• Title/Summary/Keyword: UV curable

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Study on single gap transflective liquid crystal display using the UV Curable Reactive Mesogen (광경화성 고분자를 이용한 단일 갭 반투과형 액정디스플레이 연구)

  • Her, Jung-Hwa;Kim, Jin-Ho;Chin, Mi-Hyung;Lim, Young-Jin;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.293-294
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    • 2009
  • We proposed a novel single gap transflective liquid crystal display (LCD) using liquid crystal with negative dielectric anisotropy. We designed cell structure driven by fringe electric field in the transmissive (T) part and vertical electric field in the reflective (R) part. In the device, high surface pretilt angle of the LC in the R-part is achieved through polymerization of an UV curable reactive mesogen (RM) monomer at surfaces. By optimizing the parameters, a newly developed transflective display has characteristics such as single gap and single gamma curve.

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Photo-DSC Studies of UV-Curable Hybrid Coating Systems (자외선 경화형 하이브리드 코팅의 광열분석적 연구)

  • Hong, J.W.;Lee, H.W.
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.857-861
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    • 1994
  • UV curable hybrid systems have been investigated in the urethane acrylate based formulations where potentially irritant acrylate monomers have been substituted by vinyl ethers. Generally, among the systems studied, coating properties of hybrid system are superior to those of free radical hut inferior to those of cationic systems. When the content of acrylic oligomer is above 70%, however, hybrid system could render an excellent combination of coating and curing properties which outperforms both cationic and free radical systems. Photo-DSC has been used to follow the progress of crosslinking of various coating systems. Results imply that the critical factors in determining the curing rates of coating formulations are different depending upon the formulation characteristics. In the same type of hybrid formulations, the monomer/oligomer ratio rather than photoinitiator efficiency is the critical factor determining the curing rate of the systems.

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Transfelctive Liquid Crystal Display using UV Curable Reactive Mesogen (광경화성 고분자를 이용한 반투과형 액정디스플레이)

  • Lim, Young-Jin;Jeong, Eun;Chin, Mi-Hyung;Kim, Jin-Ho;Kim, Seong-Su;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04a
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    • pp.51-52
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    • 2008
  • A single gap transflective liquid crystal display(LCD) driven by fringe electric field in the transmissive(T) region and vertical electric field in the reflective(R) region was designed. Because the pretilt angle is formed in $53^{\circ}$ through polymerization of an UV curable reactive mesogen(RM) monomer at the surface, the effective cell retardation $(d{\Delta}n_{eff})$ value of the R region becomes half of that in the T region where the LCs are homogenously aligned. Consequently, a transflective display driven by a vertical and fringe electric field with a single cell gap and single gamma curves is realized.

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Study on PVA mode using the UV curable reactive mesogen (RM) (광경화성 단분자를 이용한 PVA모드의 8-도메인 형성방안 연구)

  • Kim, Woo-Il;Kim, Sung-Min;Cho, In-Young;Kim, Mi-Young;Son, Jong-Ho;Ryu, Jae-Jin;Kim, Kyeong-Hyeon;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.339-340
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    • 2008
  • The Conventional PVA (patterned vertical alignment) mode showed characteristics of 8-domain using T-T type or C-C type. But these methods have disadvantages such as decreasing aspect ratio and transmittance. In order to resolve these problems, in this paper we have studied a new 8-domain method which is partially using the UV curable reactive mesogen (RM) that is a role in surface stabilization. The characteristic of off-axis color shift is decreased because the part of surface stabilized area is compensated to other area in a pixel. Consequently, the device shows improved color shift by 8-domain.

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A Piezo-driven Ultra-precision Stage for Alignment Process of a Contact-type Lithography (접촉식 리소그라피의 정렬공정을 위한 압전구동 초정밀 스테이지)

  • Choi, Kee-Bong;Lee, Jae-Jong;Kim, Gee-Hong;Lim, Hyung-Jun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.6
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    • pp.756-760
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    • 2011
  • This paper proposed an alignment stage driven by piezo actuators for alignment process of a contact-type lithography. Among contact-type lithography processes, an UV-curable nanoimprint process is an unique process to be able to align patterns on upper and lower layers. An alignment stage of the UV-curable nanoimprint process requires nano-level resolution as well as high stiffness to overcome friction force due to contact moving. In this paper, the alignment stage consists of a compliant mechanism using flexure hinges, piezo actuators for high force generation, and capacitive sensors for high-resolution measurement. The compliant mechanism is implemented by four prismatic-prismatic compliant chains for two degree-of-freedom translations. The compliant mechanism is composed of flexure hinges with high stiffness, and it is directly actuated by the piezo actuators which increases the stiffness of the mechanism, also. The performance of the ultra-precision stage is demonstrated by experiments.

Thermal Conductivity and Adhesion Properties of Thermally Conductive Pressure-Sensitive Adhesives

  • Kim, Jin-Kon;Kim, Jong-Won;Kim, Myung-Im;Song, Min-Seok
    • Macromolecular Research
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    • v.14 no.5
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    • pp.517-523
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    • 2006
  • The effects of particle content, size and shape on the thermal conductivity (k) and adhesion properties of thermally conductive, pressure-sensitive adhesives (PSAs) were investigated. The matrix resins were thermally crosslinkable, 2-ethylhexyl acrylic polyol and ultraviolet (UV)-curable, random copolymer consisting of acrylic oligomer and various acrylates. We found that k increased with increasing diameter and particle aspect ratio, and was further enhanced due to the reduction of the interfacial thermal barrier when the coupling agent, which increases the adhesion between particles and the matrix resin, was used. On the other hand, adhesion properties such as peel strength and tack of the thermally crosslinkable resin decreased sharply with increasing particle content. However, for UV curable resin, increased particle addition inhibited the decrease in adhesion properties.

Synthesis of UV-Curable Modified (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate Acrylate (자외선 경화형 변성 (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate 아크릴레이트의 합성)

  • Lee, Jongmin;Yi, Hwanpyo;Lee, Sanggun;Park, Hyungnam;Choi, Kangsik;Kim, Dojin
    • Korean Journal of Materials Research
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    • v.27 no.4
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    • pp.199-205
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    • 2017
  • In this study, (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate acrylate was synthesized by reacting (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate with acrylic acid to minimize hardening shrinkage and to improve heat resistance, which are known as disadvantages of photopolymers for 3D printing application. Urethane acrylate was synthesized by reacting 1,3,5-triazine-2,4,6-triamino alcohol, 2-hexylethyl acrylate, and isophorone diisocyanate in order to improve the mechanical properties without deteriorating the heat resistance. The physical properties before and after the synthesis of the acrylate and the mechanical properties when the urethane acrylate was applied were investigated. The reaction progress of the composite was examined by FTIR and $^{13}C$ NMR. The heat deflection temperature, flexural strength, and surface hardness of the molding were measured. The curing behavior by Photo-DSC ultraviolet irradiation was also examined.

Ink-Jet 3D Printability of Ceramic Ink with Contact Angle Control

  • Park, Jae-Hyeon;Lee, Ji-Hyeon;Kim, Deug Joong;Hwang, Kwang-Taek;Kim, Jin-Ho;Han, Kyu-Sung
    • Journal of the Korean Ceramic Society
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    • v.56 no.5
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    • pp.461-467
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    • 2019
  • Ink-jet printing technology, which utilizes a digitalized design to print fine ink directly on a substrate, has been of interest in various industries due to its high efficiency and adaptability to various materials. Recently, active attempts have been made to apply ceramic materials having excellent heat resistance, light resistance, and chemical resistance to the ink-jet printing process. In this study, ceramic ink was synthesized by combining ceramic pigments with UV curable polymer. 3D printability at various contact angles between ceramic ink and substrate was analyzed in detail. Rheological properties of the synthesized ceramic ink were optimized to meet the requirements of the ink-jet printing process, and the contact angle of UV curable ceramic ink was controlled through surface treatment of the substrate. The potential for additive manufacturing of ceramic material using ink-jet printing was investigated by analyzing the effect of contact angle control on ceramic ink droplets and their 3D printability.

Dual-curable Flame-Retardant Finish of Silk Fabrics Using a Water-soluble Cyclophosphazene Derivative (수용성 Cyclcophosphazene 유도체를 이용한 견섬유의 이중경화형 방염가공)

  • Kim, Jeong-Hwan;Baek, Ji-Yun;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.34 no.4
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    • pp.217-223
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    • 2022
  • Flame-retardant finished silk fabrics could release carcinogenic formaldehyde resulting from the conventional finishing agents. New water-soluble cyclophosphazene derivative can be used as a formaldehyde-free flame retardant for the silk protein. Dichloro tetrakis{N-[3-dimethylamino)propyl]methacrylamido}cyclophosphazene(DCTDCP) can be cured by heat or UV irradiation as a durable flame retardant for the silk fabrics. Treatment conditions were optimized including curing temperature and time, finishing formulations, and UV energy. At the 30% DCTDCP application, peak HRR and THR decreased by 42.6% and 49.6% respectively compared to the pristine silk fabrics. Also char residue increased up to 48% from 11% indicating solid-phase retarding mechanism. The flame-retardant silk fabrics showed a LOI of 31.1 and the washed sample maintained a LOI of 26.8 even after ten laundering cycles.

Development of Multi Piezo Ink-Jet Printing System Using Arbitrarily Waveform Generator (임의 전압파형발생기를 이용한 다중 피에조 잉크젯 3D 프린팅 장비 개발)

  • Kim, Jung Su;Kim, Dong Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.9
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    • pp.781-786
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    • 2015
  • Recently, studies of 3D printing methods have been working in various applications. For example, the powder base method laminates the prints by using a binding or laser sintering method. However, the draw back of this method is that the post process is time consuming and does not allow for parts to be rapidly manufactured. The binding method requires the post process while the time required for the post process is longer than the manufacturing time. This paper proposes a UV curing binding method with an integrated piezo printing head system. The optimization of an arbitrary waveform generation for the control of a UV curable resin droplet was researched, in addition to developed optimized UV curing processes in multi nozzle ink jet heads.