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A Survey of Zearalenone in Beans Using High Performance Liquid Chromatography-Fluorescence Detector (HPLC-FLD) and Ultra Performance Liquid Chromatography Tandem Mass Spectrometry (LC-MS/MS) (HPLC-FLD 및 LC-MS/MS에 의한 두류 중 제랄레논 오염실태 조사)

  • Jang, Mi-Ran;Lee, Chang-Hui;Lee, Hyo-Jeong;Kim, Ji-Yeon;Son, Sang-Hyeok;Sin, Chun-Sik;Kim, So-Hui;Kim, Dae-Byeong
    • Korean Journal of Food Science and Technology
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    • v.40 no.3
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    • pp.354-359
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    • 2008
  • A survey for zearalenone contamination was conducted on 27 soy bean samples, 27 red bean samples, 16 black bean samples, 19 seoritae samples, 14 seomoktae samples, for a total of 127 commercial Korean samples. Zearalenone was quantified by the immunoaffinity column clean-up method with high performance liquid chromatography-fluorescence detection (HPLC-FLD), and was confirmed by liquid chromatography tandem mass spectrometry(LC-MS/MS). The limits of detection and quantification were $2.0{\mu}g/kg$ and $6.0{\mu}g/kg$, respectively. The recovery in the beans ranged from 82.2 to 98.4%. According to HPLC-FLD, zearalenone was detected in 13 samples (10.2% incidence), including 1 soybean and 12 red bean samples. The zearalenone contamination levels were in the range of 8.01${\sim}38.98{\mu}g/kg$. Finally, LC-MS/MS analysis was conducted in the contaminated samples to verify the results of HPLC-FLD. The LC-MS/MS results confirmed the presence of zearalenone in all 13 samples. The contamination level was lower than that of EU, which is below $100{\mu}g/kg$ for raw grains.

Effect of Heat-Treat Methods on the Soluble Calcium Levels in the Commercial Milk Products

  • Yoo, Sung-Ho;Kang, Seung-Bum;Park, Jin-Ho;Lee, Kyung-Sang;Kim, Jin-Man;Yoon, Sung-Sik
    • Food Science of Animal Resources
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    • v.33 no.3
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    • pp.369-376
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    • 2013
  • Milk is well known to be rich in some nutrients such as protein, calcium, phosphorus, and vitamins. In particular, absorption and bioavailability of calcium receive lots of attention because calcium is very little absorbed until it is changed to the ionized form in the intestine. In this study, concentration of the soluble calcium was determined in the commercial bovine milk products, which were processed by different heat-treatment methods for pasteurization. As for general constituents, lactose, fat, protein, and mineral were almost same in the liquid milk products by different processors. Ultrafiltration of the skimmed milk caused little change in the permeate as for lactose content but both fat and protein decreased. pH values ranges from 6.57-6.62 at room temperature and slightly increase after centrifugation, 10,000 g, 10 min. Rennet-coagulation activity was the lowest in the ultra high temperature (UHT-)milk compared to the low temperature long time (LTLT-) and high temperature short time (HTST-)milk products. Each bovine milk products contains 1056.5-1111.3 mg/kg of Ca. The content of sulfhydryl group was the lowest in raw milk compared to the commercial products tested. For the skimmed milks after ultrafiltration with a membrane (Mw cut-off, 3 Kd), soluble Ca in the raw milk was highest at 450.2 mg/kg, followed by LTLT-milk 336.4-345.1 mg/kg, HTST-milk 305.5-313.3 mg/kg, UHT-milk 370.3-380.2 mg/kg in the decreasing order. After secondary ultrafiltration with a membrane (Mw cut-off, 1 kD), total calcium in raw milk had a highest of 444.2 mg/kg, and those in the market milk products. As follow: UHT-milk, 371.3 to 378.2 mg/kg; LTLT-milk, 333.3 to 342.2 mg/kg; HTST-milk 301.9 to 311.2 mg/kg in a decreasing order.

The Effect of the Amount of Polycarboxylate Superplasticizer on the Properties of Ultra-High Performance Fiber-Reinforced Concrete (폴리칼본산계 고성능감수제 사용량이 초고성능 섬유보강 콘크리트의 성질에 미치는 영향)

  • Kang, Su-Tae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.38 no.1
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    • pp.11-18
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    • 2018
  • As the amount of polycarboxylate superplasticizer varied from 1.2% to 3.0% of the mass of binder, the change in the flowability & rheological properties, and strength of UHPFRC was investigated with experiments. The test results presented that the increase in the amount of superplasticizer was effective in improving the flowability up to 1.8%, but addition more than 1.8% was hardly beneficial for enhancing the flowability and rhelogical properties. Compressive strengths with different amounts of superplasticizer showed that the strength with 1.8% was slightly higher than that of 1.2%, but the amount more than 1.8% caused strength reduction, which was higher as the amount increased. The results in flexural strength according to the amount of superplasticizer showed a similar trend with the results in compressive strength. When the effect of compressive strength and fiber distribution characteristics on the flexural strength was analysed separately, it was found that high amount of superplasticizer caused an effect of fiber distribution in addition to the effect of compressive strength on flexural strength. This effect seems to be closely related to the results of flowability or rheological properties.

Alcohol Fermentation of Uncooked Ground Rice with Ultrasonication Process (초음파를 이용한 무증자 분쇄 백미의 알코올 발효)

  • Lee, You-Jin;Kang, Sung-Tae
    • Korean Journal of Food Science and Technology
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    • v.44 no.3
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    • pp.306-311
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    • 2012
  • This study was performed to evaluate the effects on saccharification and alcohol fermentation, according to the size of the ground rice (12, 20, 35 mesh) and ultra sonication process (15, 30, 60, 120 min). After saccharification of the ground rice samples for 3 h at $60^{\circ}C$, sugar content was observed to be high in the order of cooked ground rice (CGR) > ultrasonicated ground rice (UGR) > ground rice (GR), in all sizes of ground rice. Further, higher sugar content was obtained by increasing the time of ultrasonication process. Almost 90% saccharification of CGR ($11.5^{\circ}Bx$) could be reached up to $10.2^{\circ}Bx$ by ultrasonicating 35 mesh ground rice for 120 min. After alcohol fermentation on the 35 mesh saccharified-UGR for 4 days at $25^{\circ}C$, 16.7% alcohol concentration could be obtained, as high as of CGR (17.2%). After 4 days of alcohol fermentation, UGR showed a lower pH and a higher acidity (pH 4.06-4.17, 0.99-1.1%) than CGR (pH 4.27, 0.75%).

Performance Analysis of Noncoherent OOK UWB Transceiver for LR-WPAN (저속 WPAN용 비동기 OOK 방식 UWB 송수신기 성능 분석)

  • Ki Myoungoh;Choi Sungsoo;Oh Hui-Myoung;Kim Kwan-Ho
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.11A
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    • pp.1027-1034
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    • 2005
  • IEEE802.15.4a, which is started to realize the PHY layer including high precision ranging/positioning and low data rate communication functions, requires a simple and low power consumable transceiver architecture. To satisfy this requirements, the simple noncoherent on-off keying (OOK) UWB transceiver with the parallel energy window banks (PEWB) giving high precision signal processing interface is proposed. The flexibility of the proposed system in multipath fading channel environments is acquired with the pulse and bit repetition method. To analyze the bit error rate (BER) performance of this proposed system, a noise model in receiver is derived with commonly used random variable distribution, chi-square. BER of $10^{-5}$ under the line-of-sight (LOS) residential channel is achieved with the integration time of 32 ns and signal to noise ratio (SNR) of 15.3 dB. For the non-line-of-sight (NLOS) outdoor channel, the integration time of 72 ns and SNR of 16.2 dB are needed. The integrated energy to total received energy (IRR) for the best BER performance is about $86\%$.

Effect of Chemical Composition of Nut Material on the Fracture Behavior in Nut Projection Welding of Hot-Stamped Steel Sheet (핫스탬핑강의 너트 프로젝션 용접시 너트 재질이 용접부 파단모드 변화에 미치는 영향)

  • Lim, Sung-Sang;Kim, Young-Tae;Chun, Eun-Joon;Nam, Ki-Sung;Park, Young-Wan;Kim, Jae-Wan;Lee, Sun-Young;Choi, Il-dong;Park, Yeong-Do
    • Journal of Welding and Joining
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    • v.34 no.2
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    • pp.1-10
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    • 2016
  • The use of materials for modern lightweight auto-bodies is becoming more complex than hitherto assemblies. The high strength materials nowadays frequently used for more specific fields such as the front and rear sub frames, seat belts and seats are mounted to the assembled body structure using bolt joints. It is desirable to use nuts attached to the assembled sheets by projection welding to decrease the number of loose parts which improves the quality. In this study, nut projection welding was carried out between a nut of both boron steel and carbon steel and ultra-high strength hot-stamped steel sheets. Then, the joints were characterized by optical and scanning electron microscope. The mechanical properties of the joints were evaluated by microhardness measurements and pullout tests. An indigenously designed sample fixture set-up was used for the pull-out tests to induce a tensile load in the weld. The fractography analysis revealed the dominant interfacial fracture between boron steel nut weld which is related to the shrinkage cavity and small size fusion zone. A non-interfacial fracture was observed in carbon steel nut weld, the lower hardness of HAZ caused the initiation of failure and allowed the pull-out failure which have higher in tensile strengths and superior weldability. Hence, the fracture load and failure mode characteristics can be considered as an indication of the weldability of materials in nut projection welding.

Removal of Metallic Impurity at Interface of Silicon Wafer and Fluorine Etchant (실리콘기판과 불소부식에 표면에서 금속불순물의 제거)

  • Kwack, Kwang-Soo;Yoen, Young-Heum;Choi, Seung-Ok;Jeong, Noh-Hee;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.1
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    • pp.33-40
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    • 1999
  • We used Cu as a representative of metals to be directly adsorbed on the bare Si surface and studied its removal DHF, DHF-$H_2O_2$ and BHF solution. It has been found that Cu ion in DHF adheres on every Si wafer surface that we used in our study (n, p, n+, p+) especially on the n+-Si surface. The DHF-$H_2O_2$ solution is found to be effective in removing metals featuring high electronegativity such as Cu from the p-Si and n-Si wafers. Even when the DHF-$H_2O_2$ solution has Cu ions at the concentration of 1ppm, the solution is found effective in cleaning the wafer. In the case the n+-Si and p+-Si wafers, however, their surfaces get contaminated with Cu When Cu ion of 10ppb remains in the DHF-$H_2O_2$ solution. When BHF is used, Cu in BHF is more likely to contaminate the n+-Si wafer. It is also revealed that the surfactant added to BHF improve wettability onto p-Si, n-Si and p+-Si wafer surface. This effect of the surfactant, however, is not observed on the n+-Si wafer and is increased when it is immersed in the DHF-$H_2O_2$ solution for 10min. The rate of the metallic contamination on the n+-Si wafer is found to be much higher than on the other Si wafers. In order to suppress the metallic contamination on every type of Si surface below 1010atoms/cm2, the metallic concentration in ultra pure water and high-purity DHF which is employed at the final stage of the cleaning process must be lowered below the part per trillion level. The DHF-$H_2O_2$ solution, however, degrades surface roughness on the substrate with the n+ and p+ surfaces. In order to remove metallic impurities on these surfaces, there is no choice at present but to use the $NH_4OH-H_2O_2-H_2O$ and $HCl-H_2O_2-H_2O$ cleaning.

An Evaluation of Flexural Performance of Composite Beam with Ultra High Performance Concrete Deck and Inverted T-Shaped Steel Girder (초고강도 콘크리트 바닥판과 역T형 강재 합성보의 휨 성능 평가)

  • Yoo, Sung-Won;Joh, Chang-Bin;Choi, Kwang-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.1
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    • pp.64-71
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    • 2016
  • In this paper, when the composite beam is made with UHPC deck and steel girder, the steel girder takes the form of the inverted-T shape without top flange because of high strength and stiffness of UHPC deck. There is no evaluation by experiment and analysis about the shear connector behavior on the web of steel girder and flexural behavior of inverted-T shape composite beam. By this reason, this study compares between experiment and analysis by using tension softening model of UHPC on the basis of flexural test results of 16 members considering compressive strength of UHPC, spacing of stud and thickness of deck as variables. The results of tensile strength of UHPC by inverse analysis were 6.57 MPa(in case of 120 MPa) and 9.57 MPa(in case of 150 MPa). In case of the test members with small stud spacing, the results of analysis and test were close clearly, and the test members with thick deck and low UHPC compressive strength also similar, but effects were small. As it compared between analysis and experiment totally, the results of analysis and experiment agree well. So the tension softening model of UHPC is reasonably reflected on the real behavior of composite beam of UHPC.

An effective transform hardware design for real-time HEVC encoder (HEVC 부호기의 실시간처리를 위한 효율적인 변환기 하드웨어 설계)

  • Jo, Heung-seon;Kumi, Fred Adu;Ryoo, Kwang-ki
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2015.10a
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    • pp.416-419
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    • 2015
  • In this paper, we propose an effective design of transform hardware for real-time HEVC(High Efficiency Video Coding) encoder. HEVC encoder determines the transform mode($4{\times}4$, $8{\times}8$, $16{\times}16$, $32{\times}32$) by comparing RDCost. RDCost require a significant amount of computation and time because it is determined by bit-rate and distortion which is computated via transform, quantization, dequantization, and inverse transform. This paper therefore proposes a new method for transform mode determination using sum of transform coefficient. Also, proposed hardware architecture is implemented with multiplexer, recursive adder/subtracter, and shifter only to derive reduction of the computation. Proposed method for transform mode determination results in an increase of 0.096 in BD-PSNR, 0.057 in BD-Bitrate, and decrease of 9.3% in encoding time by comparing HM 10.0. The hardware which is proposed is implemented by 256K logic gates in TSMC 130nm process. Its maximum operation frequency is 200MHz. At 140MHz, the proposed hardware can support 4K Ultra HD video encoding at 60fps in real time.

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The Fabrication of Poly-Si Solar Cells for Low Cost Power Utillity (저가 지상전력을 위한 다결정 실리콘 태양전지 제작)

  • Kim, S.S.;Lim, D.G.;Shim, K.S.;Lee, J.H.;Kim, H.W.;Yi, J.
    • Solar Energy
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    • v.17 no.4
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    • pp.3-11
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    • 1997
  • Because grain boundaries in polycrystalline silicon act as potential barriers and recombination centers for the photo-generated charge carriers, these defects degrade conversion effiency of solar cell. To reduce these effects of grain boundaries, we investigated various influencing factors such as thermal treatment, various grid pattern, selective wet etching for grain boundaries, buried contact metallization along grain boundaries, grid on metallic thin film. Pretreatment above $900^{\circ}C$ in $N_2$ atmosphere, gettering by $POCl_3$ and Al treatment for back surface field contributed to obtain a high quality poly-Si. To prevent carrier losses at the grain boundaries, we carried out surface treatment using Schimmel etchant. This etchant delineated grain boundaries of $10{\mu}m$ depth as well as surface texturing effect. A metal AI diffusion into grain boundaries on rear side reduced back surface recombination effects at grain boundaries. A combination of fine grid with finger spacing of 0.4mm and buried electrode along grain boundaries improved short circuit current density of solar cell. A ultra-thin Chromium layer of 20nm with transmittance of 80% reduced series resistance. This paper focused on the grain boundary effect for terrestrial applications of solar cells with low cost, large area, and high efficiency.

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