• 제목/요약/키워드: Two liquids

검색결과 163건 처리시간 0.035초

Solid-State High-Resolution 1H-NMR Study for Ammonia Borane of Hydrogen Storage Material

  • Han, J.H.;Lee, Cheol-Eui;Kim, Se-Hun;Kim, Chang-Sam;Han, Doug-Young
    • 한국자기공명학회논문지
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    • 제14권1호
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    • pp.38-44
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    • 2010
  • In liquids NMR, $^{1}H$ is the most widely observed nucleus, which is not the case in solids NMR. The reason is due to the strong homo-dipolar interactions between the hydrogen atoms which mask the useful chemical shift information. Therefore we must remove the strong homo-dipolar interactions in order to get structural information, which can be investigated by the isotropic chemical shift. There are two ways of obtaining it. One is the ultra-fast MAS of ca. 70 kHz spinning speed, which has become available only recently. The other way is devising a pulse sequence which can remove the strong homo-dipolar interaction. In the latter way, MAS with a moderate spinning rate of a few kHz, is enough to remove the chemical shift anisotropy. In this report, 1D-CRAMPS and 2D MASFSLG techniques are utilized and their results will be compared. This kind of highresolution $^{1}H$ NMR for solids, should become a valuable analytical tool in the understanding and the developing of a new class of hydrogen storage materials. Here ammonium borane $-NH_{3}BH_{3}$, whose hydrogen content is high, is used as a sample.

기계평면시일에서 온도전파를 위한 파속도의 이론적해석 (ANALYSIS OF WAVE VELOCITY FOR TEMPERATURE PROPERGATION IN A MECHANICAL FACE SEAL)

  • 김청균
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 1987년도 제5회 학술강연회초록집
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    • pp.50-56
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    • 1987
  • A mechanical face seal is most commonly used to seal liquids and gases at various speeds, pressures and temperatures. The primary seal ring is in sliding contact with the seal seat and as a result heat in the vicinity of the interface is generated. Local temperatures at points along the circumferential direction will fluctuate as asperities on the surfaces pass. This kind of fluctuation of temperature has been investigated to take place. This may lead to the hot spots phenomenon between the contacting asperities. Sibley and Allen showed photographic evidence of systemically moving hot spots in the contact zone. The appearance of such a temperature disturbance has been attributed to a kind of thermoelastic instabilities between two surfaces: This involves a feedback loop which comprises localized elevation of frictional heating, resultant localized thermal bulding, localized pressure increase as the result of the bulging and futher elevation of frictional heating as the result of the pressure increase. The heating of hot spots will be continued until the expanded material due to the frictional heating is worn off. Therefore to predict the speed of temperature propagation into the body is essential to the analysis of heat transfer on the edge of the seal.

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Non-contact monitoring of 3-dimensional vibrations of bodies using a neural network

  • Ha, Sung Chul;Cho, Gyeong Rae;Doh, Deog-Hee
    • Journal of Advanced Marine Engineering and Technology
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    • 제39권10호
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    • pp.1011-1016
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    • 2015
  • Gas piping systems in power plants and factories are always influenced by the mechanical vibrations of rotational machines such as pumps, blowers, and compressors. Unusual vibrations in a gas piping system influence possible leakages of liquids or gases, which can lead to large explosive accidents. Real-time measurements of unusual vibrations in piping systems in situ prohibit them from being possible leakages owing to the repeated fatigue of vibrations. In this paper, a non-contact 3-dimensional measurement system that can detect the vibrations of a solid body and monitor its vibrational modes is introduced. To detect the displacements of a body, a stereoscopic camera system is used, through which the major vibration types of solid bodies (such as X-axis-major, Y-axis-major, and Z-axis-major vibrations) can be monitored. In order to judge the vibration types, an artificial neural network is used. The measurement system consists of a host computer, stereoscopic camera system (two-camera system, high-speed high-resolution camera), and a measurement target. Through practical application on a flat plate, the measured data from the non-contact measurement system showed good agreement with those from the original vibration mode produced by an accelerator.

A New Generation of Biocompatible Pulse-discharged Plasma by Marx Generator and Its Application on the Biomolecules

  • 박지훈;;홍영준;;김상엽;김영조;이구협;이승목;박봉상;전수남;최은하
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.240.2-240.2
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    • 2014
  • Characteristics of pulse-discharged plasma in liquid and its biological applications to proteins are investigated by making use of high voltage Marx generator. The Marx generator has been consisted of 5 stages, where each charging capacitor is $0.5{\mu}F$ to generate a high voltage pulse with rising time of $1{\mu}s$. We have applied an input voltage of 6 kV to the each capacitor of $0.5{\mu}F$. The high voltage pulsed plasma has been generated inside a polycarbonate tube by a single-shot operation, where the breakdown voltage is measured to be 7 kV, current of 1.2 kA, and pulse width of ${\sim}1{\mu}s$ between the two electrodes of anode-cathode made of stainless steel, which are immersed into the liquids. For the investigation of the influence of pulsed plasma on biomolcules, we have focused on the amino acids, DNA, proteins, cell and cholesterol.

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심장 내 이식형 축류 혈액 펌프용 자성 유체 축봉의 내압 특성 (Characteristics of the Sealing Pressure of a Magnetic Fluid Shaft Seal for Intra-Cardiac Axial Flow Blood Pumps)

  • 김동욱
    • 대한전기학회논문지:시스템및제어부문D
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    • 제51권10호
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    • pp.477-482
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    • 2002
  • One of the key technologic requirements for rotary blood pumps is the sealing of the motor shaft. A mechanical seal, a journal bearing, magnetic coupling, and magnetic suspension have been developed, but they have drawbacks such as wear, thrombus formation, and power consumption. A magnetic fluid seal is durable, simple, and non power consumptive. Long-term experiments confirmed these advantages. The seal body was composed of a Nd-Fe-B magnet and two pole pieces; the seal was formed by injecting magnetic fluid into the gap (50${\mu}m$) between the pole pieces and the motor shaft. To contain the ferro-fluid in the seal and to minimize the possibility of magnetic fluid making contact with blood, a shield with a small cavity was attached to the pole piece. While submerged in blood, the sealing pressure of the seal was measured and found to be 31kPa with magnetic fluid LS-40 (saturated magnetization, 24.3 KA/m) at a motor speed of 10,000 rpm and 53kPa under static conditions(0mmHg). The specially designed magnetic fluid seal for keeping liquids out is useful for axial flow blood pumps. The magnetic fluid seal was incorporated into an intra-cardiac axial flow blood pump.

판각형 열교환기 성능해석에 관한 연구 (A Study on the Performance Analysis in the Plate and Shell Heat Exchanger)

  • 서무교;박재홍;김영수
    • 동력기계공학회지
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    • 제5권1호
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    • pp.35-43
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    • 2001
  • Heat exchangers are called with important devices which have been widely used in industrial fields. Therefore, the design method for a heat exchanger is an important study in the aspect of energy saving. In this study, performance analyses for two types of plate and shell heat exchangers having a corrugated trapezoid shape of a chevron angle with $45^{\circ}$, were executed and compared with experiments. For this study, the operation liquids were adopted with non-phase changing water. In the analysis, ${\epsilon}-NTU$ method was used for a plate and shell heat exchanger and a program was constructed. Independent variables for a plate and shell heat exchanger are flow rate and inlet temperature. Compared with experimental data, the accuracy of the developed are ${\pm}2.5%\;and\;{\pm}5%$ at the type A and type B in the heat transfer rate, respectively. In the pressure drop, the accuracy of the proposed program for a plate and shell heat exchanger is within ${\pm}3%$ and 5% error bounds for the type A and type B, respectively.

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복합적층 원뿔형 쉘의 자유진동에 관한 기하학적 형상의 영향 (Effects of Geometrical Shape on the Free Vibration of Laminated Composite Conical Shells)

  • 손병직;지효선;장석윤
    • 한국강구조학회 논문집
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    • 제14권4호
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    • pp.519-527
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    • 2002
  • 쉘 구조물은 지붕 구조물, 굴뚝 구조물, 압력구조물, 선박구조물, 항공구조물 등에 널리 사용되는 구조물이다. 본 논문은 전단변형 효과를 고려한 비등방성 복합성층 원뿔형 쉘의 자유진동에 관하여 연구하였다. 복합재료는 2개 또는 이상의 재료들로 구성되어 구조적인 효율성을 증진시키도록 구성된 재료이다. 이러한 복합재료로 구성된 구조물의 거동은 매우 복잡하기 때문에 해석해를 구하기가 거의 불가능하다. 따라서 본 연구에서는 이러한 복합재료로 구성된 원뿔형 쉘의 자유진동을 해결하는데 유한차분법을 사용하였다. 중심각, 정점각 및 다른 기하학적 파라미터의 진동에 대한 효과를 연구하였고, 진동모드 형상을 예시함으로서 진동모드에 관한 물리적 및 공학적인 이해를 증진시키고자 하였다.

Marangoni convection radiative flow of dusty nanoliquid with exponential space dependent heat source

  • Mahanthesh, Basavarajappa;Gireesha, Bijjanal Jayanna;PrasannaKumara, Ballajja Chandra;Shashikumar, Nagavangala Shankarappa
    • Nuclear Engineering and Technology
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    • 제49권8호
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    • pp.1660-1668
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    • 2017
  • The flow of liquids submerged with nanoparticles is of significance to industrial applications, specifically in nuclear reactors and the cooling of nuclear systems to improve energy efficiency. The application of nanofluids in water-cooled nuclear systems can result in a significant improvement of their economic performance and/or safety margins. Therefore, in this paper, Marangoni thermal convective boundary layer dusty nanoliquid flow across a flat surface in the presence of solar radiation is studied. A two phase dusty liquid model is considered. Unlike classical temperature-dependent heat source effects, an exponential space-dependent heat source aspect is considered. Stretching variables are utilized to transform the prevailing partial differential system into a nonlinear ordinary differential system, which is then solved numerically via the Runge-Kutta-Fehlberg approach coupled with a shooting technique. The roles of physical parameters are focused in momentum and heat transport distributions. Graphical illustrations are also used to consider local and average Nusselt numbers. We examined the results under both linear and quadratic variation of the surface temperature. Our simulations established that the impact of Marangoni flow is useful for an enhancement of the heat transfer rate.

클리브랜드 개방식 장치를 이용한 2-propanol+acid류 계의 하부 인화점 측정 및 예측 (The Measurement and Estimation of Lower Flash Point for 2-Propanol+Acid Systems Using Cleveland Open Cup Apparatus)

  • 하동명;이성진
    • 한국화재소방학회논문지
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    • 제21권4호
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    • pp.32-37
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    • 2007
  • 인화점의 정보를 확보하는 것은 화재 및 폭발의 예방을 위해 대단히 중요하다. 본 연구에서는 2-propanol+acetic acid 계와 2-propanol+n-propionic acid 계의 하부 인화점을 클리브랜드 개방식 장치를 이용하여 측정하였다. 실험값은 Raoult의 법칙, Wilson 식과 NRTL 식에 의해 계산된 값과 비교하였다. 그 결과, Wilson 식과 NRTL 식에 의한 예측값이 Raoult의 법칙에 의한 예측값 보다 실험값에 더욱 근접하였다. 또한, NRTL 식의 실험값에 대한 모사성이 Wilson 식의 그것 보다 우수하였다.

광섬유 2차 코팅다이 형상 변화에 따른 유리섬유 고속 코팅공정 영향성 해석연구 (Numerical Study of Secondary Coating Die Geometry Effects on High Speed Optical Glass Fiber Coating Process)

  • 김경진;박중윤
    • 반도체디스플레이기술학회지
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    • 제18권3호
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    • pp.12-18
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    • 2019
  • The protective double layer polymer coatings on silica optical fibers are realized by wet-on-wet liquid coating process and they play an important role in final quality of mass produced optical fibers. This numerical study aims to analyze the effects of secondary coating die design parameters by employing two dimensional axisymmetric model of coating cup and coating die geometry and computational fluid dynamics simulations which include temperature dependent viscosity of polymer coating liquids and viscous dissipation heating. Under high speed fiber drawing conditions and pressurized coating liquid supply, the effects of converging die angle are investigated in order to appreciate the change of coating liquid flow patterns such as flow recirculation zone near coating die as well as primary and secondary coating layer thicknesses. The auxiliary coating die to converging coating die is also tested and the results find that this concept is advantageous in achieving stable double layer coatings on silica glass fiber.