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Synthesis of Silicon Carbide Whiskers (I) : Reaction Mechanism and Rate-Controlling Reaction (탄화규소 휘스커의 합성(I) : 반응기구의 율속반응)

  • 최헌진;이준근
    • Journal of the Korean Ceramic Society
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    • v.35 no.12
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    • pp.1329-1336
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    • 1998
  • A twt -step carbothermal reduction scheme has been employed for the synthesis of SiC whiskers in an Ar or a H2 atmosphere via vapor-solid two-stage and vapor-liquid-solid growth mechanism respectively. It has been shown that the whisker growth proceed through the following reaction mechanism in an Ar at-mosphere : SiO2(S)+C(s)-SiO(v)+CO(v) SiO(v)3CO(v)=SiC(s)whisker+2CO2(v) 2C(s)+2CO2(v)=4CO(v) the third reaction appears to be the rate-controlling reaction since the overall reaction rates are dominated by the carbon which is participated in this reaction. The whisker growth proceeded through the following reaction mechaism in a H2 atmosphere : SiO2(s)+C(s)=SiO(v)+CO(v) 2C(s)+4H2(v)=2CH4(v) SiO(v)+2CH4(v)=SiC(s)whisker+CO(v)+4H2(v) The first reaction appears to be the rate-controlling reaction since the overall reaction rates are enhanced byincreasing the SiO vapor generation rate.

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Clinical Analysis of 102 Cases of Open Heart Surgery (개심수술 102례 의 임상적 고찰)

  • 김형묵
    • Journal of Chest Surgery
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    • v.14 no.3
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    • pp.235-240
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    • 1981
  • A total of 102 patients who had an Open Heart Surgery from April 1976 to July 1981 were reviewed. 55 paeitnts were congenital heart disease and 47 patients were acquired heart disease. Among SS patients of congenital heart disease, 18 T 0 F, 18 V S D, 8 A S D, and each one case of l\ulcorner 0 R V, Truncus arteriosus, Ebstein anomaly, Single ventricle, P D A, P 5, A S D + P 5, E C D, V 5 D + P D A, A - P window, D C R V were noted respectively. In 47 patients of acquired heart disease and one Ebstein patient, 46 prosthetic values were implanted: 17 had M V R, 4 had A V R, 2 had M V R + A V R, and 4 had M V R + T V R and one T V R. The operative mortality was 8.S% in acquired heart disease and 17% in congenital heart disease. The follow up period was between 6 months and 6 years. There were 3 cases of late mortality in acquired heart disease and one case in congenital heart disease.

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Benzyl Alcohol Oxidation over H5PMo10V2O40 Catalyst Chemically Immobilized on Sulfur-containing Mesoporous Carbon (황이 포함된 중형기공성 탄소에 화학적으로 고정화된 H5PMo10V2O40 촉매 상에서 Benzyl Alcohol 산화반응)

  • Gim, Min Yeong;Kang, Tae Hun;Choi, Jung Ho;Song, In Kyu
    • Korean Chemical Engineering Research
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    • v.54 no.3
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    • pp.419-424
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    • 2016
  • $H_5PMo_{10}V_2O_{40}$ ($PMo_{10}V_2$) catalyst chemically immobilized on sulfur-containing mesoporous carbon (S-MC) was prepared, and it was applied to the benzyl alcohol oxidation reaction. S-MC was synthesized by a templating method using SBA-15 and p-toluenesulfonic acid as a templating agent and a carbon precursor, respectively. S-MC was then modified to have a positive charge, and thus, to provide sites for the immobilization of $PMo_{10}V_2$. By taking advantage of the overall negative charge of $[PMo_{10}V_2O4_{40}]^{5-}$, $PMo_{10}V_2$ catalyst was immobilized on the S-MC support as a charge matching component. It was revealed that $PMo_{10}V_2$ species were finely and molecularly dispersed on the S-MC via chemical immobilization. In the vapor-phase oxidation of benzyl alcohol, $PMo_{10}V_2$/S-MC catalyst showed higher conversion of benzyl alcohol and higher yield for benzaldehyde and benzoic acid than unsupported $PMo_{10}V_2$ catalyst. The enhanced catalytic performance of $PMo_{10}V_2$/S-MC was due to fine dispersion of $PMo_{10}V_2$ species on the S-MC via chemical immobilization.

Site Characterization using Shear-Wave Velocities Inverted from Rayleigh-Wave Dispersion in Wonju, Korea (레일리파 분산을 역산하여 구한 횡파속도를 이용한 원주시의 부지특성)

  • Kim, Chungho;Ali, Abid;Kim, Ki Young
    • Geophysics and Geophysical Exploration
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    • v.17 no.1
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    • pp.11-20
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    • 2014
  • To reveal shear-wave velocities ($v_s$) and site characterization of Wonju, Korea, Rayleigh waves were recorded at 78 sites of lower altitude using 12 to 24 4.5-Hz vertical geophones for 20 days during the period of February to September 2013. Dispersion curves of the Rayleigh waves obtained by the extended spatial autocorrelation method were inverted using the damped least-squares method to derive $v_s$ models. From these 1-D models, the average $v_s$ to a depth of 30 m ($v_s30$), $v_s$ of weathered rocks, depths to these basement rocks, and average $v_s$ of the overburden layer were derived to be $16.3{\pm}0.7m$, $576{\pm}8m/s$, $290{\pm}7m/s$, and $418{\pm}13m/s$, respectively, in the 95% confidence range. To determine adequate proxies for $v_s30$, we computed correlation coefficients of $v_s30$ with topographic slope (r = 0.46) and elevation (r = 0.43). An empirical linear relationship is presented as a combination of individually estimated $v_s30$ with weighting factors of 0.45, 0.45, and 0.1 for topographic slope, elevation, and mapped lithology, respectively. Due to a weak correlation between $v_s30$ obtained from inversion of dispersion curves and the proxy-based estimation (r = 0.50), however, the relatively large error range should be considered for applications of this relationship.

Some Cycle and Star Related Nordhaus-Gaddum Type Relations on Strong Efficient Dominating Sets

  • Murugan, Karthikeyan
    • Kyungpook Mathematical Journal
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    • v.59 no.3
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    • pp.363-375
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    • 2019
  • Let G = (V, E) be a simple graph with p vertices and q edges. A subset S of V (G) is called a strong (weak) efficient dominating set of G if for every $v{\in}V(G)$ we have ${\mid}N_s[v]{\cap}S{\mid}=1$ (resp. ${\mid}N_w[v]{\cap}S{\mid}=1$), where $N_s(v)=\{u{\in}V(G):uv{\in}E(G),\;deg(u){\geq}deg(v)\}$. The minimum cardinality of a strong (weak) efficient dominating set of G is called the strong (weak) efficient domination number of G and is denoted by ${\gamma}_{se}(G)$ (${\gamma}_{we}(G)$). A graph G is strong efficient if there exists a strong efficient dominating set of G. In this paper, some cycle and star related Nordhaus-Gaddum type relations on strong efficient dominating sets and the number of strong efficient dominating sets are studied.

Comparison of Methods Predicting VS30 from Shallow VS Profiles and Suggestion of Optimized Coefficients (얕은 심도 VS주상도를 활용한 VS30 예측 방법론 비교 및 최적 계수 제시)

  • Choi, Inhyeok;Kwak, Dongyoup
    • Journal of the Korean Geotechnical Society
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    • v.36 no.3
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    • pp.15-23
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    • 2020
  • Ground motion models predicting intensity measures on surface use a time-averaged shear wave velocity, VS30, as a key variable simulating site effect. The VS30 can be directly estimated from VS profiles if the profile depth (z) is greater than or equal to 30 m. However, some sites have VS profiles with z < 30 m. In this case VS30 can be predicted using extension models. This study proposes new coefficient sets for existing prediction equations using 297 Korea VS profiles. We have collected VS profiles from KMA and Geoinfo database. Fitting six existing methods to data, we suggest new coefficients for each method and evaluate their performance. It turns out that if z ≥ 15 m, the standard deviation (σ) of residual in log10 is 0.061, which indicates that the estimated VS30 is nearly accurate. If z < 15 m, the σ keeps increasing up to 0.1 for z = 5 m, so we caution the use of models at very low z. Nonetheless, we recommend investigating up to 30 m depth for VS30 calculation if possible.

Some Characterizations of Catenary Rotation Surfaces

  • Kim, Dong-Soo;Kim, Young Ho;Yoon, Dae Won
    • Kyungpook Mathematical Journal
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    • v.57 no.4
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    • pp.667-676
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    • 2017
  • We study the positive $C^1$ function z = f(x, y) defined on the plane ${\mathbb{R}}^2$. For a rectangular domain $[a,b]{\times}[c,d]{\subset}{\mathbb{R}}^2$, we consider the volume V and the surface area S of the graph of z = f(x, y) over the domain. We also denote by (${\bar{x}}_V,\;{\bar{y}}_V,\;{\bar{z}}_V$) and (${\bar{x}}_S,\;{\bar{y}}_S,\;{\bar{z}}_S$) the geometric centroid of the volume under the graph of z = f(x, y) and the centroid of the graph itself defined on the rectangular domain, respectively. In this paper, first we show that among nonconstant $C^2$ functions with isolated singularities, S = kV, $k{\in}{\mathbb{R}}$ characterizes the family of catenary rotation surfaces f(x, y) = k cosh(r/k), $r={\mid}(x,y){\mid}$. Next, we show that one of $({\bar{x}}_S,\;{\bar{y}}_S)=({\bar{x}}_V,\;{\bar{y}}_V)$, $({\bar{x}}_S,\;{\bar{z}}_S)=({\bar{x}}_V,\;2{\bar{z}}_V)$ and $({\bar{y}}_S,\;{\bar{z}}_S)=({\bar{y}}_V,\;2{\bar{z}}_V)$ characterizes the family of catenary rotation surfaces among nonconstant $C^2$ functions with isolated singularities.

A study on SFCL application for 154kV power system interconnection of 345kV S/S in Korean power system (국내 345kV 변전소 하위 154kV 계통 연계지점 SFCL 적용방안에 관한 연구)

  • Lee, Seung-Ryul;Kim, Jong-Yul;Yoon, Jae-Young
    • Proceedings of the KIEE Conference
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    • 2005.11b
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    • pp.340-343
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    • 2005
  • This paper is for studying the feasibility of SFCL application for the interconnection operation of 154kV power systems under 345kV S/S in Korean power system. All Korean 154kV power systems are constructed as loop systems in downtown. However, the present 154kV systems are operated with separated systems around 345kV S/S because of fault current and overload problems. In this study, we investigate the structure and operation of 154kV power system in Seoul and study the feasibility of interconnection operation of 154kV systems under 345kV systmes by applying SFCLs to 154kV bus-tie.

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EXTENDED DIRECTED TRIPLE SYSTEMS WITH A GIVEN AUTOMORPHISM

  • Cho, Chung-Je;Han, Yong-Hyeon
    • Communications of the Korean Mathematical Society
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    • v.19 no.2
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    • pp.355-373
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    • 2004
  • An extended directed triple system of order v, denoted by EDTS(v), is a pair (V, (equation omitted)) where V is a v-set and (equation omitted) is a set of transitive triples of elements of V such that every ordered pair of elements of V is contained in exactly one member of (equation omitted). We obtain a necessary and sufficient condition for the existence of cyclic EDTS(v)s, and when k=1 or 2, we also obtain a necessary and sufficient condition for the existence of k-rotational EDTS(v)s.

A Study on the Stability Control Method of Soft and Polluted Silt Soils (연약한 실트지반과 오염된 실트지반의 안정관리 방법에 관한 연구)

  • Ahn, Jong-Pil;Park, Sang-Bum
    • Journal of the Korean Geotechnical Society
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    • v.24 no.6
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    • pp.5-16
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    • 2008
  • This study investigated the existing theoretical backgrounds in order to examine the stability control method of lateral flow caused by the Plasticity of soils when unsymmetrical surcharge works on polluted soils and then compared and analyzed the results measured through model tests. Ultimate bearing power of ML and $ML_{p1}$ and $ML_{p2}$ obtained at surcharge(q)-settlement$(S_v)$ curve showed similar trends to ultimate bearing power obtained from control chart of deflection $(S_v-Y_m)$ by Tominaga.Hashimoto, that of $S_v-(Y_m/S_v)$ by Matsuo.Kawamura and that of $(q/Y_m)-q$ by Shibata.Sekiguchi and so it is considered that it has no problem in actual applicability. ${S_v-(Y_m/S_v)}$ of control chart of $ML_{p1}$ by Matsuo.Kawamura showed smaller value than ultimate bearing capacity value from surcharge-settlement curve $(q-S_v)$. Expression of ML of fracture baseline at stability control charge by Matsuo Kawamura is ${S_v=3.21exp}\{-0.48(Y_m/S_v)\}$ and expression of $ML_{p1}$ is ${S_v=3.26exp}\{-0.96(Y_m/S_v)\}$ and expression of $ML_{p2}$ is ${S_v=6.33exp}\{-0.45(Y_m/S_v)\}$.