Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Electrochemical Behavior of Nanostructured Fe-Pd Alloy During Electrodeposition on Different Substrates

  • Rezaei, Milad (Department of Mining & Metallurgical Engineering, Amirkabir University of Technology) ;
  • Haghshenas, Davoud F. (Department of Mining & Metallurgical Engineering, Amirkabir University of Technology) ;
  • Ghorbani, Mohammad (Department of Materials Science and Engineering, Sharif University of Technology) ;
  • Dolati, Abolghasem (Department of Materials Science and Engineering, Sharif University of Technology)
  • Received : 2018.04.05
  • Accepted : 2018.05.23
  • Published : 2018.09.30
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Abstract

In this work, Fe-Pd alloy films have been electrodeposited on different substrates using an electrolyte containing $[Pd(NH_3)_4]^{2+}$ (0.02 M) and $[Fe-Citrate]^{2+}$ (0.2 M). The influences of substrate and overpotential on chemical composition, nucleation and growth kinetics as well as the electrodeposited films morphology have been investigated using energy dispersive X-ray spectroscopy (EDS), current-time transients, scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray diffraction (XRD) patterns. In all substrates - brass, copper and sputtered fluorine doped tin oxide on glass (FTO/glass) - Fe content of the electrodeposited alloys increases by increasing the overpotential. Also the cathodic current efficiency is low due to high rate of $H_2$ co-reduction. Regarding the chronoamperometry current-time transients, it has been demonstrated that the nucleation mechanism is instantaneous with a typical three dimensional (3D) diffusion-controlled growth in the case of brass and copper substrates; while for FTO, the growth mode changes to 3D progressive. At a constant overpotential, the calculated number of active nucleation sites for metallic substrates is much higher than that of FTO/glass; however by increasing the overpotential, the number of active nucleation sites increases. The SEM micrographs as well as the XRD patterns reveal the formation of Fe-Pd alloy thin films with nanostructure arrangement and ultra-fine grains.

Keywords

References

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