• Title/Summary/Keyword: UV Energy

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Fundamental Study on the Photocatalytic Degradation of Organics in Industrial Waste Water with the Presence of Titanium Dioxide

  • Kusaka, Eishi;Izawa, Mihiro;Fukunaka, Yasuhiro;Ishii, Ryuji
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.286-291
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    • 2001
  • As part of fundamental studies on the degradation of the organic compounds in industrial waste water, the photocatalytic degradation properties of the organic compound by means of the UV/TiO$_2$degradation process have been investigated. The test organic compound of acetic acid was chosen in this study. The testing of photo catalytic degradation were performed under various operation conditions such as TiO$_2$dosages, initial concentration of the organic, the aqueous pH's, etc. The effects of various parameters on the short time activity of the present acetic acid-UV/TiO$_2$system could be demonstrated from this investigation.

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The Inactivation Effects of UV Light on Bacteriophage f2 (박테리오파지 f2에 대한 자외광선의 살균효과)

  • Kim, Chi-Kyung;Quae Chae
    • Microbiology and Biotechnology Letters
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    • v.11 no.3
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    • pp.155-161
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    • 1983
  • The effects of ultraviolet light on bacteriophage f2 were investigated to determine the inactivation kinetics and its mechanism. The 260nm light showed a little higher inactivation rate than the one of 300 nm. In this work, our main concern was whether structural and/or conformational changes in the protein capsid could occur by UV irradiation. The inactivation for the first 20 minutes irradiation was rapid with a loss of about 4 logs and followed by a slower rate during the next 40 minutes with no survival noted in the samples irradiated for 90 minutes or longer. The structural change of the protein capsid was examined by optical spectroscopic techniques and electron microscopy. The absorption spectra of the UV irradiated phages showed no detectable differences in terms of the spectral shape and intensity from the control phage. However, the fluorescence emission spectroscopic data, i.e. 1) fluorescence quenching of tryptophan residues upon irradiation of 300 nm light, 2) enhancement of fluorescence emission of ANS (8-aniline-1-naphthalene sulfonate) bound to the intact phages compared to the one in the UV-treated phages, and 3) decrease of energy transfer efficiency from tryptophan to ANS in the UV-treated samples, presented remarkable differences between the intact and UV-treated phages. Such a structural alteration was also observed by electron microscopy The UV-treated phages appeared to be broken and empty capsids. Therefore, the inactivation of the bacteriophage f2 by UV irradiation is thought to be attributed to the structural change in the protein capsid as well as damage in the viral RNA by UV irradiation.

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Characteristics of direct laser micromachining of IC substrates using a nanosecond UV laser (나노초 UV 레이저 응용 IC 기판 소재 조성별 가공 특성)

  • Sohn, Hyon-Kee;Shin, Dong-Sig;Choi, Ji-Yeon
    • Laser Solutions
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    • v.15 no.3
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    • pp.7-10
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    • 2012
  • Dimensions (line/space) of circuits in IC substrates for high-end chips (e.g. CPU, etc.) are anticipated to decrease as small as $10{\mu}m/10{\mu}m$ in 2014. Since current etch-based circuit-patterning processes are not able to address the urgent requirement from industry, laser-based circuit patterning processes are under active research in which UV laser is used to engrave embedded circuits patterns into IC substrates. In this paper, we used a nanosecond UV laser to directly fabricate embedded circuit patterns into IC substrates with/without ceramic powders. In experiments, we engraved embedded circuit patterns with dimensions (width/depth) of abut $10{\mu}m/10{\mu}m$ and $6{\mu}m/6{\mu}m$ into the IC substrates. Due to the recoil pressure occurring during ablation, the circuit patterning of the IC substrates with ceramic powders showed the higher ablation rate.

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The Study of $Eu^{2+}$-activated Calcium Aluminium Silicate Phosphors for White UV-LED (백색 UV-LED를 위한 $Eu^{2+}$-활성화 칼슘 알루미늄 실리케이트 형광체 연구)

  • Hwang, Jung-Ha;Jang, Bo-Yun;Park, Joo-Seok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.32-35
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    • 2006
  • For the white UV-LED applications, $Eu^{2+}$-activated calcium aluminium silicate phosphors were synthesized for the first time and the structures and luminescence characteristics of these phosphors were investigated. The phosphors in this study emitted blue. green or blue-green light depending on the starting materials for synthesis. In addition, the structure was also changed when the different starting materials were used. When CaO and $CaCO_3$ was used as a starting material. tetragonal $Ca_2Al_2SiO_7$ was formed and blue-green and pure green light was emitted. respectively. However. in the case of $CaSiO_3$, triclinic $CaAl_2Si2O_8$ was formed and only pure blue emission was detected. The maximum emission intensity was obtained from $CaAl_2Si_2O_8:Eu^{2+}$ phosphors, which intensity was about 1.4 times higher than that of YAG:$Ce^{3+}$ phosphor used for blue LED.

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The Peel Energy Behavior of UV-Cured Acrylic PSAs (UV경화형 아크릴계 점착제의 박리 에너지 변화)

  • Son, Hee-Chul;Kim, Ho-Gyum;Lee, Dong-Ho;Min, Kyung-Eun
    • Polymer(Korea)
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    • v.32 no.4
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    • pp.313-321
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    • 2008
  • Acrylic pressure sensitive adhesive(PSA) was prepared by UV radiation curing and the peel energy and physical properties of PSA were investigated. The increase of amount of acrylic acid leads to improve the peel energy, associated with the substrate having smooth surface and high layer thickness. The high peel energy is obtained when the direction of irregularity in substrate is horizontal with the peeling direction. This is attributed to the increase of resistance to peeling in spite of decrease of wetting and the result corresponds to our supposition.

The Effect of Electron Beam Irradiation on Discoloration and Thermal Property of HDPE Filled with Antioxidants and UV Stabilizers (전자선 조사에 따른 산화방지제 및 자외선안정제 첨가 HDPE의 변색 영향과 열적 특성 분석)

  • Jeun, Joon Pyo;Jung, Seung Tae;Kim, Hyun Bin;Oh, Seung Hwan;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.7 no.1
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    • pp.23-28
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    • 2013
  • In this study, we fabricated high density polyethylene (HDPE) composites filled with antioxidants and UV stabilizers. The electron beam irradiation on the fabricated composites was carried out over a range of absorbed doses from 50 to 200 kGy to confirm the changes of discoloration. The changes of discoloration were characterized using a color difference meter and FT-IR for confirming the changes of the color difference and structural change. It was observed that the color difference of IRGANOX 1010-, IRGAFOS 168-, and TINUVIN 328- added HDPE was higher than that of the control HDPE by electron beam irradiation. The melting temperature of UV stabilizer-added HDPE was not significantly changed by electron beam irradiation. However, the melting temperature of phenol-containing antioxidant-added HDPE was increased with increasing the absorbed dose. And the melting temperature of phosphorus-containing antioxidant-added composite was decreased with increasing the absorbed dose.

Catalytic combustion type hydrogen gas sensor using TiO2 and UV LED (TiO2 광촉매와 UV LED를 이용한 접촉연소식 수소센서)

  • Hong, Dae-Ung;Han, Chi-Hwan;Han, Sang-Do;Gwak, Ji-Hye;Lee, Sang-Yeol
    • Journal of Sensor Science and Technology
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    • v.16 no.1
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    • pp.7-10
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    • 2007
  • A thick film catalytic gas sensors which can be operated at $142^{\circ}C$ in presence of ultra violet-light emitting diode has been developed to measure hydrogen concentration in 0-5 % range. The sensing material as a combustion catalyst consists of $TiO_{2}$ (5 wt%) and Pd/Pt (20 wt%) supported on $Al_{2}O_{3}$ powder and the reference material to compensate the heat capacity of it in a bridge circuit was an catalyst free $Al_{2}O_{3}$ powder. Platinum heater and sensor materials were formed on the alumina plate by screen printing method and heat treatment. The effect of UV radiation in the presence of photo catalyst $TiO_{2}$ on the sensor sensitivity, response and recovery time has been investigated. The reduction of operating temperature from $192^{\circ}C$ to $142^{\circ}C$ for hydrogen gas sensing property in presence of UV radiation is attributed to the hydroxy radical and superoxide which was formed at the surface of $TiO_{2}$ under UV radiation.

Disinfection of E.coli in Drinking Water by TiO2 Photocatalytic System (TiO2 광촉매 시스템을 이용한 음용수 중의 대장균 살균연구)

  • Jung, Jin-Ah;Kwak, Do Hwan;Oh, Dae Woong;Park, Dong Min;Yang, O-Bong
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.11-17
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    • 2012
  • Disinfection of Escherichia coli (E. coli) in drinking water was investigated by using $TiO_2$ and $TiO_2-SiO_2$ based photocatalyst prepared by sol-gel method. The disinfection test was carried out in an annular flow reactor with circulating sterile water containing the photocatalysts powder under UV-A irradiation. The disinfection activity was proportional to the anatase`s intensity of crystalline peak of the $TiO_2$ photocatalysts. 100% disinfection of E.coli without endotoxin was achieved with $TiO_2$ coated photocatalytic system under UV-A irradiation within 2 h. However, toxic endotoxine was exist in the disinfection of E.colithe under UV-C irradiation even though 100% disinfection of E.colithe within 30 min, which suggest that $TiO_2$ coated photocatalytic system with UV-A is useful tool for the disinfection of E.coli in drinking water.

Breathable Waterproof Finish of PET Fabrics via Microporous UV Coating of Polyurethane Diacrylate (폴리우레탄 디아크릴레이트의 미세다공성 UV코팅에 의한 PET 직물의 투습방수가공)

  • Koo, Gwang-Hoe;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.22 no.3
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    • pp.239-245
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    • 2010
  • Breathable waterproof PET fabrics were prepared by the UV coating of UV-curable polyurethaneacrylate(PUA) formulation mixed with polyethyleneglycol(PEG) as a water soluble pore former. The dispersed PEG in the UV-cured coating was extracted by warm water, which can generate individual circular pores uniformly distributed all over the coating instead of pore channels. Accordingly the moisture permeability of the microporously coated fabrics increased substantially with increasing PEG addition without significant reduction of hydrostatic pressure. Also the silicone diacrylate addition in the formulation was beneficial in increasing the hydrostatic pressure. The UV-based microporous coating can be an alternative to conventional thermal curing of solventborne polyurethane coating owing to the enhanced environment friendliness and energy saving.

Hydrophobic Properties on RF-sputtered PTFE Films coated on UV-treated Glass Substrates (UV 처리된 유리기판위에 RF-스퍼터된 PTFE 박막들의 발수 특성)

  • Son, Jin-Woon;Youn, Hyon-O;Bae, Kang;Sohn, Sun-Young;Kim, Hwa-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.1
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    • pp.6-9
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    • 2010
  • Surface properties of polytetrafluoroethylene(PTFE) films fabricated by rf-magnetron sputtering system with UV surface treatment were investigated to increase water contact angle for their hydrophobic property. We found that the surface morphology and water contact angles of PTFE film modified as a function of the UV treatment times using UV-irradiation were influenced. The water contact angle of PTFE film with optimized UV treatment time for 15 minute showed a high hydrophobicity compared with the film without any surface treatment. We thought that it was due to the energy change of PTFE surface with an adhesion improvement to the glass surface as a smoothing a rough surface with needle-shape and/or the enhancement of an interface property as a removing some defects on the surface like a cleaning effect.