition of manhood and masculinity. I examine different types of manhood in their association with nature in Huckleberry Finn by comparing them with the two fundamental concepts of Emerson's philosophy: "a true man" in "Self-Reliance" (1841) and transparent eyeball vision in Nature (1836). Twain's use of Huck's ambivalent position-his centrality as a protagonist in the novel in spite of his marginality in society-renegotiates Emerson's valorization of nonconformity, wholeness, and nonchalance as the characteristics of both boyhood and "a true man," Emerson's term for the ideal individual in "Self-Reliance." I also read Twain's satire of two different types of masculine characters-Bob and the Child of Calamity, boatmen of the Southern frontier, and Colonel Grangerford, patriarch of a Southern aristocratic family-as Twain's denouncement of the antebellum desire for transcendental vision, which Emerson crystalizes into his notion of transparent eyeball in Nature.

Phosphogypsum purification for plaster production: A process optimization using full factorial design

  • Moalla, Raida;Gargouri, Manel;Khmiri, Foued;Kamoun, Lotfi;Zairi, Moncef
    • Environmental Engineering Research
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    • v.23 no.1
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    • pp.36-45
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    • 2018
  • The phosphogypsum (PG) is a byproduct of the phosphate fertilizers manufacture. The world production estimated to 200 million tons per year induces environmental threats and storage problems, which requires strict policies to limit pollution and encourage its valorization. This paper presents a purification process of the crude PG including treatment with a diluted sulfuric acid, floatation, filtration and washing. The purified PG is used to produce plaster. The process optimization was conducted using a full factorial design. The significant factors considered in the experimental study are temperature ($X_1$), volume of sulfuric acid solution ($X_2$) and PG quantity ($X_3$). The main effects and interaction effects of these factors on the responses of the % $P_2O_5$, % F, Total Organic Carbon (TOC) ($mg{\cdot}kg^{-1}$) and pH were analyzed. The optimum conditions for $X_1$, $X_2$ and $X_3$ were found to be $60^{\circ}C$, 3 L and 1 kg, respectively and the optimized pH values was found to be 6.2. Under these conditions, 60% of $P_2O_5$, 95% of Fluorine and 98% of TOC were removed from PG. The predicted values were found approximately the same as the experimental ones. The plaster produced with purified PG was found to have similar properties to that produced from natural gypsum.

Effects of extrusion of rice bran on performance and phosphorous bioavailability in broiler chickens

  • Zare-Sheibani, Ali Akbar;Arab, Masoud;Zamiri, Mohammad Javad;Rezvani, Mohammad Reza;Dadpasand, Mohammad;Ahmadi, Farhad
    • Journal of Animal Science and Technology
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    • v.57 no.7
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    • pp.26.1-26.5
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    • 2015
  • Background: Rice bran is a by-product of the rice-milling process, which remains largely underutilized; however, efficient processing treatments may improve its feeding value for chickens. This is of great economic and environmental importance, as this can lower the production costs, and offer an opportunity for valorization of a low-quality agricultural by-product, to a high-value feed source. Methods: This experiment was conducted to study the effect of extruded rice bran on performance and phosphorous (P) bioavailability in broiler chickens. In a completely randomized design, 200 seven-day-old broilers (Cobb 500) were allotted to five treatments with five replicates per treatment and 8 chicks per replicate, and fed with their respective diet during the starter (8 to 21 days) and grower (22 to 42 days) periods. Diets were a basal corn-soybean based diet (T1), or diets containing 20 % rice bran (T2), 30 % rice bran (T3), 20 % extruded rice bran (T4), or 30 % extruded rice bran (T5). Results: Birds feeding on T4 and T5 diets had a higher body weight gain and lower feed-to-gain ratio compared to those feeding on T2 and T3 diets (p < 0.05). Birds receiving diets containing extruded rice bran had higher total P availability and tibia ash content, as compared with those receiving diets containing un-extruded rice bran (p < 0.05). Relative weight of the pancreas was higher in birds receiving T2 and T3 diets. Conclusions: The results confirmed the beneficial effect of extrusion treatment of rice bran on performance and P availability in broilers. Up to 30 % extruded rice bran may be included in the broiler diet without apparent adverse effects on the performance.

Valorization of Food Wastes(I) Utilization of Banana Peel Extracts in Natural Dyeing (식품폐기물의 자원화(I) 바나나 껍질 추출물의 천연염색에 활용)

  • Choi, Min;Shin, Youn-Sook;Yoo, Dong-Il
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.67-67
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    • 2012
  • 식생활 및 사회 환경 변화에 따라 식품 폐기물이 많이 발생하고 있다. 이 폐기물을 처리하는 데 막대한 비용이 소요되고 환경오염도 심각한 상황이다. 이에 식품 폐기물의 자원화를 통해 자원의 부가가치를 높이고, 처리비용 절감과 함께 환경오염 방지, 새로운 유기소재의 확보 등의 효과를 볼 것으로 사료된다. 본 연구는 바나나 껍질로부터 추출한 물질의 다양한 기능성을 조사하고, 인디고의 환원제로서 유효성을 확인하여 천연염색 분야에 식품 폐기물의 활용 방안을 모색하는데 목적이 있다. 이를 위하여 바나나 껍질은 건조 후 증류수로 $100^{\circ}C$에서 1시간 동안 추출, 농축하여 분말로 만들어 사용하였다. 바나나 껍질 추출물의 기능성을 알아보기 위해 총당분석(Phenol- sulfuric method), 항산화(DPPH radicals 소거활성), 황색포도상구균에 대한 항균성 실험(Paper disc diffusion)을 하였다. 또한 인디고 염색시 화학환원제 대신 이 분말을 사용하였고, 그 환원력 측정은 환원 포텐셜과 염색 실험을 통해 평가하였다. 본 연구에서 제조한 바나나 껍질 추출물은 항산화능이 우수하였고, 높은 당 함량을 나타냈다. 황색 포도상구균에 대한 항균성을 지녀 향후 기능성 물질로서 응용가능성이 클 것으로 전망된다. 바나나껍질 추출물은 합성인디고 환원에 효과적이었다. 인디고 환원은 바나나껍질 추출물을 첨가하면서 바로 시작되고, 24시간 경과 후 최대 염착량과 최고 전압값을 나타냈다. 바나나 껍질 추출물의 농도가 높아질수록 인디고 환원력은 높아지고 염착량도 증가하는 것으로 나타났다. 따라서 바나나 껍질 추출물은 인디고 환원에서 화학물질인 하이드로설파이트를 대체하여 사용할 수 있는 효과적인 천연유기환원제로 사용할 수 있을 것으로 기대된다.

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Itaconic and Fumaric Acid Production from Biomass Hydrolysates by Aspergillus Strains

  • Jimenez-Quero, A.;Pollet, E.;Zhao, M.;Marchioni, E.;Averous, L.;Phalip, V.
    • Journal of Microbiology and Biotechnology
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    • v.26 no.9
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    • pp.1557-1565
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    • 2016
  • Itaconic acid (IA) is a dicarboxylic acid included in the US Department of Energy's (DOE) 2004 list of the most promising chemical platforms derived from sugars. IA is produced industrially using liquid-state fermentation (LSF) by Aspergillus terreus with glucose as the carbon source. To utilize IA production in renewable resource-based biorefinery, the present study investigated the use of lignocellulosic biomass as a carbon source for LSF. We also investigated the production of fumaric acid (FA), which is also on the DOE's list. FA is a primary metabolite, whereas IA is a secondary metabolite and requires the enzyme cis-aconitate decarboxylase for its production. Two lignocellulosic biomasses (wheat bran and corn cobs) were tested for fungal fermentation. Liquid hydrolysates obtained after acid or enzymatic treatment were used in LSF. We show that each treatment resulted in different concentrations of sugars, metals, or inhibitors. Furthermore, different acid yields (IA and FA) were obtained depending on which of the four Aspergillus strains tested were employed. The maximum FA yield was obtained when A. terreus was used for LSF of corn cob hydrolysate (1.9% total glucose); whereas an IA yield of 0.14% was obtained by LSF of corn cob hydrolysates by A. oryzae.

Introduction of sand marble wastes in the composition of mortar

  • Hebhoub, H.;Belachia, M.;Djebien, R.
    • Structural Engineering and Mechanics
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    • v.49 no.4
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    • pp.491-498
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    • 2014
  • During the past years, the protection of the environment has become a major concern out passing the state frontiers to reach a planetary dimension. Depository waste sites have become a serious problem in terms of their locations and costs. On the other hand, the construction industry has a leading place in terms of quantities of waste produced from the start to the end of each construction site, by the large amounts of raw materials used and their respective consequences on the environment. The recycling of quarry wastes products, of demolished concrete, bricks and large quantities of waste resulting from the transformation of marble blocks can provide ideal solutions and advantages for the preservation of the environment, to become a supplementary source of aggregates. The main purpose of this study is to show technically the possibility of recuperating the aggregates of marble wastes as a partial substitute or total in the mortars. The aggregates used in this study is a sand of marble wastes (excess loads of sand exposed to bad weather conditions) of the quarry derived from Fil-fila marble (Skikda, east of Algeria). To achieve this work, we have studied the effect of sand substitution of marble wastes in the mortar with rates of (25, 50, 75, 100%); comparing the results obtained with reference samples (0%), the properties when the samples are fresh, and the mechanical performances of mortars at solid state (loss and gain of weight, dimensional variations). The introduction of recycled sand in the mortars gives good results and can be used as granulates.