• Title/Summary/Keyword: Two layer

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Study on Formation Mechanism of Iron Oxide Nanoparticles (산화철 나노입자의 형성 메커니즘에 대한 연구)

  • Kim, Dong-Young;Yoon, Seok-Soo;Takahashi, Migaku
    • Journal of the Korean Magnetics Society
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    • v.22 no.5
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    • pp.167-172
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    • 2012
  • In order to analyze the formation mechanism of iron oxide nanoparticles, we measured the heat flow of $Fe(OL)_3$ precursor with temperature, and TEM images and AC susceptibility of aliquots samples sequentially taken from the reaction solution, respectively. The thermal decomposition of two OL-chain from $Fe(OL)_3$ produced the Fe-OL monomer, which were contributed to the formation of iron oxide nanoparticles. In the initial stage of nanoparticles formation, the small iron oxide nanoparticles had ${\gamma}-Fe_2O_3$ structure. However, as the iron oxide nanoparticles were rapidly growth, the iron oxide nanoparticles showed ${\gamma}-Fe_2O_3$-FeO core-shell structure which the FeO layer was formed on the surface of ${\gamma}-Fe_2O_3$ nanoparticles by insufficient oxygen supply from the reaction solution. These nanoparticles were transformed to $Fe_3O_4$ structure by oxidation during long aging time at high temperature. Finally, the $Fe_3O_4$ nanoparticles with high saturation magnetization and stable in the air could be easily synthesized by the thermal decomposition method.

Magnetism and Magnetocrystalline Anisotropy of CoFe Thin Films: A First-principles Study (CoFe 박막의 자성과 자기결정이방성에 대한 제일원리계산)

  • Kim, Eun Gu;Jekal, So Young;Kwon, Oryong;Hong, Soon Cheol
    • Journal of the Korean Magnetics Society
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    • v.24 no.2
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    • pp.35-40
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    • 2014
  • We investigate magnetism and magnetocrystalline anisotropy of CoFe thin films, using VASP code in GGA. In this study Co-terminated and Fe-terminated 5-layer CoFe thin films are employed. The Co-terminated CoFe thin film shows two total energy minima at 2-dimensional lattice constants of $2.45{\AA}$ and $2.76{\AA}$. The film of $2.45{\AA}$ has fcc-like structure and the film of $2.76{\AA}$ has bcc-like structure similarly to a bulk CoFe alloy. And the fcc-like film is more stable by the energy difference of about 160 meV compared to the bcc-like film. The Fe-terminated CoFe film shows very complicated behaviour of total energy which is suspected to be closely related to its complex magnetic structure. The Co-terminated CoFe film of $2.76{\AA}$ shows perpendicular magnetocrystalline anisotropy (MCA), while the film of 2.45 does parallel MCA. The Fe-terminated CoFe film also exhibits similar MCA behaviour.

Mechanical Properties of Natural Rubber/Acrylonitrile-Butadiene Rubber Blends and Their Adhesion Behavior with Steel Cords (Natural Rubber/Acrylonitrile-Butadiene Rubber 블렌드의 기계적 물성과 강선과의 접착거동)

  • Sohn, Bong-Young;Nah, Chong-Woon
    • Elastomers and Composites
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    • v.36 no.2
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    • pp.111-120
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    • 2001
  • Mechanical properties and their adhesion behavior with zinc- and brass-plated steel cords of natural rubber/acrylonitrile-butadiene blend compounds were investigated as a function of blend ratio. The Mooney viscosity and stress relaxation time were found to be lowered with increasing NBR content. Tensile modulus generally increased with increasing NBR content. Tensile stress at break stayed constant up to about 40 phr and showed minimum at $50{\sim}60 phr$, and thereafter increased with increasing NBR content. Strain at break decreased linearly below 50 phr, and above the level it showed nearly constant value. Based on the abrupt drops in elastic modulus and tan ${\delta}$ peak, the glass transition temperature of NR and NBR were found to be -55 and $-10^{\circ}C$, respectively. In the case of NR/NBR blend compounds, two distinct transition points were observed and each transition position was not affected by NBR level indicating an incompatible nature of NR/NBR blend system. The pullout force and rubber coverage decreased to the level of about 40% to that of pure m compound, when the 50 phr of NR was replaced by NBR. However, the pure NBR compound showed the comparable adhesion performance with NR(${\sim}90%$). The sulfur concentration was found to become lower with the increased NBR content at the adhesion interface based on the Auger spectrometer results, representing a lack of adhesion layer formation, and this was explained for a possible cause of low adhesion performance with adding NBR.

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AN EXPERIMENTAL STUDY ON THE EFFECT OF THE GALVANIC CURRENT ON THE MANDIBULAR GROWTH IN RAT (Galvani전류가 백서의 하악골 성장에 미치는 영향에 관한 실험적 연구)

  • Yang, Sang-Duk;Suhr, Cheng Hoon
    • The korean journal of orthodontics
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    • v.18 no.1 s.25
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    • pp.189-207
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    • 1988
  • In almost all biologic systems, mechanically induced electric charge separation is a fundamental phenomenon. Since the hypothesis was established that the generation of electric potentials in bone by mechanical stress including muscular force might control the activity in bone by mechanical stress including muscular force might control the activity of osseous cells and their biopolymeric byproduct, the concept of electrically mediate growth mechanism, which involves biological growth and bone remodeling by any means, in living systems has been applied clinically and experimentally to orthopedic fracture repair, the regulation of orthodontic tooth movement, epiphyseal cartilage regeneration, etc. On the other hand, recent numerous research data available show apparently that the mandibular condyle has the characteristics of growth center as well as growth site. In addition, there exists a considerable difference of opinion as to the role of external pterygoid muscle in condylar growth. In view of these evidences, this. experiment was performed to investigate the effect of the galavic current on the growth of the mandible and condyle for elucidating the nature of condylar growth. The bimetallic device was composed of silver and platinum electrode connected with resistor (3.9 Mohm), which was expected to produce galvanic current of 23.6 nA according to the galvanic principle. The 25 Sprague-Dawley rats were divided into two group, 2 week group comprising 8 animals exposed to satanic current for 2 weeks and 3 control animals not exposed for 2 weeks, 4 week group comprising 10 animals in experimental group and 4 animals in control group applied for 4 weeks respectively. The experimental rats were subjected to application of the galvanic current invasively to codylar head surface and the control groups with sham electrode. On the basis of anatomic and histologic data from the mandibular condyle of experimental and control group, the following results were obtained. 1. After 2 weeks, there was no increase of mandibular size in experimental group over that of the control group. 2. After 4 weeks, the size of the condylar head was larger in experimental group than that of the control. 3. In 2 week group, the thickness of the mitotic compartment and hypertrophic chondroblastic layer was increased in experimental group. 4. In 4 week group, the number and the size of the hypertrophic chondroblasts were increased significantly on experimental group over that of the control group. 5. The application of the satanic current caused an increase in chondrocytic hypertrophy and intercellular matrix in both groups.

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Environment and Vegetation Characteristics of Aconitum austrokoreense Koidz. habitats (세뿔투구꽃의 자생지 식생과 환경특성)

  • Park, Jeong-Geun;Pi, Jung-hun;Jung, Ji-young;Park, Jeong-seok;Yang, Hyung-ho;Lee, Cheul-ho;Suh, Gang-uk;Son, Sung-won
    • Korean Journal of Environment and Ecology
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    • v.30 no.5
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    • pp.896-907
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    • 2016
  • The habitat characteristics of Aconitum austrokoreense Koidz. were investigated to provide basic data for conservation and restoration. The altitude ranged from 260m to 728m with inclinations of $4-39^{\circ}$. As a result of vegetation survey within natural populations, a total of 147 taxa were identified inside 20 quadrates in 7 natural habitats. The importance value of Aconitum austrokoreense was 23.0% based on the coverage and frequency of the herbaceous layer and sat is more dominant. Species diversity was 1.23, and dominace and evenness were found to be 0.22 and 0.77, respectively. The soil type were silty loam (four sites), sandy loam (two sites) and loam (one site). The average field organic matter was 7.83% and the total nitrogen and pH were 0.35, and 5.69. Correlation analysis between environmental factors and population characteristic showed the correlations between chlorophyll content and slope, flowering rate and soil humidity. Conservation on habitats conditions is important for stable maintenance the flora and the surrounding area including habitats has to be designated a protection area for habitats conservation.

Effect of Cation Substitution on the Lattice Vibration and Crystal Structure of Magnetic RuSr1.9A0.1GdCu2O8 (A = Ca, Sr, and Ba) Superconductors

  • Kim, Tae-Woo;Yang, In-Sang;Hwang, Seong-Ju
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2559-2562
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    • 2009
  • The lattice vibration and crystal structure of alkaline earth metal-substituted $RuSr_{1.9}A_{0.1}GdCu_{2}O_{8}$ (A = Ca, Sr, and Ba) have been investigated with micro-Raman spectroscopy. The present $RuSr_{1.9}A_{0.1}GdCu_{2}O_{8}$ materials show not only several weak Raman peaks corresponding to the vibrations of $O_{Cu}$ and $O_{Ru}$ but also strong characteristic phonon lines related to $O_{Sr}$ vibration mode. A comparison between the frequency of $O_{Sr}$ vibration and the bond distances of (Ru$O_{Sr}$) and (Cu‒$O_{Sr}$) in the present ruthenocuprates reveals that the vibration energy of $O_{Sr}$ is mainly dependent on the bond distance of (Ru‒$O_{Sr}$). The peak splitting of the $O_{Sr}$ phonon lines was observed for the unsubstituted $RuSr_{1.9}A_{0.1}GdCu_{2}O_{8}$, suggesting the existence of two different (Ru‒$O_{Sr}$) bond distances. Such a peak splitting caused by the appearance of low-energy shoulder reflects the presence of internal charge transfer pathway from the $RuO_2$ plane to the superconductive $CuO_2$ one. After the substitution of Sr with Ca or Ba, the low-energy shoulder peak of $O_{Sr}$ vibration becomes suppressed, underscoring the depression of internal charge transfer between the $RuO_2$ and $CuO_2$ planes. The weakened role of $RuO_2$ layer as charge reservoir in the $RuSr_{1.9}A_{0.1}GdCu_{2}O_{8}$8 (A = Ca, Ba) would be responsible for the depression of $T_c$ upon the Ca/Ba substitution.

Bioactivity of an Extract of Lespedezea Cuneata G. Don to Rabbit Corpus Cavernosum Smooth Muscle Tone (야관문(Lespedezea cuneata G. Don) 추출물이 토끼 음경해면체 평활근에 미치는 생리활성)

  • Chung, Young-Ho;Lim, Chi-Hwan
    • Korean Journal of Agricultural Science
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    • v.32 no.1
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    • pp.63-70
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    • 2005
  • The extracts in n-hexane layer from Lespedezea cuneata G. Don exelled at sexual activity according to in vitro experiment using biopsy of rabbit corpus cavernosum to investigate effects on sexual function. The extracts were injected into 9 samples at $10{\mu}l$. The lowest relaxation was showed at sample C, $4.8{\pm}1.4%$ and the highest relaxation was showed at sample A, $20.2{\pm}6.0%$. The relaxation by every sample, except sample C and G-1, were higher than by $10^{-7}M$ ACh, $7.8{\pm}5.1%$, and their effects were above 10%. Also, the extracts were injected into 9 samples at $15{\mu}l$. The lowest relaxation was showed at sample C, $15.4{\pm}9.7%$ and the highest relaxation was showed at sample J, $54.8{\pm}9.7%$. The relaxation by sample A and D was as much as by $10^{-6}M$ ACh, $28.0{\pm}20.1%$. The relaxation by sample H was $41.9{\pm}7.3%$. The relaxation by sample J was $54.8{\pm}9.7%$ and it was higher than by $10^{-5}M$ ACh, $53.9{\pm}25.9%$. Also, the extracts were injected into 9 samples at $20{\mu}l$. The lowest relaxation was showed at sample E, $28.9{\pm}0.6%$ and it was a little higher than by $10^{-6}M$ ACh. The relaxation by sample G was as much as by $10^{-5}M$ ACh. The two higher relaxation were showed at sample H, $99.4{\pm}16.0%$ and J, $95.7{\pm}7.2%$, and their relaxation against contraction reaction by PhE were near 100%. Experiment by sample I was not performed for lack of sample amount.

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A Design and Adaptation Technique of UML-based Layered Meta-Model for Component Development (컴포넌트 개발을 위한 UML 기반의 계층형 메타 모델 설계 및 적용기법)

  • Lee, Sook-Hee;Kim, Chul-Jin;Cho, Eun-Sook
    • Journal of the Korea Society for Simulation
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    • v.15 no.2
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    • pp.59-69
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    • 2006
  • Component-based software development is introduced as a new development paradigm in software development method. This approach is different from existing software development approach because it is based on reusable and autonomous unit, component. Therefore, component-based development(CBD)is divided into two stages; component development process and component assembly process; application development process. Component development process is the core of CBD because component has a key for good software. Currently many methodologies or tools have been introduced by various academies or industries. However, those don't suggest systematic and flexible modeling techniques adaptable easily into component development project. Existing approaches have a unique orarbitrary modeling technique or provide heuristic guidelines for component modeling. As a result, many component developers are faced with a difficult problems; how to developcomponent models, when develop which diagrams, and so on. In order to address this problem, we suggest a meta-model driven approach for component development in this paper. We provide meta-models according to both layer and development phase. We expect that suggested meta-models allow component developers to develop appropriate models of the time.

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Development of Two Dimensional Blade Section with High Efficiency for Marine Propeller (선박 프로펠러용 고효율 2차원 날개단면 개발)

  • Na, Yun-Cheol;Song, In-Haeng;Ahn, Jong-Woo
    • Journal of the Society of Naval Architects of Korea
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    • v.34 no.1
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    • pp.11-23
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    • 1997
  • This paper contains a new approach to blade section design method for marine propellers. The hydrodynamic characteristics of 2-D section are highly influenced by its geometrical parameters i.e., thickness and camber distributions and leading edge radius etc. To consider fully turbulent flow field near 2-D section. the finite volume method with k-${\varepsilon}$ turbulent model which solve Reynolds time averaged Navier-Stokes(RANS) equation is applied. In this study, O-type grid system that can provide many calculation points on blade surface is used. The results were compared with those of the experiment of NACA0012 to confirm the accuracy of the developed codes. The goal of this study is the development of a blade section with high efficiency and low drag. To achieve this, we carried out the tests of lift, drag and cavitation characteristics in cavitation tunnel. The results of experiment were compared with numerical results in order to validate the proposed blades design method. By comparing the numerical results with the experiments, we found that the new blade section, KH28 allows superior performance in efficiency and cavitation avoidance characteristics. We further investigated the blade section design method and an application study of this section, KH28 to apply to the marine propeller. In order to improve the accuracy of numerical results on prediction of lift and drag, we conclude here that the 2-layer boundary model must be used.

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Estimatation of Mean Velocity from Surface Velocity (표면유속을 이용한 평균유속 추정방법의 개발)

  • Roh, Young-Sin;Yoon, Byung-Man;Yu, Kwon-Kyu
    • Journal of Korea Water Resources Association
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    • v.38 no.11
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    • pp.917-925
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    • 2005
  • LSIV (Large Scale Image Velcocimetry) Is one of the image-based velocity measurement techniques. Since it measures surface velocities, it gives simple and inexpensive way to measure velocity, compared to other methods. Because of these advantages, there have been many studies to apply LSIV to the river discharge measurement in the field. Measuring the discharge by using LSIV requires a method which converts a surface velocity to a mean velocity In the present study, experiments and analysis of vortical velocity profile of open-channel flow in various conditions were performed to develop methods which estimate a mean velocity from a surface velocity. The result of this experiment reveals that velocity-dip phenomena occur at free-surface layer in open channel flow and Froude number affects more than bed roughness does. Two methods for estimating the mean velocity were proposed. One is to correct the wake law's profiles by using the difference of surface velocity from the mean velocity, and the other is to use the ratio of mean and surface velocities. The result of applying these methods in an experiment shows that they are quite accurate having an error of approximately $6\%$ only.