• Title/Summary/Keyword: Tungsten Carbide (WC)

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Characteristic of HVOF AISI316-WC Coating Layer on Stainless Steel Separator for PEMFC (고분자 전해질 연료전지용 스테인리스강 분리판의 HVOF AISI316-WC 코팅층 특성)

  • Nam, Dae-Geun;Kang, Nam-Hyun;Park, Yeong-Do;Kim, Young-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.1-5
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    • 2008
  • Stainless steels have been widely considered as metallic separators, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the separators and electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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Characteristics of Diamond Films Deposited on Cemented Tungsten Carbide Substrate (초경합금기판 위에 성장되는 다이아몬드 막의 특성)

  • 김봉준;박상현;박재윤
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.7
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    • pp.387-394
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    • 2004
  • Diamond films were deposited on the cemented tungsten carbide WC-Co cutting insert substrates by using both microwave plasma chemical vapor deposition(MWPCVD) and radio frequency plasma chemical vapor deposition (RFPCVD) from $CH_4$$-H_2$$-O_2$ gas mixture. Scanning electron microscopy and X-ray diffraction techniques were used to investigate the microstructure and phase analysis of the materials and Raman spectrometry was used to characterize the quality of the diamond coating. Diamond films deposited using MWPCVD from $CH_4$$-H_2$$-O_2$ gas mixture show a dense, uniform, well faceted and polycrystalline morphology. The compressive stress in the diamond film was estimated to be (1.0∼3.6)$\pm$0.9 GPa. Diamond films which were deposited on the WC-Co cutting insert substrates by RFPCVD from $CH_4$$-H_2$$-O_2$ gas mixture show relatively good adhesion, very uniform, dense and polycrystalline morphology.

Optimal Grinding Condition of Tungsten Carbide(WC) for Aspheric Glass Lens Using DOE (DOE를 적용한 비구면 Glass 렌즈 성형용 초경합금(WC) 코어 연삭가공 최적화)

  • Kim, Hyun-Uk;Jeong, Sang-Hwa;Ahn, Jun-Hyung;Cha, Du-Hwan;Lee, Dong-Gil;Kim, Sang-Suk;Kim, Hye-Jeong;Kim, Jeong-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.5 no.4
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    • pp.41-45
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    • 2006
  • In recent years, the demands of the aspheric glass lenses increase since it is difficult to obtain the desirable performance in the plastic lens. Glass lens is manufactured by the forming with high precision mold core. This paper presents the analysis of optimal grinding condition of tungsten carbide(WC, Co 0.5%) using design of experiments(DOE). The process parameters are turbin spindle, work spindle, feedrate and depth of cut. The experiments results are evaluated by MINITAB software.

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Binder-free Tungsten Carbide Fabricated by Pulsed Electric Current Sintering

  • Shimojima, K.;Hosokawa, H.;Nakajima, T.;Mizukami, M.;Yamamoto, Y.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.621-622
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    • 2006
  • In this paper, we show some experimental results of binder-free WC sintered by Pulsed Electric Current Sintering (PECS) also known as Field Assisted Sintering Technology (FAST). These binder-free WC have extremely hardness and stiffness. However, these mechanical properties are dependent on the sintering condition, e.g., maximum temperature, applied pressure, etc. We show some relationship between mechanical properties and sintering condition to improve to sinter the binder-free WC.

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Investigation on the Growth of Tungsten Carbide Layer as a Buffer for GaN-on-Si Technology (GaN-on-Si 기술을 위한 탄화텅스텐 버퍼층의 성장에 관한 연구)

  • Cho, Sungmin;Choi, Junghoon;Choi, Sungkuk;Cho, Youngji;Lee, Seokhawn;Chang, Jiho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.1
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    • pp.1-6
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    • 2017
  • Tungsten carbide (WC) has been suggested as a new buffer layer for the GaN-on-Si technology. We have investigated and optimized the sputtering condition of WC layer on the Si-substrate. We confirmed the suppression of the Si melt-back phenomenon. In addition, surface energy of WC/Si layer was measured to confirm the possibility as a buffer layer for GaN growth. We found that the surface energy(${\gamma}=82.46mJ/cm^2$) of WC layer is very similar to that of sapphire substrate(${\gamma}=82.71mJ/cm^2$). We grow GaN layer on the WC buffer by using gas-source MBE, and confirm that it is available to grow a single crystalline GaN layer.

Development of Uniaxial Tensile Test Method to Evaluate Material Property of Tungsten Carbide-Cobalt Alloys for Cold Forging Dies (냉간단조 금형 WC-Co합금의 인장시험방법 개발 및 물성평가)

  • Kwon, I.W.;Seo, Y.H.;Jung, K.H.
    • Transactions of Materials Processing
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    • v.27 no.6
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    • pp.370-378
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    • 2018
  • Cold forging, carried out at room temperature, leads to high dimensional accuracy and excellent surface integrity as compared to other forging methods such as warm and hot forgings. In the cold forging process, WC-Co (Tungsten Carbide-Cobalt) alloy is the mainly used material as a core dies because of its superior hardness and strength as compared to other structural materials. For cold forging, die life is the most significant factor because it is directly related to the manufacturing cost due to periodic die replacement in mass production. To investigate die life of WC-Co alloy for cold forging, mechanical properties such as strength and fatigue are essentially necessary. Generally, uniaxial tensile test and fatigue test are the most efficient and simplest testing method. However, uniaxial tension is not efficiently application to WC-Co alloy because of its sensitivity to alignment of the specimen due to its brittleness and difficulty in thread machining. In this study, shape of specimen, tools, and testing methods, which are appropriate for uniaxial tensile test for WC-Co alloy, are proposed. The test results such as Young's modulus, tensile strength and stress-strain curves are compared to those in previous literature to validate the proposed testing methods. Based on the validation of test results it was concluded that the newly developed testing method is applicable to other cemented carbides like Titanium carbides with high strength and brittleness, and also can be utilized to carry out fatigue tests for further investigation on die life of cold forging.

Preparation of WC Powders by SHS Process in the Presence of Alkali Salts (자전연소합성법에서의 알칼리염을 이용한 WC 분말의 제조)

  • Won, Hyung-Il;Nersisyan, Hayk;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.152-156
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    • 2007
  • Tungsten carbide powder was synthesized by SHS (self-propagating high-temperature synthesis). Except $WO_{3}$, each concentration of raw material ($WO_{3},\;Mg,\;NaCl,\;Na_{2}CO_{3},\;C$) was investigated. Final product was characterized by XRD and SEM. X-ray data demonstrated that the $NaCl+Na_{2}CO_{3}$ combined mixture has superiority in the WC formation process. Single phase and submicrometer WC powder was synthesized at the temperature below $1600^{\circ}C$. The role of sodium salts in combustion process was discussed, and chemical mechanism of WC formation was proposed. WC powder prepared by salt-assisted combustion synthesis has a size $0.2{\sim}3\;{\mu}m$ and low agglomeration degree.

Development of Nano-sized WC Powder for Hardmetals

  • Yamamoto, Yoshiharu;Mizukami, Masahiko
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.342-343
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    • 2006
  • In order to develop the nano-sized WC powder that improved the hardness of hardmetals, carbothermal reduction of WO3 by C was examined by using the thermogravimetric analysis. At the direct carburization reaction path of $WO_3{\rightarrow}WO_{2.72}{\rightarrow}WO_2{\rightarrow}W{\rightarrow}W_2C{\rightarrow}WC$, the nano-sized grain was generated at the reaction stage $WO_{2.72}$ to $WO_2$ and W. For trial production, the intermediate products which consists of metal and carbide phases obtained by the first heating has been carburized to the final WC powder. We succeeded in the development of the WC powder of about 70nm. In addition, the nano-sized WC powder in which the vanadium of the most effective grain growth inhibitor was uniformly dispersed was developed.

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A Comparative Study of Transistor and RC Pulse Generators for Micro-EDM of Tungsten Carbide

  • Jahan, Muhammad Pervej;Wong, Yoke San;Rahman, Mustafizur
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.4
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    • pp.3-10
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    • 2008
  • Micro-electrical discharge machining (micro-EDM) is an effective method for machining all types of conductive materials regardless of hardness. Since micro-EDM is an electro-thermal process, the energy supplied by the pulse generator is an important factor in determining the effectiveness of the process. In this study, an investigation was conducted on the micro-EDM of tungsten carbide (WC) to compare the performance of transistor and resistance/capacitance (RC) pulse generators in obtaining the best quality micro-hole. The performance was measured by the machining time, material removal rate, relative tool wear ratio, surface quality, and dimensional accuracy. The RC generator was more suited for minimizing the pulse energy, which is a requirement for fabricating micro-parts. The smaller-sized debris formed by the low-discharge energy of RC micro-EDM could be easily flushed away from the machined zone, resulting in a surface free of burrs and resolidified molten metal. The RC generator also required much less time to obtain the same quality micro-hole in WC. Therefore, RC generators are better suited for fabricating micro-structures, producing good surface quality and better dimensional accuracy than the transistor generators, despite their higher relative tool wear ratio.

Characteristics of Rhenium-Iridium coating thin film on tungsten carbide by multi-target sputter

  • Cheon, Min-Woo;Kim, Tae-Gon;Park, Yong-Pil
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.328-331
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    • 2012
  • With the recent development of super-precision optical instruments, camera modules for devices, such as portable terminals and digital camera lenses, are increasingly being used. Since an optical lens is usually produced by high-temperature compression molding methods using tungsten carbide (WC) alloy molding cores, it is necessary to develop and study technology for super-precision processing of molding cores and coatings for the core surface. In this study, Rhenium-Iridium (Re-Ir) thin films were deposited onto a WC molding core using a sputtering system. The Re-Ir thin films were prepared by a multi-target sputtering technique, using iridium, rhenium, and chromium as the sources. Argon and nitrogen were introduced through an inlet into the chamber to be the plasma and reactive gases. The Re-Ir thin films were prepared with targets having a composition ratio of 30 : 70, and the Re-Ir thin films were formed with a 240 nm thickness. Re-Ir thin films on WC molding core were analyzed by scanning electron microscope (SEM), atomic force microscope (AFM), and Ra (the arithmetical average surface roughness). Also, adhesion strength and coefficient friction of Re-Ir thin films were examined. The Re-Ir coating technique has received intensive attention in the coating processes field because of promising features, such as hardness, high elasticity, abrasion resistance and mechanical stability that result from the process. Re-Ir coating technique has also been applied widely in industrial and biomedical applications. In this study, WC molding core was manufactured, using high-performance precision machining and the effects of the Re-Ir coating on the surface roughness.