• 제목/요약/키워드: UV-protection

검색결과 288건 처리시간 0.027초

이온빔을 이용한 고분자 대전방지 처리 양산기술 개발 (Development of Polymer Film Mass Production by ion Beam Implantation)

  • 길재근;이찬영;손창원;이재형
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.1138-1141
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    • 2004
  • 고분자 재료에 이온을 주입하면 표면전기저항이 이온주입조건에 따라 $10^{16}\Omega/sq$ 에서 $10^7\Omega/sq$ 까지 변하게 되며, 광학적 특성도 변하게 된다. 이는 산업적으로 대전방지 등에 적용이 가능하며 이러한 신소재 개발을 위하여 산업용 이온빔 표면처리 장치를 제작하고 인출광학을 기초로 이온빔을 제어하여 고분자 재료의 이온주입처리 양산기술을 개발하였다. 본 연구에서는 대면적, 대전류 이온빔 인출을 위한 이온원의 광학적 설계 및 빔라인에서의 솔레노이드 전자석을 이용한 빔프로파일 제어방법을 설명하였다. 사용된 고분자 소재는 PC(PolyCarbonate) 및 PET(PolyEthylene Teraphthalate)이며, 질소이온주입조건은 이온에너지 40-50 keV, 이온주입량 $5\times10^{15}$, $1\times10^{16}$, $7\times10^{16}ions/cm^2$의 조건으로 공정을 수행하였다. 또한 대전방지용 고분자 대량생산을 위한 연속 생산조건과 양산공정조건에 따른 표면전기저항변화를 관찰하였다.

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코치닐을 활용한 우피의 천연염색 (Natural dyeing of cow leather with cochineal)

  • 김상률
    • 복식문화연구
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    • 제24권6호
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    • pp.817-824
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    • 2016
  • The introduction of natural dyes into modern dye houses is very promising green chemistry concept that should be popularized more to reduce the dependency of leather dyeing on some toxic and non-biodegradable synthetic dyes. In this study, the properties of dyeing of cochineal on cow leather were evaluated. The proper dyeing conditions were identified with dye uptake (K/S values) depending on the colorant concentration, dyeing duration, dyeing temperature, and dye bath pH. For the proper mordanting conditions, color changes for different mordants were observed as $La^{*}b^{*}$ and H V/C values. Color fastness (light, rubbing, and dry cleaning) was also examined. Additionally, antibacterial properties and UV protection were examined. The results were as follows: The optimized dyeing conditions were 300% o.w.f., $40^{\circ}C$, 40 min., and pH 5. The cow leather color was red in the absence of mordanting, while it was red purple after being mordanted with Al and Cu, and purple mordanted with Fe. The K/S value of cow leathers increased in the order of the dyeing using $AlK(SO_4)_2$ > $CuSO_4$ > $FeSO_4$. The colorfastness to light and rubbing were reduced compared to original (untreated) cow leather. However dry cleaning fastness was very satisfactory, with a 4~5 rating. The dyed and pre-mordanting dyed cow leather showed excellent antibacterial properties.

Characterization of Antibiotic Substance Produced by Serratia plymuthica A21-4 and the Biological Control Activity against Pepper Phytophthora Blight

  • Shen, Shun-Shan;Piao, Feng-Zhi;Lee, Byong-Won;Park, Chang-Seuk
    • The Plant Pathology Journal
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    • 제23권3호
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    • pp.180-186
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    • 2007
  • The biocontrol agent, Serratia plymuthica A21-4, has been developed for controlling pepper Phytophthora blight. Serratia plymuthica A21-4 strongly inhibits the mycelial growth, zoospore formation, and cyst germination of Phytophthora capsici in vitro. The application of a cell suspension of strain A21-4 to pepper plants in pot experiments and in greenhouse successfully controlled the disease. The bacteria produced a potent antifungal substance which was a key factor in the suppression of Phytophthora capsici. The most active chemical com-pound was isolated and purified by antifungal activity-guided fractionation. The chemical structure was identified as a chlorinated macrolide $(C_{23}H_{31}O_8Cl)$ by spectroscopic (UV, IR, MS, and NMR) data, and was named macrocyclic lactone A21-4. The active compound significantly inhibited the formation of zoosporangia and zoospore and germination of cyst of P. capsici at concentrations lower than $0.0625{\mu}g/ml$. The effective concentrations of the macrocyclic lactone A21-4 for $ED_{50}$ of mycelial growth inhibition were $0.25{\mu}g/ml,\;0.25{\mu}g/ml,\;0.30{\mu}g/ml \;and\;0.75{\mu}g/ml$ against P. capsici, Pythium ultimum, Sclerotinia sclerotiorum and Botrytis cinerea, respectively.

불꽃 감지기에서 오동작 방지에 관한 연구 (A Study on the protection of false alarm in the UV/IR flame detector)

  • 임병현;박성진;임종연;황종선;김영민
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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    • pp.209-212
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    • 2001
  • A flame detector responds either to radiant energy visible to the human eye or outside the range of human vision. Such a detector is sensitive to glowing embers, coals, or flames which radiate energy of sufficient intensity and spectral quality to actuate the alarm. An infra-red detectors can respond to the total IR component of the flame alone or in combination with flame flicker in the frequency range of 5 to 30 Hz. A major problem in the use of infrared detectors receiving total IR radiation is the possible interference of solar radiation in the infrared region. When detectors are located in places shielded from the sun, such as vaults, filtering or shielding the unit from the sun's rays is unnecessary. In this study, we proposed method for redue a false alarm with using filtering & sensor technology for distinguish of causes of raise a false alarm and pure flame.

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Synthesis of New Uraci1-5-Sulphonamide-p-Phenyl Derivatives and Their Effect on Biomphalaria alexandrina Snail's Nucleoproteins

  • Fathalla, O.A.;Gad, H.S.M.;Maghaby, A.S.
    • Archives of Pharmacal Research
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    • 제23권2호
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    • pp.128-138
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    • 2000
  • In continuation of the previous work (Fathalla, 1992) on the synthesis of some heterocycles containing uracil moiety, we report herein the incorporation of uracil moiety into cyan-opyridine thione, thiosemecarbazone, semicarbazone, cyanopyridine, ami nocyano pyridine, isoxazoline, pyrazoline, pyrimidine, triazolo pyrimidine, pyran, selena and thiazole derivatives which might modify their biological activities. The biological studies revealed that the chemical compound III f showed high molluscicdal activity than other compounds. The profile of the nucleoprotein extracted from chemically (compound IIIc, e, f and g) treated or UV-irradiated B.alexandrina snails did not show appreciable differences when compared to non-treated (native) snails by using SDS-PAGE, where no obvious qualitative or quantitative differences were observed. Immunization of experimental animals with the nucleoprotein extracted from native, chemically (compound III f & g) treated or physically treated B.alexandrina snails induced significant protection against challenge with normal S.mansoni cercariae, as compared to the non-immunized challenged control. As well as , a decrease in the number of granuloma formation and the size range of granuloma was also observed in immunized animals. It is concluded that, compounds III f and g have a potent molluscicidal activity. They also induced chemical modification comparable to that induced by physical treatment in the snail's nucleoprotein, which could possibly be used in immunization against S. mansoni infection.

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Preparation and Characterization of pH-Sensitive Poly(ethylene oxide) Grafted Methacrylic Acid and Acrylic Acid Hydrogels by ${\gamma}-ray $ Irradiation

  • Lim, Youn-Mook;Lee, Young-Moo;Nho, Young-Chang
    • Macromolecular Research
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    • 제13권4호
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    • pp.327-333
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    • 2005
  • pH-sensitive hydrogels were studied as a drug carrier for the protection of insulin from the acidic environment of the stomach before releasing it in the small intestine. In this study, hydrogels based on poly(ethylene oxide) (PEO) networks grafted with methacrylic acid (MAA) or acrylic acid (AAc) were prepared via a two-step process. PEO hydrogels were prepared by ${\gamma}-ray $ irradiation (radiation dose: 50 kGy, dose rate: 7.66 kGy/h), grafted by either MAA or AAc monomers onto the PEO hydrogels and finally underwent irradiation (radiation dose: 520 kGy, dose rate: 2.15 kGy/h). These grafted hydrogels showed a pH-sensitive swelling behavior. The grafted hydrogels were used as a carrier for the drug delivery systems for the controlled release of insulin. Drug-loaded hydrogels were placed in simulated gastric fluid (SGF, pH 1.2) for 2 hr and then in simulated intestinal fluid (SIF, pH 6.8). The in vitro drug release behaviors of these hydrogels were examined by quantification analysis with a UV-Vis spectrophotometer.

자외선 차단 제품의 SPF 측정과 안전성 (SPF Evaluation and Safety of Sunscreen Products)

  • 김종일;이병곤;고재숙
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 1992년도 자외선 차단 화장품의 SPF에 관한 심포지움(대한화장품학회)
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    • pp.5-26
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    • 1992
  • Many methods of in vitro SPF evaluation have been developed in order to measure SPF of sunscreen products. In this study, we compared two spectrophotometric in vitro measurements using the skin cast made of Luviset CAP- $X^{R}$ resin and Transpor $e^{R}$ tape as substrate with two in vivo measurements using guinea pig and human. And we also observed the radiation reaching on the earth's surface in Seoul for one year and the change of the primary skin irritancy along the change of SPF value. According to the our research, the first, in vivo measurement using guinea pig had the close agreement with SPF measurement using human and showed the tendancy that guinea pig SPF was lower than human SPF. The second, there was the good relationship between in vitro SPF by using Transpor $e^{R}$ tape and in vivo SPF, and it is possible to predict human SPF from Protection Index(PI) by using tape. The third, it is thought that SPE 20 is reasonable value because of UV intensity in Seoul and the primary skin irritancy of higher SPF than 25. So we propose that it is important to distinguish the sunscreen product having higher than approximate 25 from the category of general cosmetics including lower SPF sunscreen product.oduct.

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지붕일체형 PV모듈의 건축특성 및 적용사례 분석연구 (A study on the Architectural Condition and Cases of BIPV-module for Roof)

  • 이응직
    • KIEAE Journal
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    • 제6권3호
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    • pp.49-56
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    • 2006
  • The roof among the outer surfaces of buildings is an optimum place to install PV since it is the best favorable part in the building to be exposed to day light. Especially, in case of module of BIPV for Roof, it should have essentially the functions of both electricity generation and roof-finish as a construction material. The followings are the results of the study which has analyzed the architectural conditions and applications thereof at the job site. -The aesthetic function of BIPV module is very important because the roof, mostly located at the top of the buildings, is easily recognized and affects outer interior design of the building a lot. -The heat proof of BIPV for Roof could affect the energy consumption through the roof having a wide area. -For architectural condition to the weather, the roof has to ensure the stability of the weather, humidity proof, and airtightness to the wind respectively. -For architectural condition of the structure, endurance by physical power such as stability of both combining and fixing and transfer of load should be ensured. -For residents protection, it has also architectural functions to secure for the space and shield ozone, UV and noxious substances. -Through its practical applications, It is already confirmed that there are various types of BIPV modules overseas and its application has been proved successfully.

자외선 차단제의 SPF 지수와 피부자극지수와의 상관성 연구 (Studies on the Correlation between SPF Index and Skin Irritation Index of Sunscreens)

  • 김종원;서수경;최주영;박창원;서경원;김규봉;김광진;김재희;이선희
    • Biomolecules & Therapeutics
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    • 제10권4호
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    • pp.246-252
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    • 2002
  • In recent years, the safety of sunscreens has been challenged based on the reports of their adverse effect on users; dermatitis, allergic contact dermatitis and photo allergic contact dermatitis. The unscientific idea that higher SPF sunsreen is good for health mealeads many users to tend to prefer higher SPF sunscreen. In the toxicological aspect, the need to investigate the safety of sunscreens is steadily increasing. However, there were few studies on the correlation between sun protection factor (SPF) and the safety of sunscreens. The objective of this study was to assess whether there was a correlation between SPF and the safety of sunscreens. We measured in vitro SPF index using homosalate as a standard and examined the toxicity tests such as primary skin irritation tests, ocular irritation test and skin sensitization test. Homosalate (HS), octyl methoxycinnamate (OMC), octyl salicylate (OS), octocrylene (OC) as UVB organic filter and benzophenone-3 (BP3), butyl methoxy dibenzoil methane (BMDM) as UVA organic filter, and titanium dioxide (TD), zinc oxide (ZO) as inorganic filters were used. The skin irritation indexes in rabbits treated with HS, OMC, OS, BP3, and BMDM were significantly increased as SPF indices were increased. Neither ocular irritation in rabbits nor skin sensitization in guinea pigs were increased. It suggests that there might be a good correlation between SPF and the skin irritation indices of organic UV filters and skin irritation might be one of most sensitive index to assess the safety of sunscreens.

Photosensitized Lysis of Egg Lecithin Liposomes by L-Tryptophan and N-Acetylphenylalanyl-L-Tryptophan

  • Cho, Dae-Won;Yoon, Min-Joong
    • Bulletin of the Korean Chemical Society
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    • 제7권1호
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    • pp.78-81
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    • 1986
  • The photosensitized lysis of egg lecithin lipid membranes (liposomes) have been performed to UV-B light (270-320 nm) by L-tryptophan(L-Trp) and its peptide such as N-acetylphenylalanyl-L-tryptophan(NAPT) incorporated in the liposomes(ca. 0.1% by weight) or in the external buffer (0.1-0.3 mM). Requirement of oxygenation suggests that the lysis of liposomes is caused by the photosensitized oxidation of lipids. There was significant protection against lysis photosensitized by Trp in the external buffer by low concentration of ferricyanide (0.8 mM), but there was no effect on the lytic efficiency by $N_3^-$ which is singlet oxygen($^1O_2$) quencher, indicative of an electron transfer mechanism involved in the photosensitization. The small change of the lytic efficiency with increasing pH from 4 to 9 was interpreted by large target theory and subsequently indicates that superoxide($O_2^-$) may be an active intermediate for the oxidation. The efficiency of photosensitization of Trp was higher than that of NAPT under the same experimental condition. The weak lytic efficiency of liposomes photosensitized by NAPT was enhanced by incorporating NAPT in liposomes, but it was again quenched by ${\beta}$-carotene incorporated in the bilayer of liposomes. These results indicate that a portion of liposome lysis may be due to $^1O_2$ formation from the excited NAPT.