• 한국환경과학회지
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• 제24권10호
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• pp.1273-1283
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• 2015

In present study, the temporal characteristics of nine selected volatile organic compounds (VOCs), including four alcohol, 2 aldehyde, and 3 ketone compounds, in high-stories urban apartments over a 2-y period were investigated. The indoor VOC concentrations had generally a decreasing trend over the 2-y follow-up period. For examples, the 2E1H indoor concentration decreased from $10.8{\mu}g/m^3$ for the first two months to $5.1{\mu}g/m^3$ for the last two months. In addition, the DCA and ACT indoor concentrations decreased from 5.0 and $14{\mu}g/m^3$ for the first two months to 2.2 and $6.4{\mu}g/m^3$, respectively, for the last two months. The indoor-to outdoor concentration ratios over the 2-y period were much greater than 1, indicating that indoor VOC concentrations were higher than the outdoor VOC concentrations. Similar to those of the individual VOCs, the indoor-to-outdoor concentration ratios of all three VOC groups were higher than 1 over the 2-y follow-up period, suggesting higher indoor concentrations of the three VOC groups than outdoor concentrations. In consistence with the results of VOC indoor concentrations, the VOC emission rates decreased gradually as time passed, due to the decreased VOC emission strengths of indoor sources. Finally, there was an initial sharp decrease in the indoor VOC concentrations followed by a slower decrease, indicating a multi-exponential decay model for the target VOCs, which was demonstrated by comparison of the residuals and the adjusted coefficient of determination associated with the one and two-exponential fits of each data set.

• 한국대기환경학회지
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• 제27권6호
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• pp.772-790
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• 2011

In this paper, we use the HDDM (High-order Decoupled Direct Method)-driven ozone sensitivity to predict change in ozone concentrations in response to domain-wide $NO_x$(Oxides of Nitrogen) and VOC (Volatile Organic Compound) emission controls over the Seoul Metropolitan Area during June 11~19, 2007. In order to validate the applicability of HDDM to $NO_x$ and VOC control scenarios, the HDDM results are compared to Brute Force Method (BFM). For VOC controls, NME (Normalized Mean Error) between BFM and HDDM remains less than 2% until the domain-wide VOC emissions are reduced by 80%. The NME for a 40% reduction in the domain-wide $NO_x$ emissions is less than 5% but increases abruptly after further reductions in the $NO_x$ emissions (i.e., 80% reduction). The results indicates that it may be inaccurate to use ozone sensitivity coefficients estimated at a given base emission condition in predicting ozone after $NO_x$ reductions larger than ~50% of the domain total in the SMA. Therefore, HDDM application on piecewise emissions is desirable to predict ozone response to emission controls with accuracy (i.e., truck emissions rather than the domain total). For computational efficiency, HDDM shows approximately 30% faster than the BFM sensitivity approach.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2005년도 추계학술대회 논문집
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• pp.238-240
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• 2005

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2003년도 춘계학술대회 논문집
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• pp.301-302
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• 2003

대기 중에 존재하는 휘발성유기화합물(VOCs)은 광화학반응을 통해 오존 및 기타 광산화물을 생성하며, 또한 VOCs 물질 자체가 갖는 독성도 물질에 따라 매우 큰 것으로 알려져 있다. 따라서 이와 관련된 많은 연구가 진행되어 왔으며, 이에 대한 규제방안 역시 지속적으로 논의되고 있으나, 이러한 연구 및 정책의 기본 자료인 VOCs의 배출량에 관련된 자료 및 연구가 매우 부실한 실정이다. 특히 소규모 배출원의 경우에는 배출원에서의 VOCs 배출공정이 미국이나 유럽과 같은 선진국과 많은 차이를 나타내고 있다. (중략)

• 한국환경보건학회지
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• 제43권2호
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• pp.95-102
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• 2017

Objectives: This study was conducted to evaluate the emission of VOCs from clothing that had been dry cleaned. Methods: In order to ensure the same conditions, f100% wool scarves were selected as the fabric type. Four identical tests were conducted on the option of either removing the plastic bags which came from the dry cleaning shop or not. The scarf was located inside a closet or room for one or two days. Small chamber tests were conducted to determine the VOC emission characteristics under the same conditions such as temperature, humidity, loading factor, and air exchange rates. Air from the chamber for VOCs was sampled by Tenax TA tube and analyzed by thermal desorption and GC/MSD. Results: Assuming that test represented dry cleaning and consumer's conditions well enough, we can conclude that immediate emissions after the dry cleaning of the scarfs caused elevated levels of TVOC, five VOCs (benzene, toluene, ethylbenzene, xylene, stylene), and decane group compounds. Conclusions: By removing the plastic bags which came from the dry cleaning shop or not, the storage conditions of dry cleaned scarfs by consumers during the storage time periods (one to three days) would be significant for reducing VOC emissions.

• Asian Journal of Atmospheric Environment
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• 제11권1호
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• pp.29-32
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• 2017

Ozone concentration in Tokyo Metropolitan area is one of the most serious issues of the local air quality. Tropospheric ozone is formed by radical reaction including volatile organic compound (VOC) and nitrogen oxides ($NO_x$). Reduction of the emission of reactive VOC is a key to reducing ozone concentrations. VOC is emitted from anthropogenic sources and also from vegetation (biogenic VOC or BVOC). BVOC also forms ozone through $NO_x$ and radical reactions. Especially, in urban area, the BVOC is emitted into the atmosphere with high $NO_x$ concentration. Therefore, trees bordering streets and green spaces in urban area may contribute to tropospheric ozone. On the other hand, not all trees emit BVOC which will produce ozone locally. In this study, BVOC emissions have been investigated (terpenoids: isoprene, monoterpenes, sesquiterpenes) for 29 tree species. Eleven in the 29 species were tree species that did not emit BVOCs. Three in 12 cultivars for future planting (25 %) were found to emit no terpenoid BVOCs. Eight in 17 commonly planted trees (47%) were found to emit no terpenoid BVOC. Lower-emitting species have many advantages for urban planting. Therefore, further investigation is required to find the species which do not emit terpenoid BVOC. Emission of reactive BVOC should be added into guideline for the urban planting to prevent the creation of sources of ozone. It is desirable that species with no reactive BVOC emission are planted along urban streets and green areas in urban areas, such as Tokyo.

• 한국환경과학회지
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• 제20권11호
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• pp.1465-1481
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• 2011

The accuracy of ozone sensitivity coefficients estimated with HDDM (High-order Decoupled Direct Method) can vary depending on the $NO_x$ (Nitrogen Oxides) and VOC (Volatile Organic Compound) conditions. In order to evaluate the applicability of HDDM over the Seoul Metropolitan Area (SMA) during a high ozone episode in 2007 June, we compare BFM (Brute Force Method) and HDDM in terms of the $1^{st}$-order ozone sensitivity coefficient to explain ozone change in response to changes in NOx and VOC emissions, and the $2^{nd}$-order ozone sensitivity coefficient to represent nonlinear response of ozone to the emission changes. BFM and HDDM estimate comparable ozone sensitivity coefficients, exhibiting similar spatial and temporal variations over the SMAduring the episode. NME (Normalized Mean Error) between BFM and HDDM for the episode average $1^{st}$- and $2^{nd}$-order ozone sensitivity coefficients to NOx and VOC emissions are less than 3% and 9%, respectively. For the daily comparison, NME for the $1^{st}$- and $2^{nd}$-order ozone sensitivity coefficients are less than 4% ($R^2$ > 0.96) and 15% ($R^2$ > 0.90), respectively. Under the emission conditions used in this study, two methods show negative episode average $1^{st}$-order ozone sensitivity coefficient to $NO_x$ emissions over the core SMA. The $2^{nd}$-order ozone sensitivity coefficient to $NO_x$ emissions leads ozone to respond muchnonlinear to the reduction in $NO_x$ emissions over Seoul. Nonlinear ozone response to reduction in VOC emissions is mitigated due to the $2^{nd}$-order ozone sensitivity coefficient which is much smaller than the $1^{st}$-order ozone sensitivity coefficient to the emissions in the magnitude.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2006년도 춘계학술대회 논문집
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• pp.475-476
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• 2006

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2009년도 추계학술대회 논문집
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• pp.243-246
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• 2009

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2001년도 추계학술대회 논문집
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• pp.163-164
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• 2001

휘발성유기화합물(VOCs)과 포름알데히드(HCHO)의 발생원은 매우 다양할 뿐만아니라 주변환경과 인체에 미치는 영향이 매우 크다. VOCs와 포름알데히드의 발생원으로는 크게 인위적인 발생원, 자연적인 발생원, 실내에서의 발생원으로 구분할 수 있다. 현대인들의 하루생활 중 80%이상이 실내에서 이루어지고 있어 실내에서의 발생되는 오염물질에 대한 특성파악과 적절한 제어방안이 요구된다. VOCs와 포름알데히드의 발생원중에서 실내에서의 발생원으로는 여러 가지가 있으나, 신축건물과 리모델링에 사용되는 건축자재에서의 방출은 매우 크다고 할 수 있다. (중략)