Browse > Article
http://dx.doi.org/10.5012/jkcs.2012.56.1.062

Synthesis and Characterization of Homo Binuclear Macrocyclic Complexes of UO2(VI), Th(IV), ZrO(IV) and VO(IV) with Schiff-Bases Derived from Ethylene diamine/Orthophenylene Diamine, Benzilmonohydrazone and Acetyl Acetone  

Mohapatra, R.K. (Department of Chemistry, Orissa School of Mining Engineering (Degree Stream))
Ghosh, S. (School of Chemistry, Sambalpur University)
Naik, P. (School of Chemistry, Sambalpur University)
Mishra, S.K. (School of Chemistry, Sambalpur University)
Mahapatra, A. (School of Chemistry, Sambalpur University)
Dash, D.C. (School of Chemistry, Sambalpur University)
Publication Information
Journal of the Korean Chemical Society / v.56, no.1, 2012 , pp. 62-67 More about this Journal
Abstract
A series of homo binuclear complexs of the type $[M_2(L/L^, [where $M=U{O_2}^{2+},\;Th^{4+},\;ZrO^{2+}$] and $[(VO)_2(L/L^, L=1,5,6,9,12,15,16,20 octaaza-7,813,14-tetraphenyl-2,4,17,19-tetramethyl-1,4,6,8,12,14,16,19-docosaoctene (OTTDO) or L'=10:11;21:22-dibenzo-1,5,6,9,12,15,16,20-octaaza-7,813,14-tetraphenyl-2,4,17,19-tetramethyl-1,4,6,8,12,14,16,19-docosaoctene (DOTTOT), n=4 for $U{O_2}^{2+}$, $ZrO^{2+}$ n=8 for $Th^{4+}$ m=1,2,3 respectively, have been synthesized in template method from ethylenediamine/orthophenylene diamine, benzil monohydrazone and acetyl acetone and characterized on the basis of elemental analysis, thermal analysis, molar conductivity, magnetic moment, electronic, infrared, $^1H$-NMR studies. The results indicate that the VO(IV) ion is penta co-ordinated yielding paramagnetic complexes; $UO_2(VI)$, ZrO(IV) ions are hexa co-ordinated where as Th(IV) ion is octa co-ordinated yielding diamagnetic complexes of above composition. The fungi toxicity of the ZrO(IV) and VO(IV) complexes against some fungal pathogen has been studied.
Keywords
Schiff base; Binuclear macrocyclic complexes; Template synthesis; Structure and spectral properties;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 Radecka-Paryzek, W.; Patroniak, V.; Lisowski, J. Coord. Chem. Rev. 2005, 249, 2156.   DOI   ScienceOn
2 Wainwright, K. P. Coord. Chem. Rev. 1997, 166, 35.   DOI
3 Chohan, Z. H.; Pervez, H.; Kausar, S.; Supuran, C. T. Synth. React. Inorg. Met.-Org. Chem. 2002, 3, 529.
4 Chohan, Z. H.; Pervez, H.; Rauf, A.; Supuran, C. T. Met-Based Drugs 2002, 8, 42.
5 Chohan, Z. H.; Scozzafava, A.; Supuran, C. T. J. Enzym. Inhib. Med. Chem. 2003, 18, 259.   DOI   ScienceOn
6 Selbin, J. Angew. Chem. 1996, 5, 712.
7 Dash, K. C.; Mansingh, P. S.; Mohanty, R. R.; Jena, S. Indian J. Chem. 1996, 35A, 480.
8 Maurya, R. C.; Patel, P.; Rajput, S. Synth. React. Inorg. Met.-Org. Chem. 2003, 33, 817.   DOI   ScienceOn
9 Rao, C. N. R. Chemical Application of IR Spectroscopy; Academic Press: New York and London, 1963.
10 Ferraro, J. R. Low Frequency Vibrations of Inorganic and Coordination Compounds; Plenum Press: New York, 1971.
11 Singh, R. P.; Tandon, J. P. Indian J. Chem. 1980, 19A, 602.
12 Yadava, H. D. S.; Sengupta, S. K.; Tripathi, S. C. Inorg. Chem. Acta. 1987, 128, 1.   DOI   ScienceOn
13 Maurya, R. C.; Sharma, P. Indian J. Chem. 1999, 38A, 509.
14 Maurya, R. C.; Maurya, M. R. Rev. Inorg. Chem. 1995, 15, 1.   DOI
15 Rani, D. S.; Ananthalakshmi, P. V.; Jayatyagaraju, V. Indian J. Chem. 1999, 38A, 843.
16 Nikolaev, A. V.; Lagvienko, V. A.; Myachina, I. Thermal Analysis, Vol. 2; Academic Press: New York, 1969; p 9.
17 Gudasi, K. B.; Goudar, T. R. J. Indian Chem. Soc. 2002, 79, 529.
18 Saha, M. C.; Roy, R.; Ghosh, M. K.; Roy, P. S. Indian J. Chem. 1987, 26A, 48.
19 Lever, A. B. P. Inorganic Electronic Spectroscopy; Elsevier Publication: 1968; p 258.
20 Shakir, M.; Varkey, S. P. Trans. Met. Chem. 1994, 19, 606.   DOI   ScienceOn
21 Khan, T. A.; Hasan, S. S.; Jahan, N.; Mohamed, A. K.; Islam, K. S. Indian J. Chem. 2000, 39A, 1090.
22 Busch, D. H.; Jackson, P. J.; Kajima, M.; Chielewski, P.; Matsumoto, N.; Stevens, J. C.; Nosco, W.; Wu, D.; Herran, N.; Ye, N.; Warburton, P. R.; Masarwa, M.; Stephenson, N. A.; Christoph, G.; Alcock, N. W. Inorg. Chem. 1994, 33, 910.   DOI   ScienceOn
23 Balhausen, C. J. An Introduction to Ligand Field; McGraw Hill: New York, 1962.
24 Karmakar, T. K.; Ghosh, B. K.; Osman, A.; Fun, H. K.; Riviere, E.; Mallah, T.; Aromi, G.; Chandra, S. K. Inorg. Chem. 2005, 44, 2391.   DOI   ScienceOn
25 Lindoy, L. F. The Chemistry of Macrocyclic Ligand Com-plexes; Cambridge University Press: Cambridge, 1989.
26 Correa, W. H.; Scott, J. L. Molecules 2004, 9, 513.   DOI
27 Niasari, M. S.; Bazarganipour, M.; Ganjali, M. R.; Norouzi, P. Transition Met. Chem. 2007, 32, 9.   DOI   ScienceOn
28 Niasari, M. S.; Daver, F. Inorg. Chem. Commun. 2006, 9, 175.   DOI   ScienceOn
29 Johnson, D. K.; Murphy, T. B.; Rose, N. J.; Goodwin, W. H.; Pickart, L. Inorg. Chim. Acta. 1982, 67, 159.   DOI
30 Ranford, J. D.; Vittal, J. J.; Wang, Y. M. Inorg. Chem. 1998, 37, 1226.   DOI   ScienceOn
31 Buss, J. L.; Greene, B. T.; Turner, J.; Torti, F. M.; Torti, S. V. Curr. Top. Med. Chem. 2004, 4, 1623.   DOI   ScienceOn
32 Carlsor, J. B.; Davies, G.; Vorous, P. Inorg. Chem. 1994, 33, 2334.   DOI   ScienceOn
33 Ladavos, A. K.; Kooli, F.; Moreno, S.; Skaribas, S. P.; Pomonis, P. J.; Jones, W.; Poncelet, G. Appl. Clay Sci. 1998, 13, 49.   DOI   ScienceOn
34 Dutta, S. K.; Nanda, K. K.; Florke, U.; Bhadbhade, M.; Nag, K. J. Chem. Soc. Dalton Trans. 1996, 2371.
35 Panda, A. K.; Dash, D. C.; Mishra, P.; Acharya, S. B. Synth. React. Inorg. Met.-Org. Chem. 1998, 28(10), 1769.   DOI   ScienceOn
36 Dash, D. C.; Mohapatra, R. K.; Ghosh, S.; Naik, P. J. Korean Chem. Soc. 2008, 52(5), 468.   DOI
37 Dash, D. C.; Mohapatra, R. K.; Ghosh, S.; Naik, P. J. Indian Chem. Soc. 2009, 86, 121.
38 Dash, D. C.; Mahapatra, A.; Naik, P.; Mohapatra, R. K.; Naik, S. K. J. Korean Chem. Soc. 2011, 55(3), 412.   DOI
39 Holm, R. H.; Everestt (J), G. W.; Chakrabarty, A. Progress in Inorganic Chemistry, Interscience, 1966, 7, 83.   DOI
40 Vogel, A. I. A Hand Book of Quantitative Inorganic Analysis, 2nd ed.; Longman, ELBS: London, 1966.