• Journal of the Korean Chemical Society
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• v.56 no.1
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• pp.62-67
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• 2012

A series of homo binuclear complexs of the type $[M_2(L/L^')(NO_3)n].mH_2O$, [where $M=U{O_2}^{2+},\;Th^{4+},\;ZrO^{2+}$] and $[(VO)_2(L/L^')(SO_4)_2]{\cdot}2H_2O$, L=1,5,6,9,12,15,16,20 octaaza-7,813,14-tetraphenyl-2,4,17,19-tetramethyl-1,4,6,8,12,14,16,19-docosaoctene (OTTDO) or L'=10:11;21:22-dibenzo-1,5,6,9,12,15,16,20-octaaza-7,813,14-tetraphenyl-2,4,17,19-tetramethyl-1,4,6,8,12,14,16,19-docosaoctene (DOTTOT), n=4 for $U{O_2}^{2+}$, $ZrO^{2+}$ n=8 for $Th^{4+}$ m=1,2,3 respectively, have been synthesized in template method from ethylenediamine/orthophenylene diamine, benzil monohydrazone and acetyl acetone and characterized on the basis of elemental analysis, thermal analysis, molar conductivity, magnetic moment, electronic, infrared, $^1H$-NMR studies. The results indicate that the VO(IV) ion is penta co-ordinated yielding paramagnetic complexes; $UO_2(VI)$, ZrO(IV) ions are hexa co-ordinated where as Th(IV) ion is octa co-ordinated yielding diamagnetic complexes of above composition. The fungi toxicity of the ZrO(IV) and VO(IV) complexes against some fungal pathogen has been studied.

• Journal of the Korean Ceramic Society
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• v.40 no.5
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• pp.410-414
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• 2003

Characteristics of $UO_{2+x}$ powders oxidized at different temperatures were examined. Pellets were fabricated by adding these oxidation powders and their properties were also investigated. Particle size of the $UO_{2+x}$ powders decreased with increasing oxidation temperature while surface area increased. Only the powders oxidized at 35$0^{\circ}C$ enhanced the strength of green pellet. However, 35$0^{\circ}C$ oxidized powders added pellet had many surface defects. The difference of shrinkage rate between the oxidized and UO$_2$ powders was thought to be the cause of them.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2018.11a
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• pp.343-344
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• 2018

KAERI has about 185 tons of $D-UF_6$ from 1986 and it being stored 16 48Y type cylinders inside of storage building. The $D-UF_6$ cylinders should be transported to other countries for the deconversion into stable materials such as $U_3O_8$ in order to enhance the storage safety and disposal. For the transportation to other country and loading the cylinders to the deconversion facility, the sampling process is essential. The design and procedure for the sampling are now developing, and environmental effect evaluation and risk evaluation works will be performed to acquire license for the sampling.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.85.2-85.2
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• 2018

금속 나노구조체에서의 localized surface plasmon resonance와 surface-enhanced Raman scattering 현상은 센서를 비롯한 다양한 응용분야를 가지고 있다. 나노구조체 array 형성을 위한 대표적인 top-down 방식인 e-beam lithography 공정은 제조비용이 매우 높고 대량생산 및 대면적화에도 한계가 있기에 polystyrene(PS) bead의 self-assembly를 이용한 nanosphere lithography와 같은 bottom-up 방식이 폭넓게 연구되고 있다. Closed-packing된 PS bead의 monolayer를 얻기 위해서는 기판의 친수성 처리가 필요한데, 기존의 많은 연구에서는 기판의 표면개질에 화학적 공정을 이용하고 있다. 하지만 이는 기판 선택의 자유도를 떨어뜨리는 원인이 된다. 금속이나 실리콘 기판에서는 산성 용액을 이용한 화학적 처리방법을 적용할 수 있지만 SU-8과 같은 감광액 및 폴리머 기판에서는 산에 대한 내구성이 떨어져 화학적 공정의 도입이 불가능 하기 때문이다. 본 연구에서는 이러한 한계점을 극복하기 위해 $UV-O_3$ 공정으로 친수성 처리된 다양한 기판에서 spin coating을 통한 PS monolayer를 제조하였는데, UV 램프의 에너지 조절을 통해 기판에 붙어있는 유기물들을 효과적으로 제거할 수 있었고 $O_3$ 생성 및 분해 과정에서 기판 표면에 친수성 화학 작용기를 생성시킬 수 있었다. 제조된 PS layer를 mask로 사용하여 Ag, Al, Au 등 다양한 나노구조체 array를 형성하여 array 주기에 따른 플라즈몬 공명 특성을 분석하였다. 레이저 조사로 나노구조체의 형상을 변화시킴으로써 동일한 물질과 주기를 가진 array에서도 플라즈몬 특성의 변조가 가능함을 확인하였는데, 이는 금속 나노구조체의 응용측면에서 매우 고무적인 발견이다.

• Bulletin of the Korean Chemical Society
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• v.26 no.7
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• pp.1065-1070
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• 2005

$[Mn_{12}O_{12}(O_2CPh-4-SMe)_{16}(H_2O)_4]{\cdot}7CH_2Cl_2$ (1), a new single-molecule magnet complex has been successfully synthesized by substitution of acetate ligand of Mn12ac with 4-(methylthio)benzoic acid. Complex 1 crystallizes into triclinic P$\overline{1}$ with a = 18.321(3) $\AA$, b = 19.011(3) $\AA$, c = 27.230(4) $\AA$, $\alpha$ = 86.973(3)$^{\circ}$, $\beta$ = 76.919(3)$^{\circ}$, $\gamma$ = 87.613(3)$^{\circ}$, and Z = 2. In complex 1, one Mn(III) ion has an abnormal Jahn-Teller elongation axis oriented at an oxide ion. Complex 1 has two out-of-phase ac susceptibility peaks in the 2-4 K and 4-7 K regions. Effective anisotropy energy barrier and pre-exponential factor are $U_{eff}$ = 45.95 K, 1/$\tau$0 = 8.6 ${\times}\;10^9s^{-1}\;for\;{\chi}_M$'' peaks in the lower temperature region and $U_{eff}$ = 59.45 K, 1/$\tau_0$ = 2.2 ${\times}\;10^8\;s^{-1}$ for $\chi_M$'' peaks in the higher temperature region. The parameters of S = 10, g = 1.87, D = -0.40 $cm^{-1}$, and E = 0.00034 $cm^{-1}$ were obtained from the M/N${\mu}_B$ vs. H/T plot of complex 1.

• Bulletin of the Korean Chemical Society
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• v.30 no.8
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• pp.1749-1754
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• 2009

Solubilities of carbon dioxide (C$O_2$) in a series of fluorine-free room temperature ionic liquids (RTILs), dialkylimidazolium dialkylphosphates and dialkylimidazolium alkylphosphites, were measured at 313∼333 K and pressures up to 5 MPa. Henry’s law coefficients as the solubility parameter of C$O_2$ in RTILs were derived from the isotherm of fugacity versus C$O_2$ mole fraction. The C$O_2$ solubility in a phosphorus-containing RTIL was found to increase with the increasing molar volume of the RTIL. In general, dialkylimidazolium dialkylphosphate exhibited higher absorption capacity than dialkylimidazolium alkylphosphite as long as the RTILs possess an identical cation. Among RTILs tested, 1-butyl-3-methylimidazolium dibutylphosphate [BMIM][B$u_2PO_4$] and 1-butyl-3-methylimidazolium butylphosphite [BMIM][BuHP$O_3$] exhibited similar Henry’s law coefficients to 1-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl)imide ([BMIM][T$f_2$N]) and 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][B$F_4$]), respectively. The Krichevsky-Kasarnovsky equation was employed to derive the C$O_2$ solubility parameter (Henry’s law coefficient) from the solubility data measured at elevated pressures.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.533-537
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• 2017

우리나라는 2012년에 4대강 사업을 통하여 수자원확보를 통한 가뭄대응전략으로 16개의 대형보가 건설되었고 영산강에는 승촌보와 죽산보 2개의 보가 건설되었다. 보의 건설로 흐름은 급격히 감소하여 정체구역의 수역이 확장되면서 여름에서 초가을까지 녹조현상은 매년 지속적으로 발생하고 있으며, 최근 국민들은 안전한 농산물의 안정적인 생산에 요구가 점증함에 따라 농업용수질 오염문제가 범국가적 문제로 대두되고 있고, 그 중요도 및 심각성이 점차 커져가고 있다(한강유역환경청, 2007). 많은 량의 물을 농업용수로 사용하고 있는 영산강의 녹조현상 및 수질개선이 절실하다. 따라서 본 연구에서는 영산강의 승촌보와 죽산보의 건설과 수질오염총량관리제의 시행에 따른 부영양화특성의 변화를 파악하기 위하여 환경부, 국립환경과학원(2006)에서 개발한 한국형 부영양화지수(TSIko) 평가법을 이용하여 영산강유역의 12개 주요지점에 대하여 수집한 자료를 봄(3월~5월), 여름(6월~8월), 가을(9월~11월), 겨울(12월~2월)로 분리하고, 다시 4대강 사업의 영향을 검토하기 위하여 2013년을 전후하여 분리하였으며, 계절별 수질인자 COD, T-P, Chl-a 값을 이용하여 계절별 $TSI_{Ko}$를 산정하여 영양상태를 4개의 등급으로 구분하여 부영양화특성을 파악하였다.

• Bulletin of the Korean Chemical Society
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• v.24 no.4
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• pp.413-420
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• 2003

A gas chromatography/mass spectrometric assay method was developed for the simultaneous determination of neutral and bacis twenty-five disruptors $(ED_S)$ in frog and fish. Afther homogenization and sonication of 5 g of sample, purification was achieves in one step with a solid phase extraction procedure using silica gelflorisl. Eluton was performed with 50mL of acetone : n-hexane (1 : 9) solution. The eluate was concentrated to approximately 10uL and dissolves with 100 uL of hexane and analyzed by GC-MS (SIM). The peaks had good chromatographic properties and the extraction of these compounds from sample also gave relatively high recoveries with small variatoins. Detection limits were 0.1 ng/g for 4-nitrotoluene, benzophenone, hexachlorobenzene, atrazine, malathion, o,p-DDT, o,p-DDT and permethrin, and 0.2 ng/g for heptachlor epoxide, γ-chlordane, α-chlordane, p,p'-DDE, p,p'-DDD, cypermethrin and fenvalerate, and 0.3 ng/g for trifluralin, metribuzin, alachlor, dieldrin and p,p'-DDT, and 0.5 ng/g for heptachlor, aldrin and parathion, and 0.7 ng/g for endrin, and 0.8 ng/g for nitrofen. The recoveries were between 33 and 109%. The method was used to analyze twenty-five frogs and forty-six fishes fishes samples caught from various regions in Korea. Benzophenone was detected at concentration of up to 17.2 ng/g in frog or fish. Heptachlor, aldrin, γ-chlordane, p,p'-DDE, p,p'-DDD, endrin and o,p-DDD were detected at concentrations of 0.7-12.5 ng/g in frog or fish. Also significant leveles of dieldrin (up to 22.5 ng/g) were observed. The developed method may be valuable to be used to the national monitoring project of EDS in biota samples.

• Proceedings of the IEEK Conference
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• 2006.06a
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• pp.617-618
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• 2006

A CMOS quadrature Up-converter for a direct-conversion receiver of 5.15-5.825GHz wireless LAN is described. The Up-converter consists of two sub-harmonic mixers, for I and Q channels, and an LO generation network. In order to decrease the number of inductor, I and Q path are merged. The simulation results including all the parasitics show -17.3dB conversion gain at center and -8 dBv oIP3 while consuming 22.968mW under 1.8V supply. The quadrature Up-converter is under fabrication with the other transmitter blocks in a $0.18{\mu}m$ CMOS technology.

• Progress in Superconductivity
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• v.13 no.2
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• pp.97-104
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• 2011

In the dielectric resonator method, which has been widely used for measuring the microwave surface resistance of superconductors, accuracies in the geometrical factors (G-factors) affect the uncertainty in the measured surface resistance. We compare the G-factors of short-ended sapphire resonator as obtained by using field analysis with those by using computer simulations: The former is obtained by using the analytic expressions for the electric and the magnetic field components inside the resonator, and the latter by using computer software. The G-factors as obtained by using the latter appear to be closer to those obtained by using the former as the resonator space is divided into larger number of sub-space, i.e., a tighter mesh, with a difference of ~8 % observed for a mesh of 14400 sub-spaces reduced to ~2 % for 114996 sub-spaces. Variations in the relative uncertainty in the surface resistance of typical $YBa_2Cu_3O_{7-\delta}$ superconductor films with those in the G-factors are studied, which provides an upper limit of the relative uncertainty in the G-factors required for realizing the target uncertainty in the surface resistance. These results could be useful in estimating the optimum number of meshes for obtaining the G-factors through computer simulations.