• Title/Summary/Keyword: Vacuum dry

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Synthesis of the Nano-sized SrAl2O4 Phosphors by Wet Processing and its Photoluminescence Properties (SrAl2O4계 축광재료의 습식공정에 의한 나노분말 합성 및 발광특성)

  • Kim, Jung-Sik
    • Journal of the Korean Ceramic Society
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    • v.45 no.8
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    • pp.477-481
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    • 2008
  • $Eu^{2+}$ and $Dy^{3+}$ co-doped strontium aluminate, $SrAl_2O_4$ long phosphorescent phoshor was fabricated and its photoluminescence was characterized. The phosphor, $SrAl_2O_4:Eu^{2+},Dy^{3+}$ was synthesized by a coprecipitation in which metal salts of $Sr(NO_3)_2$, $Al(NO_3)_3{\cdot}9H_2O$, were dissolved in $(NH_4)_2CO_3$ solution with adding $Eu(NO_3)_3{\cdot}5H_2O$ and $Dy(NO_3)_3{\cdot}5H_2O$ as a activator and co-activator, respectively. The coprecipitated products were separated from solution, washed, and dried in a vacuum dry oven. The dried powders were then mixed with 3 wt% $B_2O_3$ as a flux and heated at $800{\sim}1400^{\circ}C$ for 3 h under the reducing ambient atmosphere of 95%Ar+$5%H_2$ gases. For the synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$, properties of photoluminescence such as emission, excitation and decay time were examined. The emission intensity increased as the annealing temperature increased and showed a maximum peak intensity at 510 nm with a broad band from $400{\sim}650\;nm$. Monitored at 520 nm, the excitation spectrum showed a maximum peak intensity at $315{\sim}320\;nm$ wavelength with a broad band from $200{\sim}500\;nm$ wavelength. The decay time of $SrAl_2O_4:Eu^{2+},Dy^{3+}$ increased as the annealing temperature increased.

Microscopic Investigation on the Micro-Deformation of Draped Helmet Structure Made of fabric Composite (직물 복합재료를 이용한 드레이핑 헬멧의 미소 변형 관찰)

  • 장승한
    • Composites Research
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    • v.16 no.4
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    • pp.29-35
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    • 2003
  • In this paper. various tow parameters such as equivalent tow thickness, amplitude of longitudinal tow and tow intervals were investigated and compared with each other by using microscopic observation to find out the exact deformation patterns between both directions of the fabric structure(Longitudinal and Transverse Directions). And those observation results were compared with bias extension. biaxial tests results with dry fabric which has the same tow structure as the draped helmet materials and also compared with prepreg specimen which is cured by autoclave moulding without vacuum and pressure condition. Specimens for the observation were taken from draped helmet which is made of fabric composite(Five Harness Satin Weave). From the observation results, it was found that there are different deformation pattern between tow directions and effect of geometric condition on the deformation of the fabric materials during draping process was verified.

Fabrication and Characterization of Transparent Piezoresistors Using Carbon Nanotube Film (탄소나노튜브 필름을 이용한 투명 압저항체의 제작 및 특성 연구)

  • Lee, Kang-Won;Lee, Jung-A;Lee, Kwang-Cheol;Lee, Seung-Seob
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.12
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    • pp.1857-1863
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    • 2010
  • We present the fabrication and characterization of transparent carbon nanotube film (CNF) piezoresistors. CNFs were fabricated by vacuum filtration methods with 65?92% transmittance and patterned on Au-deposited silicon wafer by photolithography and dry etching. The patterned CNFs were transferred onto poly-dimethysiloxane (PDMS) using the weak adhesion property between the silicon wafer and the Au layer. The transferred CNFs were confirmed to be piezoresistors using the equation of concentrated-force-derived resistance change. The gauge factor of the CNFs was measured to range from 10 to 20 as the resistance of the CNFs increased with applied pressure. In polymer microelectromechanical systems, CNF piezoresistors are the promising materials because of their high sensitivity and low-temperature process.

A Study on the Fracture Behavior of Quartz Glass(II) (석영 유리의 파괴 거동에 관한 연구(II))

  • Choi, Seong-Dae;Cheong, Seon-Hwan;Kwon, Hyun-Kyu;Jeong, Young-Kwan;Hong, Yong-Bae
    • Journal of the Korean Society of Industry Convergence
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    • v.10 no.4
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    • pp.213-219
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    • 2007
  • Glass-to-metal contact should be prevented in the design of any structural glass component. Because glass is extremely brittle and will fracture readily if even a small point load is applied. If the assembly includes a glass component supported by metallic structure, designers should provide a pliable interface of some kind between the two parts. But there happens high demand of glass-to metal contact in semiconductor industries due to adoption of dry cleaning process as one of the good solution to reduce running cost - carry out equipments cleaning with high corrosive and etching gas such as CF4 with keeping process temperature as the same as high service temperature. Therefore the quartz glass have to be received compression by direct contact with metal as the form of weight itself and vacuum pressure and fatigue by vibrations caused by process during the process. In this paper investigation will be carried out on fracture behavior of quartz glass contacted with metal directly under local load and fatigue given by process vibration with apparatus which can give $lox{\backslash}cal$ load and vibration through PZT ceramics to give guideline to prevent unintended fracture of quartz glass.

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Study on the response surface optimization of online upgrading of bio-oil with MCM-41 and catalyst durability analysis

  • Liu, Sha;Cai, Yi-xi;Fan, Yong-sheng;Li, Xiao-hua;Wang, Jia-jun
    • Environmental Engineering Research
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    • v.22 no.1
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    • pp.19-30
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    • 2017
  • Direct catalysis of vapors from vacuum pyrolysis of biomass was performed on MCM-41 to investigate the effects of operating parameters including catalyzing temperature, catalyzing bed height and system pressure on the organic yields. Optimization of organic phase yield was further conducted by employing response surface methodology. The statistical analysis showed that operating parameters have significant effects on the organic phase yield. The organic phase yield first increases and then decreases as catalyzing temperature and catalyzing bed height increase, and decreases as system pressure increases. The optimal conditions for the maximum organic phase yield were obtained at catalyzing temperature of $502.7^{\circ}C$, catalyzing bed height of 2.74 cm and system pressure of 6.83 kPa, the organic phase yield amounts to 15.84% which is quite close to the predicted value 16.19%. The H/C, O/C molar ratios (dry basis), density, pH value, kinematic viscosity and high heat value of the organic phase obtained at optimal conditions were 1.287, 0.174, $0.98g/cm^3$, 5.12, $5.87mm^2/s$ and 33.08 MJ/kg, respectively. Organic product compositions were examined using gas chromatography/mass spectrometry and the analysis showed that the content of oxygenated aromatics in organic phase had decreased and hydrocarbons had increased, and the hydrocarbons in organic phase were mainly aliphatic hydrocarbons. Besides, thermo-gravimetric analysis of the MCM-41 zeolite was conducted within air atmosphere and the results showed that when the catalyst continuously works over 100 min, the index of physicochemical properties of bio-oil decreases gradually from 1.15 to 0.45, suggesting that the refined bio-oil significantly deteriorates. Meanwhile, the coke deposition of catalyst increases from 4.97% to 14.81%, which suggests that the catalytic activity significantly decreases till the catalyst completely looses its activity.

Performance Evaluation of Soil Vapor Extraction Using Prefabricated Vertical Drain System (연직배수시스템을 이용한 토양증기추출공법의 성능 평가)

  • Shin, Eun-Chul;Park, Jeong-Jun
    • Journal of Soil and Groundwater Environment
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    • v.12 no.5
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    • pp.9-18
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    • 2007
  • Soil vapor extraction (SVE) is an effective and cost efficient method of removing volatile organic compounds (VOCs) and petroleum hydrocarbons from unsaturated soils. However, soil vapor extraction becomes ineffective in soils with low gas permeability, for example soils with air permeabilities less than 1 Darcy. Incorporating PVDs in an SVE system can extend the effectiveness of SVE to lower permeability soils by shortening the air flow-paths and ultimately expediting contaminant removal. The objective of the research described herein was to effectively incorporate PVDs into a SVE remediation system. The test results show that the gas permeability was evaluated for four different equivalent diameters, increasing the equivalent diameter results in a decrease in the calculated gas permeability. It was found that the porosity for the dry condition was greater than that of the wet condition and will allow flow rate for the same vacuum flow, offering a low resistance to the air flow.

Analysis and the Conservation Treatment of the Paper Relics of the Seonwon Temple Area (선원사지(禪源寺地)출토 지류 유물의 분석 및 보존 처리 방법)

  • Lim, Ju-Hee;Park, Chi-sun
    • Journal of Conservation Science
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    • v.12 no.1 s.15
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    • pp.71-82
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    • 2003
  • The paper relics excavated from the 4th excavation of the historical spot No.259 Seonwon temple area were analyzed and conserved. Because these works remained folded, the most important conservation treatment was a separation. This process depended on the state of the works: dry state works were separated using Gore-Tex chamber and the filtrated water, wet state works were separated through vacuum freeze drying method. Analyses of the paper relics performed were examination on the paper to find its distinction, binocular microscope and SEM on fiber, and XRF on character ingredient. This study presumed the times though $C^{14}$ dating of these works. The works were able to be classified through analysis and conservation treatment. This separation made lost part of the works conserve an archetype. This study presented the application of conservation methods on the paper relics which are in the bad condition and obtained information through carbon dating of it.

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Physio-chemical studies on the after-ripening of hot pepper fruits -(Part 2) Changes in hot-taste component- (신미종(辛味種)고추의 추숙(追熟)에 관(關)한 생리화학적(生理化學的) 연구(硏究) -제2보(第2報) 신미성분(辛味成分)의 변화(變化)-)

  • Lee, Sung-Woo
    • Applied Biological Chemistry
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    • v.14 no.1
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    • pp.29-34
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    • 1971
  • Changes in hot-taste component during the after-ripening period of hot pepper fruit were surveyed and summarized as follows; (1) Capsaicinoid contents were steadily increased as the after-ripening proceeded when physiological activity of the sample was suppressed during each stage of the ripening with the vacuum dry freezing. (2) It was assumed by determining phenylalanine contents and activities of phenylalanine ammonialyase to see synthetical process of capsaicin in the metabolic part of vanillylamine that there is a gradual synthesis and accumulation of capsaicin during the after-ripening period. (3) Lignin-like substances, as in the case of capsaicinoid, showed a steady increase during the after-ripening period. (4) The contents of polyphenolic compounds and polyphenol oxidase activity were higher with low temperature treatment.

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The Influence of Combine Crawler Attaching Slurry Spreader on Soil and Growth of Rye (호밀생육과 토양에 미치는 궤도형 분뇨살포기의 영향)

  • Ryoo Jong Won
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.25 no.1
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    • pp.65-70
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    • 2005
  • This study was conducted to investigate the effect of combine crawler attaching slurry spreader on soil and growth of rye. The performance test at actual field was conducted to test for possibility of practical use. Field test of the slurry spreader was operated in upland and paddy field. Experiments was conducted to compare the effects of the soil damage and crop productivity incorporating Pig slurry by two different types of slurry spreader. In this experiment a slurry spreader using crawler of combine have been designed and developed to enhance the operation in small field and reduce e damage of soil structure. but it was not suitable for transference in long distance. Conventional tractor mounted vacuum is not suitable for $71.6\%$ water condition in the small areas of paddy land. But the slurry spreader using crawler could be controlled the working point and moving by crawler in paddy land of small area. The wheels depths of soil in the supplementary application in the rye field was 4.9 m in tractor mounted spreader. but the wheels depth of crawler attaching spreader was 1.6cm. The dry matter yield of rye was reduced by $12\%$ in supplementary application of slurry due to mechanical damage from passage of the tires. This is particularly noticeable at high soil moisture condition in paddy land. It was concluded that the slurry spreader developed in this study could be successfully used for basal and supplementary application of slurry in rye paddy field.

WATER ACTIVITY AND PIGMENT DEGRADATION IN DRIED LAVERS STORED AT ROOM TEMPERATURE (건해태(김) 저장시의 수분활성과 색소분해반응)

  • LEE Kang-Ho;CHOI Ho-Yeon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.6 no.1_2
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    • pp.27-36
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    • 1973
  • The effect of water activity on degradation of pigments in dried lavers, Porphyra tenera Kjellm. was examined when stored at room temperature for fifty days. Chlorophyll pigment was extracted with methanol-petroleum ether mixture solvent(2:1 v/v), partitioned in ether, and analysed spectrophotometrically at 662 nm as chlorophyll a. The degradation products of chlorophyll were isolated on sugar-starch column(85:15 w/w) with n-propanol-petroleum ether solution(1:200 v/v) as a developing solvent. The isolated green colored zones were analysed individually at the wavelengths of 650, 662, and 667 nm as allomerized product, chlorophyll a retained, and pheophytin formed respectively. Carotenoida were also extracted with the methanol mixture solvent, partitioned in ether, and finally redissolved in acetone after the evaporation of ether in a rotary vacuum evaporator. The total carotenoid content was measured as lutein at 450 nm. From the results, it is noted that the rate of chlorophyll degradation reached a minimum at 0.11 to 0.33 water activity while progressively increased at higher moisture levels resulting in rapid conversion of chlorophyll to pheophytin. At lower activity, autocatalysed oxidizing reaction like allomerization seemed prevailing the acid catalysed conversion reaction. The loss of carotenoid pigment was also greatly reduced at the range of 0.22 to 0.34 water activity with much faster oxidative degradation at both higher and extremely lower moisture levels. These two moisture levels indicated above at which the both pigments exhibited maximum stability are considerably higher than the BET monolayer moisture which appeared 7.91 percent on dry basis at Aw=0.10 calculated from the adsorption isothermal data of the sample at $20^{\circ}C$. The rate of pigment loss in heat treated samples at 60 and $100^{\circ}C$ for 2 hours prior to storage somewhat decreased, particularly at higher moisture levels although the final pigment retention was not much stabilized.

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