Browse > Article
http://dx.doi.org/10.5012/bkcs.2002.23.5.683

Preparation of UV Curable Gel Polymer Electrolytes and Their Electrochemical Properties  

Oh, Boo-Keun
Jung, Won-Il
Kim, Dong-Won
Rhee, Hee-Woo
Publication Information
Bulletin of the Korean Chemical Society / v.23, no.5, 2002 , pp. 683-687 More about this Journal
Abstract
We have investigated the effect of the number of ethylene oxide (EO) units inside poly(ethylene glycol)dimethacrylate (PEGDMA) on the ionic conductivity of its gelled polymer electrolyte, whose content ranges from 50 to 80 wt%. PEGDMA gelled polym er electrolytes, a crosslinked structure, were prepared using simple photo-induced radical polymerization by ultraviolet light. The effect of the number of EO on the ionic conductivity was clearly shown in samples of lower liquid electrolyte content. We have concluded that the ionic conductivity increased in proportion to both the number of EO units and the plasticizer content. We have also studied the electrochemical properties of 13PEGDMA (number of EO units is 13) gelled polymer electrolyte.
Keywords
Polyethylene glycol dimethacrylate; Ionic conductivity; Chain length of ethylene oxide;
Citations & Related Records

Times Cited By Web Of Science : 6  (Related Records In Web of Science)
Times Cited By SCOPUS : 7
연도 인용수 순위
1 Sun, X. G.; Lin, Y. Q.; Ding, L. M.; Jing, X. B. ElectrochimicaActa 1996, 41(9), 1573.   DOI   ScienceOn
2 Sander, B.; Weinkauf, A.; Reiche, A.; Siury, K.; Tubke, J.;Wartewig, S.; Shashkov, S. Electrochimica Acta 1998, 43(10-11),1263.   DOI   ScienceOn
3 Lee, K.; Kim, K.; Lim, H. S. J. Electrochem. Soc. 2001, 148(10),A1148.   DOI   ScienceOn
4 Sander, B.; Steurich, T.; Wiesner, K.; Bischoff, H. Polym. Bulletin1992, 28, 355.   DOI
5 Huq, R.; Koksbang, R.; Tonder, P. E.; Farrington, G. C. ElectrochimicaActa 1992, 37(9), 1681.   DOI   ScienceOn
6 Lithium ion secondary battery (Japanese Ed.) Materials & Application; THE NIKKAN KOGYO SHIMBUN: Japan, 1996; p. 86.
7 Kim, D. W.; Kim, Y. R.; Sun, Y. K.; Oh, B.; Moon, S. I.; Jin, B. S.Polymer(Korea) 1997, 21(5), 861.
8 Abbrent, S.; Lindgren J.; Tegenfeldt J.; Wendsjo A. ElectrochimicaActa 1998, 43(10-11), 1185.   DOI   ScienceOn
9 Croce, F.; Appetecchi, G. B.; Persi, L.; Scrosati, B. Nature 1988,394, 456.
10 Wright, P. V. Br. Polym. J. 1975, 7, 319.   DOI
11 Huguenin, F.; Cavalcante, M. G.; Torresi, R. M. Solid State Ionics1999, 126, 259.   DOI   ScienceOn
12 Sun, H. Y.; Sohn, H.-J.; Yamamoto, O.; Takeda, Y.; Imanishi, N. J.Electrochem. Soc. 1999, 146(5), 1672.   DOI   ScienceOn
13 Best, A. S.; Ferry, A.; MacFarlane, D. R.; Forsyth, M. Solid StateIonics 1999, 126, 269.   DOI   ScienceOn
14 Frech, R.; Manning, J.; Teeters, D.; Black, B. E. Solid State Ionics1988, 28-30, 954.   DOI   ScienceOn
15 Wolfenson, A. E.; Torresi, R. M.; Bonagamba, T. J.; DePaoli, M.A.; Panepucci, H. Solid State Ionics 1996, 85, 219.   DOI   ScienceOn
16 Reiche, A.; Sander, R.; Weinkauf, A.; Sander, B.; Fleischer, G.;Rittig, F. Polymer 2000, 41, 3821   DOI   ScienceOn
17 Armand, M. Solid State Ionics 1994, 69, 309.   DOI   ScienceOn
18 Wang, Z.; Ikeda, M.; Hirata, N.; Kubo, M.; Itoh, T.; Yamamoto, O.J. Electrochem. Soc. 1999, 146(6), 2209.
19 Watanabe, M.; Itoh, M.; Sanui, K.; Ogata, N. Macromolecules1987, 20, 569.   DOI
20 Itoh, T.; Hirata, N.; Moriya, Y.; Kubo, M.; Yamamoto, O. J.Power Sources 1999, 81-82, 824.   DOI   ScienceOn
21 Wilson, D. J.; Nicholas, C. V.; Mobbs, R. H.; Booth, C. Br. Polym.J. 1990, 22, 129.   DOI   ScienceOn
22 Appetecchi, G. B.; Dautzenberg, G.; Scrosati, B. J. Electrochem.Soc. 1996, 143(1), 6.   DOI
23 Oh, B.; Kim, Y. R. Solid State Ionics 1999, 124, 83.   DOI   ScienceOn
24 Kim, J. Y.; Kim, S. H. Solid State Ionics 1999, 124, 91.   DOI   ScienceOn
25 Gray, F. M. Polymer Electrolytes; The Royal Society of Chemistry: Cambridge, 1997; Chapter 1.
26 Sung, H.-Y.; Wang, Y.-Y.; Wan, C.-C. J. Electrochem. Soc. 1998,145(4), 1207.   DOI   ScienceOn
27 Berthier, C.; Gorecki, W.; Minier, M.; Armand, M.; Chabagno, J.M.; Rigaud, P. Solid State Ionics 1983, 11, 91.   DOI   ScienceOn
28 Croce, F.; Brown, S. D.; Greenbaum, S. G.; Slane, S. M.;Salomon, M. Chem. Mater. 1993, 5, 1268.   DOI   ScienceOn