• 제목/요약/키워드: UV sensitivity

검색결과 230건 처리시간 0.027초

Acid-Sensitivity and Physical Properties of Polymethylmethacrylate and Polyurethane Films Containing Polymeric Styryl Dye

  • Cho, Jae-Whan;Lee, Sun-Hwa;So, Jung-Hyun;Jaung, Jae-Yun;Yoon, Kee-Jong
    • Fibers and Polymers
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    • 제5권3호
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    • pp.239-244
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    • 2004
  • Solution-cast films of polymethylmethacrylate (PMMA) and polyurethane (PU) containing polymeric styryl dye up to 5 % by weight were prepared to investigate their acid-sensitivity and mechanical and thermal properties. Original red samples due to styryl dye turned out yellow very rapidly as they were exposed to acid vapor of hydrochloric acid or p-toluenesulfonic acid. According to UV/VIS spectroscopic measurements, characteristic peak intensities near 430 nm and 520 nm increased or decreased relatively with exposed amounts of acid, respectively. Both PMMA and PU samples showed uniform color distribution due to a good miscibility between polymer and dye which can be evidenced by measurements of glass transition temperature. No significant difference in acid-sensitivity was found between PU and PMMA except relative absorbance. However, dependence of their mechanical properties on dye content was somewhat different with PU or PMMA. In case of PMMA, modulus and breaking stress increased up to about 50 % with increasing dye content, whereas those of PU samples showed only slight increase. It was ascribed to whether the matrix polymer was in the glassy or rubbery state.

UVSC of Aspergillus nidulans is a Functional Homolog of RAD51 in Yeast

  • Yoon, Jin-Ho;Seong, Kye-Yong;Chae, Suhn-Kee;Kang, Hyen-Sam
    • BMB Reports
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    • 제34권5호
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    • pp.428-433
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    • 2001
  • A defect in uvsC of Aspergillus nidulans caused high methyl methansulfonate (MMS)-sensitivity, hyporecombination, and a lack of UV induced mutation. The uvsC gene of Aspergillus nidulans shares a sequence similarity with the RAD51 gene of Saccharomyces cerevisiae. In this study, in vitro and in vivo tests were conducted in order to determine whether or not the UVSC protein had functional similarities to RAD51, the recombination enzyme in yeast. The purified recombinant UVSC protein, following expression in Escherichia coli, showed binding activity to single-stranded DNA (ssDNA), when both ATP and magnesium are present. In addition, ATPase activity was also demonstrated and its activity was stimulated in the presence of ssDNA. The UVSC protein that was expressed under the ADH promoter in S. cerevisiae suppressed in part the sensitivity to MMS of the rad51 null mutant. Similarly, when the uvsC cDNA was expressed from the nmt promoter, the MMS sensitivity of the rhp51 null mutant of Schizosaccharomyces pombe was partially complemented. These results indicate that the A. nidulans UVSC protein is a functional homologue of the RAD51 protein.

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Ultraviolet-B radiation sensitivities in rice plant: cyclobutane pyrimidine dimer photolyase activities and gene mutations

  • Hidema, Jun;Kumagai, Tadashi
    • 한국식물생명공학회:학술대회논문집
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    • 한국식물생명공학회 2004년도 생명공학 실용화를 위한 비젼
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    • pp.29-34
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    • 2004
  • Reduction in stratospheric ozone layer increases the amount of ultraviolet-B radiation (UVB: 280-320 nm) that reaches the earth ’ s surface. UVB radiationcan damage plants, resulting in decrease in growth and productivity. UVB-augmentation studies have indicated that the sensitivity to UVB radiation in plants varies among the species and cultivars. However. there are no definitive answers for the mechanisms of UVB-resistance in higher plants and for bioengineering design and development of UVB-tolerant plants. We have been studying physiological and biochemical aspects of the effects of UVB radiation on growth and yield of rice COryza sativa LJ. aiming to clarify the mechanism of resistance to UVB radiationin rice. At this meeting. weintroduce our research as followed: (1) supplementary UVB radiation has inhibitory effects on the growth. yield and grain development of rice; (2) UVB sensitivity of rice varies widely among cultivars; (3) among Japanese rice cultivars. Sasanishiki. a leading variety in northeast Japan. is more resistant to UVB. while Norin 1. a progenitor of Sasanishiki. is less resistant; (4)UV-sensitive Norin 1 cultivar is deficient in photorepair of UVB-induced cyclobutane pyrimidine dimer (CPD). and this deficiency results from one amino acid residue alteration of CPD photolyase. These results suggest that spontaneously occurring mutation in CPD photolyase gene could lead to difference in UVB sensitivity in rice. and that CPD photolyase might be a useful target for improving UVB-sensitivity in rice by selective breeding or bioengineering of UVB-tolerant rice.

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자외선 및 고에너지 가시광 차단 기능을 갖는 눈 건강을 위한 폴리머 안경렌즈 (Polymer Eyeglass Lens with Ultraviolet & High-Energy Visible Light Blocking Function for Eye Health)

  • 김기출
    • 한국산학기술학회논문지
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    • 제21권12호
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    • pp.10-15
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    • 2020
  • 파장 400 nm 이하의 자외선은 눈 건강에 매우 해롭다. 또한 고에너지 가시광도 망막 세포에 영향을 줄 수 있음이 최근에 밝혀졌다. 따라서 자외선 및 고에너지 가시광 차단 기능의 안경렌즈 개발이 시대적으로 요청되고 있다. 본 연구에서는 m-자일릴렌 디이소시아네이트 모노머와 2,3-bis((2-mercaptoethyl)thio)-1-propanethiol 모노머 및 벤트리아졸 UV 흡수제, 알킬인산에스터 이형제, 안료혼합물(CI solvent violet 13), 이염화부틸주석 촉매제 등의 혼합물을 인젝션 몰드 방법으로 열중합 공정을 적용하여, 굴절률 1.67의 고굴절률 폴리머 안경렌즈를 제조하였다. 제조된 폴리머 안경렌즈의 양면에 전자빔 진공증착 시스템으로 다층 반사방지 코팅을 하였다. 제조된 안경렌즈의 자외선 및 고에너지 가시광 차단 기능을 UV-visible spectrophotometer로 분석하였다. 그 결과 UV 흡수제를 0.5wt% 첨가한 폴리머 안경렌즈가 411 nm 파장 이하의 자외선 및 고에너지 가시광을 99 % 이상 차단하였다. 또한 460 ~ 660 nm 파장의 명소시 시각 민감도 10% 이상의 영역에서 평균 투과율이 97.9%를 나타내어 명소시에서 선명한 상을 얻을 수 있었다.

UV KrF 레이저 공정조건에 따른 FBG 센서의 방사선 영향 (Radiation Effects on Fiber Bragg Grating Sensors Written in UV KrF Laser Process Condition)

  • 김종열;이남호;정현규
    • 한국정보통신학회논문지
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    • 제20권1호
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    • pp.161-166
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    • 2016
  • 본 논문에서는 광섬유 브래그 격자의 공정조건 변화에 따른 $Co^{60}$ 감마방사선 영향을 연구하였다. 광섬유 브래그 격자는 붕소가 첨가된 광민감 광섬유를 이용하여 UV KrF 레이저 세기를 달리하여 제작하였으며, 제작된 광섬유 브래그 격자 센서에 총 선량 33.8 kGy 감마선을 조사하였다. 실험결과를 통하여, 격자 공정을 위한 UV 레이저 세기가 광섬유 브래그 격자의 방사선 민감도에 큰 영향을 줄 수 있다는 것을 확인하였으며, 레이저 공정조건 변화에 따른 방사선에 의한 광섬유 브래그 파장의 변화는 30 % 이상의 차이를 보였다.

VERTICAL OZONE DENSITY PROFILING BY UV RADIOMETER ONBOARD KSR-III

  • Hwang Seung-Hyun;Kim Jhoon;Lee Soo-Jin;Kim Kwang-Soo;Ji Ki-Man;Shin Myung-Ho;Chung Eui-Seung
    • 한국우주과학회:학술대회논문집(한국우주과학회보)
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    • 한국우주과학회 2004년도 한국우주과학회보 제13권2호
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    • pp.372-375
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    • 2004
  • The UV radiometer payload was launched successfully from the west coastal area of Korea Peninsula aboard KSR-III on 28, Nov 2002. KSR-III was the Korean third generation sounding rocket and was developed as intermediate step to larger space launch vehicle with liquid propulsion engine system. UV radiometer onboard KSR-III consists of UV and visible band optical phototubes to measure the direct solar attenuation during rocket ascending phase. For UV detection, 4 channel of sensors were installed in electronics payload section and each channel has 255, 290, 310nm center wavelengths, respectively. 450nm channel was used as reference for correction of the rocket attitude during the flight. Transmission characteristics of all channels were calibrated precisely prior to the flight test at the Optical Lab. in KARI (Korea Aerospace Research Institute). During a total of 231s flight time, the onboard data telemetered to the ground station in real time. The ozone column density was calculated by this telemetry raw data. From the calculated column density, the vertical ozone profile over Korea Peninsula was obtained with sensor calibration data. Our results had reasonable agreements compared with various observations such as ground Umkhr measurement at Yonsei site, ozonesonde at Pohang site, and satellite measurements of HALOE and POAM. The sensitivity analysis of retrieval algorithm for parameters was performed and it was provided that significant error sources of the retrieval algorithm.

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전기철도 전차선로의 설치 상태 판단을 위한 복합검측 기술 구현 (Implementation of Multi-functional Type Condition Monitoring System for Railway Catenary Systems)

  • 박영;이기원;박신영;박준영;최원석
    • 전기학회논문지
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    • 제64권9호
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    • pp.1406-1410
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    • 2015
  • The railway catenary systems consist of a complex structure, electrical and mechanical conditions are exposed to dangerous environment due to current collection between pantograph and catenary systems. These two types of conditions for the catenary systems are critically assessed for management and are becoming increasingly more dependent on reliable inspection system. In this paper, a new measurement system which enables inspection of catenary faults was studied and implemented. The system uses wavelength band of ultraviolet (UV) and IR (Infrared) to measure the insulation of corona and temperature of catenary wire. In order to determine the sensitivity of implemented system, the performance test such as distance detection range of UV camera and temperature resolution of IR camera were conducted, respectively. The field test of development system was also conducted in metro and high-speed line using mobile type UV and IR multi-composited measurement systems.

간접 분광 검출법에 의한 음이온의 분석(I) (Analysis of Anions by Indirect Photometric Detection (I))

  • 박만기;김박광;박정일;김경호;이미영;정재은
    • 약학회지
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    • 제34권3호
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    • pp.215-218
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    • 1990
  • An ion chromatographic method based on indirect photometric detection of UV transparent anions was developed. Separation of anion was accomplished on strong anion exchange column (Waters SAX) using UV detector at 254 nm. Among examined UV-active additives (Dns-H, Dns-glu, Dnsser, Dns-val), Dns-glu showed the highest sensitivity. Studies on the effects of the pH and ionic strength of eluent revealed that the increase of pH and ionic strength of the eluent decreased capacity factor. The best eluent for the separation of acetate, fluoride, chloride, nitrate and bromide was $1\;{\times}\;10^{-4}M$ Dns-glu in 5 mM phosphate buffer (pH 6.30). The detection limit of chloride ion was 2.1 ng in this condition.

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셀레늄 함유 건조효모제제 중 셀레늄 분석방법에 관한 연구 (Determination of Selenium in Dried Yeast Preparations)

  • 오세종;오영택;윤원용;박성배
    • Journal of Pharmaceutical Investigation
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    • 제24권1호
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    • pp.29-32
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    • 1994
  • In order to improve the sensitivity of the current assay methods of selenium in dried-yeast preparations, atomic absorption spectrophotometry (AAS), high performance liquid chromatography (HPLC) and UV-Vis spectrophotometry were employed. The sample was prepared with the digestion by acid mixture of hydrochloric acid, nitric acid and perchloric acid after elimination of ether-soluble substances. The range of quantitation of selenium was $1.0{\sim}6.0\;{\mu}g/ml$ by UV-Vis spectrophotometry, $5.0{\sim}20.0\;{\mu}g/ml$ by HPLC and $0.03{\sim}0.10\;{\mu}g/ml$ by AAS.

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Spectral Properties of a pH Responsive Water Soluble Spironaphthoxazine and Its Multi-Switching Property

  • Bae, Jin-Seok;Kim, Sung-Hoon
    • 한국염색가공학회지
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    • 제25권1호
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    • pp.18-24
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    • 2013
  • A water soluble spironaphthoxazine (SPO) was synthesized, and its spectral properties were determined. Under UV irradiation, colorless SPO shows intensive blue color while the intensity of its initial fluorescence decreased. In addition, SPO also exhibited high sensitivity to pH stimuli both in colorimetry and fluorometry distinguishing from the spectral appearance observed under UV irradiation. Further, integrating these two optical characteristics a three-state switching system can be established, and all interconversions can be observed by naked-eye.