• Title/Summary/Keyword: UV-CURABLE

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UV-nanoimprint Patterning Without Residual Layers Using UV-blocking Metal Layer (UV 차단 금속막을 이용한 잔류층이 없는 UV 나노 임프린트 패턴 형성)

  • Moon Kanghun;Shin Subum;Park In-Sung;Lee Heon;Cha Han Sun;Ahn Jinho
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.4 s.37
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    • pp.275-280
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    • 2005
  • We propose a new approach to greatly simplify the fabrication of conventional nanoimprint lithography (NIL) by combined nanoimprint and photolithography (CNP). We introduce a hybrid mask mold (HMM) made from UV transparent material with a UV-blocking Cr metal layer placed on top of the mold protrusions. We used a negative tone photo resist (PR) with higher selectivity to substrate the CNP process instead of the UV curable monomer and thermal plastic polymer that has been commonly used in NIL. Self-assembled monolayer (SAM) on HMM plays a reliable role for pattern transfer when the HMM is separated from the transfer layer. Hydrophilic $SiO_2$ thin film was deposited on all parts of the HMM, which improved the formation of SAM. This $SiO_2$ film made a sub-10nm formation without any pattern damage. In the CNP technique with HMM, the 'residual layer' of the PR was chemically removed by the conventional developing process. Thus, it was possible to simplify the process by eliminating the dry etching process, which was essential in the conventional NIL method.

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Preparation of UV Curable Gel Polymer Electrolytes and Their Electrochemical Properties

  • Oh, Boo-Keun;Jung, Won-Il;Kim, Dong-Won;Rhee, Hee-Woo
    • Bulletin of the Korean Chemical Society
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    • v.23 no.5
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    • pp.683-687
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    • 2002
  • We have investigated the effect of the number of ethylene oxide (EO) units inside poly(ethylene glycol)dimethacrylate (PEGDMA) on the ionic conductivity of its gelled polymer electrolyte, whose content ranges from 50 to 80 wt%. PEGDMA gelled polym er electrolytes, a crosslinked structure, were prepared using simple photo-induced radical polymerization by ultraviolet light. The effect of the number of EO on the ionic conductivity was clearly shown in samples of lower liquid electrolyte content. We have concluded that the ionic conductivity increased in proportion to both the number of EO units and the plasticizer content. We have also studied the electrochemical properties of 13PEGDMA (number of EO units is 13) gelled polymer electrolyte.

Nanopatterning of Proteins Using Composite Nanomold and Self-Assembled Polyelectrolyte Multilayers

  • Kim, Sung-Kyu;Kim, Byung-Gee;Lee, Ji-Hye;Lee, Chang-Soo
    • Macromolecular Research
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    • v.17 no.4
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    • pp.232-239
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    • 2009
  • This paper describes the simple nanopatterning of proteins on polyelectrolyte surfaces using microcontact printing with a nanopatternable, hydrophilic composite nanomold. The composite nanomold was easily fabricated by blending two UV-curable materials composed of Norland Optical Adhesives(NOA) 63 and poly(ethylene glycol) dimethacrylate(PEG-DMA). NOA 63 provided stable nanostructure formation and PEG-DMA induced high wettability of proteins in the nanomold. Using the composite mold and functionalized surface with polyelectrolytes, the fluorescent, isothiocyanate-tagged, bovine serum albumin(FITC-BSA) was successfully patterned with 8 nm height and 500 nm width. To confirm the feasibility of the protein assay on a nanoscale, a glycoprotein-lectin assay was successfully demonstrated as a model system. As expected, the lectins correctly recognized the nano-patterned glycoproteins such as chicken ovalbumin. The simple preparation of composite nanomold and functionalized surface with a universal platform can be applied to various biomolecules such as DNA, proteins, carbohydrates, and other biomolecules on a nanoscale.

Micromolding process using PDMS for refractive microlens (Micromolding process에 의한 refractive microlens의 제작)

  • Ahn, Si-Hong;Lee, Sang-Ho;Kim, Min-Soo;Kim, Yong-Kweon
    • Proceedings of the KIEE Conference
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    • 2000.11c
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    • pp.578-580
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    • 2000
  • Micromolding process에 의한 refractive microlens array를 제작한다. PDMS, UV curable acryl adhesive 등 여러 가지 polymer 재료를 시도한다. 기존의 공장에서 주로 사용되던 etched bulk silicon, electroplated metal 등의 구조물이 아닌, polymer 구조물을 mold로 사용한다. Micromolding process에 의해 제작되는 microlens의 특성은 mold의 험상에 의해 결정된다. Reflow 공정에 의해 제작된 photoresist microlens는 매우 우수한 표면 특성과 형상 대칭성을 보여주므로, microlens의 mold로서 사용하기에 적합하다.

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The study on ON-LINE and OFF-LINE systems of electronic image editing by time-code adressing method (전자 영상 편집에 있어서 time-code adressing 방식에 의한 ON-LINE, OFF-LINE system에 대한 연구)

  • BongJoKim
    • Journal of the Korean Graphic Arts Communication Society
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    • v.13 no.1
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    • pp.93-104
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    • 1995
  • Liquid crystal-polymer composite(LCPC) films promising new materials for both projection displays and vision product. LCPC films consist of a continous liquid crystal phase embedded in a three- dimensional network of polymer matrix. The liquid crystal in these LC phases can be elecrtrically switched giving rise to an opaque scattering off-stats and a transparent, non-scatting on- stats. In this work. a premixture is composed of LC, UV-curable monomer and photonitiator. LCPC films are formed by photopolymerization induced phase separation from this premixture. In conclusion, structure and electro-optical properties of LCPC films strongly depends on the selection of monomer, LC content and curing rate.

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Structures and Electro-optical Properties of Liquid Crystal-Polymer Composite Films (액정-고분자 복합막의 구조와 전기광학특성)

  • 남수용
    • Journal of the Korean Graphic Arts Communication Society
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    • v.13 no.2
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    • pp.19-32
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    • 1995
  • Liquid crystal-polymer composite(LCPC) films are promising new materials for both projection displays and vision products. LCPC films consist of a continuous liquid crystal phase embedded in a three- dimensional network of polymer matrix. The liquid crystal in these LC phases can be electrically switched giving rise to an opaque scattering off-state and a transparent, non- scattering on-state. In this work, a premixture is composed of LC, UV-curable monomer and photonitiator. LCPC films are formed by photopolymerization induced phase separation from this premixture. In conclusion, structure and electro-optical properties of LCPC films strongly depends on the selection of monomer, LC content and curing rate.

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The Recent Tendency of Environmentally-friendly Tackifiers

  • Sakurai, Yoshihiro
    • Journal of Adhesion and Interface
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    • v.8 no.1
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    • pp.28-33
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    • 2007
  • It is a main trend not to use organic solvents in the adhesive industry from the recent environmental and safe points of view. For example, water-based, hot-melt, or UV curable adhesives are being investigated. Several different kinds of tackifiers that are formulated in the adhesives in order to give them more functional properties like initial tack and higher adhesion, etc., have been proposed to meet the recent trend. Firstly, the characteristics and fundamental properties of the respective materials are presented. In Japan, the trend to develop the water-based adhesives is most remarkable. While the environmental regulations are getting harder, Arakawa Chemical has been spending a lot of energy for the research, and developed toluene-free and solvent free tackifier dispersions that are presented precisely.

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Liquid Crystal Lens Array with Thermally Controllable Focal Length and Electrically Convertible Lens Type

  • Heo, Kyong Chan;Kwon, Jin Hyuk;Gwag, Jin Seog
    • Journal of the Optical Society of Korea
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    • v.19 no.1
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    • pp.88-94
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    • 2015
  • This paper reports the fabrication of a lenticular liquid crystal (LC) lens array with thermally tunable focus and with the function of a convertible lens type, using the surface structure of a UV-curable polymer and a twisted-nematic (TN) LC cell. The TN LC cell makes the LC lenticular lens function as a converging or diverging lens by controlling electrically the polarization of input light. Therefore, the focal lengths for both the converging and diverging lenses, which can be switched from the TN cell, can be tuned by changing the effective refractive index of the LC by Joule heating of the transparent electrode. As a result, the focal length of the lens with the E7 LC was changed continuously from 8.7 to 31.2 mm for the converging lens type and from -9.8 to -14.2 mm for the diverging lens when the temperature was increased from 25 to $56^{\circ}C$.

Fabrication of the Outer type-Dynamic Microlens Array using Surface-Stabilized Ferroelectric Liquid Crystal

  • Kim, Young-Wook;Gwag, Jin-Seog;Kim, Kyung-Bae;Kang, Tae-Ho;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.344-347
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    • 2008
  • We fabricated the outer type-dynamic microlens array using a surface-stabilized ferroelectric liquid crystal, UV curable polymer and the stacked liquid crystalline polymer. The outer type-microlens array has a lower driving voltage and fast switching property. It is applicable to a variety of optical systems.

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Improvement of the permeation properties with a thin hybrid - passivation layer to apply the Large-sized Organic Display Devices

  • Lee, Joo-Won;Bea, Sung-Jin;Park, Jung-Soo;Lee, Young-Hoon;Chin, Byung-Doo;Kim, Jai-Kyeong;Jang, Jin;Ju, Byeong-Kwon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1779-1783
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    • 2006
  • The hybrid thin-film (HTF) passivation layer composed of the UV curable acrylate layer and MS-31 (MgO:SiO2=3:1wt%) layer was adopted in organic light emitting diode (OLED) to protect organic light emitting materials from penetrations of oxygen and water vapors. The moisture resistance of the deposited HTF layer was measured by the water vapor transmission rate (WVTR). The results showed that the HTF layer possessed a very low WVTR value of lower than $0.007g/m^2$ per day at $37.8^{\circ}C$ and 100% RH. Therefore, the HTF on the OLED was found to be very effective in protect what from the penetrations of oxygen and moisture.

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