• 한국대기환경학회지
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• 제17권1호
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• pp.75-84
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• 2001

Hot gas filtration method via using ceramic filters is an evolving technology applicable to numerous industrial and air pollution control processes. Alumino silicate, organic and inorganic binders were the major raw materials in manufacturing ceramic filters. In this work, disc type ceramic filters(50$\phi$$\times$10t) were manufactured by vacuum forming processes using ceramic raw materials. The porosity and bulk density of disc type ceramic filers ranged from 86 to 89% and from 0.27 to 0.36 g/㎤, respectively. In this work disc type ceramic medium were tested utilizing coupon experimental apparatus. Disc type filters showed high collection efficiencies over 99.96% with Darchs law coefficients of 4.1$\times$10(sup)10~9.63$\times$10(sup)10/$m^2$ depending on mean pore sizes. In addition, filtration and detachment of ceramic filters turned out to be performed effectively using 10 cm/sec face velocity, 5 minutes filtration cycle, 100msec pulse jet valve opening time and 3 bar pulsing pressure.

• Composites Research
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• 제36권3호
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• pp.162-166
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• 2023

복합재료는 일반적인 고강도 구조체에 활용성이 증가하고 있지만 최신의 복합적인 전자기기 내부 소자 등과 같은 multifunctional 재료들의 성능 특성 요구가 증가하고 있다. 기기의 방열 특성의 경우 대표적으로 요구되는 물성인 반면 복합재료의 경우 적층 공정으로 인해 수직 방향의 열적 특성 제어는 해결해야 될 문제 중 하나이다. 본 연구에서는 vacuum filtration 방법을 이용하여 Carbon fiber reinforced polymer를 제작하였다. 복합재료 제작 공정에서는 섬유들의 분산에 활용성이 가장 뛰어난 세 가지 solvent들을 사용하여 solvent의 영향을 살펴보았다. 또한 세가지의 aspect ratio를 가지는 단섬유 carbon fiber들의 수직 방향의 배열성을 확인하기 위해 현미경을 통한 morphology를 관찰하였고 제작된 시편의 열전도도 측정을 통해 배열성을 검토하였다. 시편의 열전도도 측정 결과 단섬유 carbon fiber의 aspect ratio가 낮을수록 높은 열전도도를 보였으며 through-plane 방향의 열전도도는 DMF, NMP, Acetone 순으로 각각 8.69 W/m·K, 10.32 W/m·K, 13.01 W/m·K의 증가되는 값을 보였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.466-466
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• 2011

There have been several methods to fabricate carbon nanotube (CNT) emitters, which include as-grown, spraying, screen-printing, electrophoresis and bonding methods. Unfortunately, these techniques generally suffer from two main problems. One is a weak mechanical adhesion between CNTs and the cathode. The as-grown, spraying and electrophoresis methods show a weak mechanical adhesion between CNTs and the cathodes, which induces CNT emitters pulled out under a high electric field. The other is a severe degradation of the CNT tip due to organic binders used in the fabrication process. The screen-printing method which is widely used to fabricate CNT emitters generally shows a critical degradation of CNT emitters caused by the organic binder. Such kinds of problems induce a short lifetime of the CNT field emitters which may limit their practical applications. Therefore, a robust CNT emitter which has the strong mechanical adhesion and no degradation is still a great challenge. Here, we introduce a simple and effective technique for fabrication of CNT field emitter, namely filtration-taping-transfer method. The CNT emitters fabricated by the filtration-taping-transfer method show the low turn-on electric fields, the high emission current, good uniformity and good stability. The enhanced emission performance of the CNT emitters is mainly attributed to high emission sites on the emitter area, and to good ohmic contact and strong mechanical adhesion between the emitters and cathodes. The CNT emitters using a simple and effective fabrication method can be applied for various field emission applications such as field emission displays, lamps, e-beam sources, and x-ray sources. The detail fabrication process will be covered at the poster.

• Current Optics and Photonics
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• 제6권4호
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• pp.367-374
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• 2022

A photodetector based on a reduced graphene oxide (RGO)/n-Si heterojunction with high responsivity, detectivity and fast response speed is presented. Here, we put forward a simple vacuum filtration method to prepare RGO film and transfer it onto an n-Si substrate to form an RGO/n-Si heterojunction. The experimental results show that the heterojunction has good rectification characteristics, and the response and recovery time are less than 0.31 s and 0.25 s, respectively. Under 470 nm light conditions at -2 V applied voltage, the responsivity and detectivity of the device are 65 mA/W and 4.02 × 10¹⁰ cmHz^1/2W^-1, respectively. The simple preparation process and good performance of the RGO/n-Si heterojunction make it a promising material for photoelectric detection, especially in the near-ultraviolet band.

• Composites Research
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• 제29권5호
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• pp.269-275
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• 2016

Multiscale hybrid composites, which consist of polymeric resins, microscale fibers and nanoscale reinforcements, have drawn significant attention in the field of advanced, high-performance materials. Despite their advantages, multiscale hybrid composites show challenges associated with nanomaterial dispersion, viscosity, interfacial bonding and load transfer, and orientation control. In this paper, carbon nanotube(CNT)/carbon fiber(CF)/polycarbonate(PC) multiscale hybrid composite were fabricated by a solution process to overcome the difficulties associated with controlling the melt viscosity of thermoplastic resins. The dependence of CNT loading was studied by varying the method to add CNTs, i.e., impregnation of CF with CNT/PC/solvent solution and impregnation of CNT-coated CF with PC/solvent solution. In addition, hybrid composites were fabricated through surfactant-aided CNT dispersion followed by vacuum filtration. The morphologies of the surfaces of hybrid composites, as analyzed by scanning electron microscopy, revealed the quality of PC impregnation depends on the processing method. Dynamic mechanical analysis was performed to evaluate their mechanical performance. It was analyzed that if the position of the value of tan ${\delta}$ is closer to the ideal line, the adhesion between polymer and carbon fiber is stronger. The effect of mechanical interlocking has a great influence on the dynamic mechanical properties of the composites with CNT-coated CF, which indicates that coating CF with CNTs is a suitable method to fabricate CNT/CF/PC hybrid composites.

• Bulletin of the Korean Chemical Society
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• 제35권7호
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• pp.1973-1978
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• 2014

Here, we present a facile method to synthesize Pt nanoparticles (NPs) and graphene composite materials (Pt/G) via vacuum filtration. Anodic aluminum oxide (AAO) templates were used to separate Pt/G composite and liquid phase. This method can be used to easily tune the mass ratio of Pt NPs and graphene. Pt NPs, graphene, and carbon nanotubes (CNTs) as building blocks were characterized by a variety of techniques such as scanning electron microscopy, UV-Vis spectroscopy, and Raman spectroscopy. We compared the electrocatalytic activities of Pt/G with Pt NP and CNT films (Pt/CNT) by cyclic voltammetry (CV), CO oxidation, and methanol oxidation. Pt/G was much more stable than pure Pt films. Also, Pt/G had better electrochemical activity, CO tolerance and methanol oxidation than Pt/CNT loaded with the same amount of Pt NPs due to the better dispersion of Pt NPs on graphene flakes without aggregation. We further synthesized Au@Pt disk/G and Pt nanorods/G to determine if our synthetic method can be applied to other NP shapes such as nanodisks and nanorods, for further electrocatalysis studies.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2018년도 추계학술논문요약집
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• pp.379-379
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• 2018

MXenes are a new family of 2D transition metal carbide nanosheets analogous to graphene (Lv et al., 2017; Sun et al., 2018). Due to the easy availability, hydrophilic behavior, and tunable chemistry of MXenes, their use in applications for environmental pollution remediation such as heavy metal adsorption has recently been explored (Li et al., 2017). In this study, three-dimensional (3D) MXene ($Ti_3C_2T_x$) films with high adsorption capacity, good mechanical strength, and high selectivity for specific radionuclide from aquose solution were successfully fabricated by a polymeric precursor method using vacuum-assisted filtration. The highest removal efficiency on the films was 99.54%, 95.61%, and 82.79% for $Sr^{2+}$, $Co^{2+}$, and $Cs^+$, respectively, using a film dosage of 0.06 g/ L in the initial radionuclide solution (each radionuclide concentration = 1 mg/L and pH = 7.0). Especially, the adsorption process reached an equilibrium within 30 min. The expanded interlayer spacing of $Ti_3C_2T_x$ sheets in MXene films showed excellent radionuclide selectivity ($Cs^+$ and/or $Sr^{2+}/Co^{2+}$) (Simon, 2017). Besides, the MXene films was not only able to be easily retrieved from an aqueous solution by filtration after decontamination processes, but also to selectively separate desired target radionuclides in the solutions. Therefore, the newly developed MXene ($Ti_3C_2T_x$) films has a great potential for radionuclide removal from aqueous solution.

• Carbon letters
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• 제20권
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• pp.26-31
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• 2016

In this study, we report a general method for preparation of a one-dimensional (1D) arrangement of Au nanoparticles on single-walled carbon nanotubes (SWNTs) using biologically programmed peptides as structure-guiding 1D templates. The peptides were designed by the combination of glutamic acid (E), glycine (G), and phenylalanine (F) amino acids; peptides efficiently debundled and exfoliated the SWNTs for stability of the dispersion and guided the growth of the array of Au nanoparticles in a controllable manner. Moreover, we demonstrated the superior ability of 1D nanohybrids as flexible, transparent, and conducting materials. The highly stable dispersion of 1D nanohybrids in aqueous solution enabled the fabrication of flexible, transparent, and conductive nanohybrid films using vacuum filtration, resulting in good optical and electrical properties.

• 한국표면공학회지
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• 제57권1호
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• pp.31-37
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• 2024

The surge in demand for lithium is primarily fueled by the expanding electric vehicle market, the necessity for renewable energy storage, and governmental initiatives aimed at achieving carbon neutrality. This study proposes a straightforward method for lithium extraction utilizing cellulose nanofiber (CNF) via a vacuum filtration process. This approach yields a porous CNF film, showcasing its potential utility as a lithium extractor and indicator. Given its abundance and eco-friendly characteristics, cellulose nanofiber (CNF) emerges as a material offering both economic and environmental advantages over traditional lithium extraction techniques. Hence, this research not only contributes to lithium recovery but also presents a sustainable solution to meet the growing demand for lithium in energy storage technologies.

• Korean Chemical Engineering Research
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• 제60권2호
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• pp.184-192
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• 2022

수열합성을 통해 합성한 다공성 NiO는 리튬 폴리설파이드의 용출을 억제하기 위하여 리튬-황 전지의 전극에 사용되었다. 리튬-황 전지의 전극은 경제적이고 간단한 진공 여과 방법을 이용하여 집전체와 바인더가 없는 프리스탠딩 플렉서블 전극으로 제작되었다. 다공성 NiO를 첨가한 S/CNT/NiO 전극은 순수 S/CNT 전극에 비해 125 mA h g^-1 증가한 877 mA h g^-1 (0.2 C)의 초기 방전용량과 200 사이클 후 84% (S/CNT: 66%)의 우수한 용량 유지율을 나타내었다. 이는 방전 과정 중에서 NiO와 리튬 폴리설파이드의 강한 화학적 결합에 의하여 리튬 폴리설파이드의 전해질로 용출되는 것을 억제하여 나타난 결과이다. 또한 S/CNT/NiO 전극의 유연성 테스트를 위해 1.6 × 4 cm²의 파우치셀로 제작하여 폴딩한 상태와 하지 않은 상태에서 모두 620 mA h g^-1의 안정적인 사이클 특성을 나타내었다.