• Title/Summary/Keyword: Ultra-high

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Electrochemical Behavior of Nanostructured Fe-Pd Alloy During Electrodeposition on Different Substrates

  • Rezaei, Milad;Haghshenas, Davoud F.;Ghorbani, Mohammad;Dolati, Abolghasem
    • Journal of Electrochemical Science and Technology
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    • v.9 no.3
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    • pp.202-211
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    • 2018
  • In this work, Fe-Pd alloy films have been electrodeposited on different substrates using an electrolyte containing $[Pd(NH_3)_4]^{2+}$ (0.02 M) and $[Fe-Citrate]^{2+}$ (0.2 M). The influences of substrate and overpotential on chemical composition, nucleation and growth kinetics as well as the electrodeposited films morphology have been investigated using energy dispersive X-ray spectroscopy (EDS), current-time transients, scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray diffraction (XRD) patterns. In all substrates - brass, copper and sputtered fluorine doped tin oxide on glass (FTO/glass) - Fe content of the electrodeposited alloys increases by increasing the overpotential. Also the cathodic current efficiency is low due to high rate of $H_2$ co-reduction. Regarding the chronoamperometry current-time transients, it has been demonstrated that the nucleation mechanism is instantaneous with a typical three dimensional (3D) diffusion-controlled growth in the case of brass and copper substrates; while for FTO, the growth mode changes to 3D progressive. At a constant overpotential, the calculated number of active nucleation sites for metallic substrates is much higher than that of FTO/glass; however by increasing the overpotential, the number of active nucleation sites increases. The SEM micrographs as well as the XRD patterns reveal the formation of Fe-Pd alloy thin films with nanostructure arrangement and ultra-fine grains.

NDR Property and Energy Band Diagram of Nitro-Benzene Molecule Using STM (STM에 의한 니트로벤젠 분자의 NDR 특성과 에너지 밴드 구조)

  • Lee, Nam-Suk;Chang, Jeong-Soo;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.139-141
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    • 2005
  • It is possble to study charge transfer property which is caused by height variation because we can see the organic materials barrier height and STM tip by organic materials energy band gap. Here, we investigated the negative differential resistance(NDR) and charge transfer property of self-assembled 4,4-Di(ethynylphenyl)-2'-nitro-1-(thioacetyl)benzene, which has been well known as a conducting molecule. Self-assembly monolayers(SAMs) were prepared on Au(111), which had been thermally deposited onto pre-treatment($H_{2}SO_{4}:H_{2}O_{2}$=3:1) Si. The Au substrate was exposed to a 1 mM/l solution of 1-dodecanethiol in ethanol for 24 hours to form a monolayer. After thorough rinsing the sample, it was exposed to a $0.1{\mu}M/1$ solution of 4,4-Di(ethynylphenyl)-2'-nitro-1-(thioacetyl)benzene in dimethylformamide(DMF) for 30 min and kept in the dark during immersion to avoid photo-oxidation. After the assembly, the samples were removed from the solutions, rinsed thoroughly with methanol, acetone, and $CH_{2}Cl_{2}$, and finally blown dry with $N_2$. Under these conditions, we measured electrical properties of self-assembly monolayers(SAMs) using ultra high vacuum scanning tunneling microscopy(UHV-STM). The applied voltages were from -1.50 V to -1.20 V with 298 K temperature. The vacuum condition is $6{\times}10^{-8}$ Torr. As a result, we found that NDR and charge transfer property by a little change of height when the voltage is applied between STM tip and electrode.

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Type-tested of Accessories for 345kV Oil Filled Cable (345kV OF 케이블용 부속재의 인정시험완료)

  • Lee, S.K.;Choi, S.G.;Kim, K.S.;Lee, K.H.;Jeon, S.I.;Huh, G.D.;Park, W.K.;Choi, M.K.;Lee, S.H.;Kim, S.J.
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.261-264
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    • 1997
  • Joints and terminations for 345kV Oil Filled $1C{\times}2000mm^2$ cable have been developed and tested including BPT (Bellows Pressure Tank) on the bases of various ultra-high voltage technologies. Electrical design was performed by using Finite Element Method. The type test certified by KEPCO (Korea Electric Power Corporation) has been performed as the final stage of development. In order to confirm the reliability of long-term life for 30 years, load cycle test was conducted for 30 days with good result. As the result, the techniques we obtained from this development are applicable to higher voltage level systems (i.e. 765 kV).

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Attenuation of p-dimethylaminoazobenzene initiated genotoxicity and cytotoxicity in mice by the combined treatment of a traditional homeopathic remedy Chelidonium Majus 200C and vitamin-C

  • Biswas, Surjyo Jyoti;Karmakar, Susanta Roy;Khuda-Bukhsh, Anisur Rahman
    • CELLMED
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    • v.2 no.4
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    • pp.35.1-35.11
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    • 2012
  • The homeopathic remedy Chelidonium majus 200C (Chel-200) is traditionally used by homeopathic practitioners in liver ailments arising out of hepatotoxicity. The present investigation was aimed at examining whether vitamin C (L-ascorbic acid or AA), used in both traditional and orthodox medicines, can show better effects when used in combination with Chel-200, in favorably modifying the toxicological effects induced by the chronic feeding of p-dimethylaminoazobenzene (p-DAB, initiator) and phenobarbital (PB, promoter) in mice for 7 days through 120 days to induce hepatotoxicity and liver tumors. Mice were euthanized at 7, 15, 30, 60, 90, and 120 days of carcinogen feeding to assess various cytogenetical, biochemical and histological changes occurring in them. In a placebo controlled study, Chel-200 or the respective placebo (Alcohol-200C or Alc, "vehicle" of homeopathic drug), was orally administered to toxicant-fed mice. Sub-groups of the mice receiving Chel-200 were also fed either AA or an Alc placebo and their individual and conjoint effects were studied against the respective controls, to evaluate if the combination therapy of Chel-200 with AA can be of additional help in the amelioration of the toxicities generated by the toxicants. The combined feeding of Chel-200 and AA appeared to reduce the cytotoxic and genotoxic effects significantly, when compared to either only the Chel-200 or AA fed group. A similar trend was also obtained in the results of scanning and transmission electron microscopic studies of the livers. Experiments in other mammalian models are warranted to confirm if these drugs in combination could be used in palliative care of human patients with liver diseases including cancer.

Estimation on the Emission Reduction of SULEV LPG Vehicles (SULEV LPG 자동차의 배출가스 저감효과 평가)

  • Park, Jun-Hong;Lee, Jong-Tae;Kim, Sun-Moon;Kim, Jeong-Soo;Kang, Dae-Il;Lim, Yun-Sung;Han, Bo-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.1
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    • pp.68-76
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    • 2012
  • SULEV (Super Ultra Low Emission Vehicle) which is one of the emission standards in Fleet Average System introduced to Korea from 2009 is known as the most severe standard to achieve with internal combustion engine. Considering low sales volume of hybrid vehicles in Korea, vehicle manufacturers are required to develop SULEV technologies for conventional gasoline and LPG vehicles to meet the future Fleet Average standard. In this study, the comparison of emissions has been made between SULEV developed and ULEV LPG vehicles mainly produced in this time. To estimate the emission reduction of SULEV vehicles, CVS-75 and NIER test modes have been used. CVS-75 has been used for emission certification of gasoline and LPG vehicles. NIER modes cover various average vehicle speed and reflect Korean real driving patterns better than CVS-75. The test results show that SULEV LPG vehicles have very high potential to reduce $NO_x$ in regulated emissions, $N_2O$ in green house gases and toluene in VOCs. However, SULEV LPG vehicles don't affect much on the reduction of CO and total green house gases.

The Mechanical Effect of Rod Contouring on Rod-Screw System Strength in Spine Fixation

  • Acar, Nihat;Karakasli, Ahmet;Karaarslan, Ahmet A.;Ozcanhan, Mehmet Hilal;Ertem, Fatih;Erduran, Mehmet
    • Journal of Korean Neurosurgical Society
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    • v.59 no.5
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    • pp.425-429
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    • 2016
  • Objective : Rod-screw fixation systems are widely used for spinal instrumentation. Although many biomechanical studies on rod-screw systems have been carried out, but the effects of rod contouring on the construct strength is still not very well defined in the literature. This work examines the mechanical impact of straight, $20^{\circ}$ kyphotic, and $20^{\circ}$ lordotic rod contouring on rod-screw fixation systems, by forming a corpectomy model. Methods : The corpectomy groups were prepared using ultra-high molecular weight polyethylene samples. Non-destructive loads were applied during flexion/extension and torsion testing. Spine-loading conditions were simulated by load subjections of 100 N with a velocity of $5mm\;min^{-1}$, to ensure 8.4-Nm moment. For torsional loading, the corpectomy models were subjected to rotational displacement of $0.5^{\circ}\;s^{-1}$ to an end point of $5.0^{\circ}$, in a torsion testing machine. Results : Under both flexion and extension loading conditions the stiffness values for the lordotic rod-screw system were the highest. Under torsional loading conditions, the lordotic rod-screw system exhibited the highest torsional rigidity. Conclusion : We concluded that the lordotic rod-screw system was the most rigid among the systems tested and the risk of rod and screw failure is much higher in the kyphotic rod-screw systems. Further biomechanical studies should be attempted to compare between different rod kyphotic angles to minimize the kyphotic rod failure rate and to offer a more stable and rigid rod-screw construct models for surgical application in the kyphotic vertebrae.

Development of Quality Control Method for a Novel Herbal Medicine, HPL-1 using UHPLC (UHPLC를 이용한 새로운 한약제제 HPL-1의 품질관리법 개발)

  • Kim, Se-Gun;Lamichhane, Ramakanta;Lee, Kyung-Hee;Jung, Hyun-Ju
    • The Korea Journal of Herbology
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    • v.30 no.3
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    • pp.19-24
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    • 2015
  • Objectives : HPL-1, a novel herbal medicine which is composed of five herbs such as Kalopanacis Cortex, Chaenomelis Fructus, Raphani Semen, Atractylodis Rhizoma and Pulvis Aconiti Tuberis Purificatum, was developed for treatment of osteoarthritis. This study is aimed to develop analytical method for consistent quality control of HPL-1 and validate chromatographic method. Methods : Chromatographic analysis was performed using ultra-high performance liquid chromatography - diode array detector (UHPLC-DAD) equipped with RP-amide column, column oven, and auto sampler. Marker compounds [protocatechuic acid, chlorogenic acid, liriodendrin, 3,5-dicaffeoylquinic acid, ${\beta}$-D-(3-O-sinapoyl)-fructofuranosyl-$\alpha$-D-(6-O-sinapoyl)glucopyranoside and benzoylmesaconine] were separated by step gradient elution of acetonitrile and 0.1% phosphoric acid/water. The method validation was evaluated by quantitative validation parameters of linearity, accuracy, precision, limit of detection (LOD) and limit of quantification (LOQ) according to KFDA guideline.Results : An optimized method for six marker compounds in HPL-1 was established by UHPLC-DAD. The correlation coefficient (R2) with each calibration curve was greater than 0.99. The LOD and LOQ were within the range of 0.008-0.090 and $0.023-0.274{\mu}g/mL$, respectively. The relative standard deviation (RSD) of intra- and inter-day variability were less than 4.0%. The result of recovery test was range from 93.3-106.3% with RSD < 4.0%.Conclusions : These results suggest that the quantitative UHPLC method is precise, accurate, effective for quality evaluation of HPL-1. The method may also contribute to improve quality of crude drug preparations used for treatment of various diseases.

A COMPARATIVE STUDY OF ROENTGENOGRAPHIC APPEARANCE OF PERIODONTAL OSSEOUS LESIONS (치조병소에 대한 X-선학적 비교연구)

  • Khim Jhai Dhuck
    • Journal of Korean Academy of Oral and Maxillofacial Radiology
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    • v.10 no.1
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    • pp.63-68
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    • 1980
  • The purpose of this article is to re-examine the roentgenographic appearance of alveolar osseous in an effort to determine the value of the orthopantomogram in the diagnosis of periodontal disease. A total of 158 osseous lesions from 13 human dry skulls were studied. 14 Ultra-speed periapical films, 2 bitewing films and Kodak panoramic film are used to obtain radiographs of all defects. The bisecting technic was used, with a target-film distance of. 8 inches and exposure factors of 70 kVp, 10MA and 0.4 sec. at anterior teeth, 0.6 see at posterior teeth in exposure time. For orthopantomogram, Panoura Eight-C was used with a exposure factors of 90kVp, 10MA. and 15sec. exposure time. All films were developed in a light. tight darkroom at 68°F for 4½ minutes. Comparison of orthopantomogram and intraoral films on the view-box was carefully studied in relation to the types of osseous defect visually evident; Proximal intraosseous defects, Interproximal craters, Interproximal hemisepta, Furcal defects on multirooted teeth, and Facial or Lingual one-walled defects. The results obtained were as follows; 1. Proximal osseous defects throughout the dental arches and furcal defects on facial and lingual surfaces of multirooted teeth can be identified with a high degree of accuracy from their orthopantomographic appearances. 2. Lesions on facial or lingual surface of the alveolar arches are rather difficult to locate or recognize on the dental radiographs. 3. In determining whether the proximal and furcal lesions are located facially or lingually, Orthopantomogram is superior to the conventional film Orthopantomogram obtained with standardization of head in proper position revealed the complete visualization of alveolar bone without showing occlusal surface of molars and proximal superimposition of teeth. Thus, on the standardized orthopantomograms, The roentgenographic characteristics of each defect were determined.

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Dispersion-managed Optical Transmission Links with the Random Distributed SMF Lengths (SMF 길이가 랜덤하게 분포하는 분산 제어 광전송 링크)

  • Lee, Young-Kyo
    • Journal of Advanced Navigation Technology
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    • v.22 no.5
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    • pp.462-466
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    • 2018
  • Optical phase conjugation combining with dispersion management (DM) is promising technique to compensate for signal distortion due to chromatic dispersion and nonlinear Kerr effects of single mode fiber (SMF) in optical communication systems. However the fixed SMF length in every fiber spans usually used in the optical links with optical phase conjugator(OPC) and DM restricts the flexible link configuration. The goal of this paper is to investigate the possibility of the flexible configurations of the ultra-high and long-haul optical transmission systems by using the random distribution of SMF length of each fiber spans consisted of the optical link. It is confirmed that the excellent compensation for the distorted wavelength division multiplexing signals in the optical links with the randomly distribution is obtained in case of the shorter averaged SMF length over all fiber spans. It is also confirmed that the control method of net residual dispersion suitable to good compensation is postcompensation and the extent of net residual dispersion(NRD) is -10 ps/nm in DM optical link consisted of fiber spans with the randomly distributed SMF lengths.

The Design and Implementation of S/W Packet Modem based on Frequency Hopping Legacy Radio System (재래식 주파수도약 통신장비용 S/W 패킷모뎀 개발 및 적용에 관한 연구)

  • Koo, Jung;Pyo, Sang-Ho;Kang, Kyeong-Sung;Kim, Ki-Hyung
    • Journal of the Korea Institute of Military Science and Technology
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    • v.14 no.2
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    • pp.222-231
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    • 2011
  • In this paper, we have proposed a method which can make it possible to stably transmit and receive data like the ARC-164 radio frequency hopping environment as a S/W packet modem with PSK modulation. This is a method that the S/W packet modem with PSK digital modulation and the use of PC sound cards change over from data to voice signals and then transmit/receive data. We confirmed not only that it is possible to solve the slow speed communication with the use of sending data through multi-channels and PSK modulation that has the ability to methodically improve transmission rates, but also that it is possible to send the state of frequency hopping stably. In conclusion, we've confirmed both tactical values that though the transmission rate may be a tad slow, a state of frequency hopping of more than 94% confidence plus voice and data can be sent via radio at the same time. In this paper, the proposed S/W packet modem is only an implemented S/W component, so when we apply it to aircraft that we don't consider EMC problems with, then we have the advantage of a wider use of conventional UHF/VHF/HF radio that is possible to voice communication. If we recognize these operational requirements, we can apply for a lot of field equipment efficiently.