• Mass Spectrometry Letters
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• v.6 no.4
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• pp.105-111
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• 2015

Sixteen compounds of Neobalanocarpus heimii were successfully identified directly from their plant extract using a triple quadrupole LC-MS/MS system. In order to fulfil the objectives of this work, a series of stilbene oligomers of various degrees of condensation were isolated and their structure are characterized. Out of these, four are resveratrol dimers, three trimers, and nine tetramers. The isolation process was done on a fully automated semi-preparative HPLC system. Their structures were elucidated on the basis of 1D- and 2D-NMR as well as MS data. The mass fragmentation patterns of the compounds were recorded and a retrievable in-house library was built to keep the data. In order to demonstrate the potential of this approach, the polyphenolic crude extract was analysed with the LC-MS/MS system and the MS/MS spectra extracted for each chromatographic peak of interest. The fragmentation patterns were compared with those of anticipated pure compounds that were previously recorded. All compounds were successfully identified. It is therefore believed that the LC-MS/MS potential for dereplication of structurally similar compounds in a crude mixture was thus firmly established.

• Journal of the Mineralogical Society of Korea
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• v.11 no.2
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• pp.106-116
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• 1998

The adsorption of Cs-137 and Sr-90 onto kaolinite in prescence of major groundwater cations (Ca2+, K+, Na+) with different concentrations was simulated by using triple-layer surface complexation model (TL-SCM). The site density (8.73 sites/nm2) of kaolinite used for TL-SCM was calculated from it's CEC and specific surface area. TL-SCM modeling results indicate that concentrations dependence on 137Cs and 90Sr adsorption onto kaolinite as a function of pH is best modeled as an outer-sphere surface reaction. This suggests that Cs+ and Sr2+ are adsorbed at the $\beta$-layer in kaolinite-water interface where the electrolytes, Nacl, KCl and CaCl2, bind. However, TL-SCM results on Sr adsorption show a discrepancy between batch data and fitting data in alkaline condition. This may be due to precipitation of SrCO3 and complexation such as SrOH+. Intrinsic reaction constants of ions obtained from model fit are as follows: Kintcs=10-2.10, KintSr=10-2.30, KintK=10-2.80, KintCa=10-3.10 and KintNa=10-3.32. The results are in the agreement with competition order among groundwater ions (K+>Ca2+>Na+) and sorption reference of nuclides (Cs-137>Sr-90) at kaolinite-water interface showed in batch test.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• v.2
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• pp.131-136
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• 2006

Commercial uses of GPS have been growing rapidly with applications for aircraft, ship, and land vehicle navigation as well as for surveying and time keeping. The next generation GPS and Japanese QZS (Quasi Zenith Satellite) will provide three different civil signals. Galileo will also provide several types of civil signals. The availability of the third civil frequency has obvious advantages to instantaneous carrier phase accuracy and ambiguity resolution for centimeter level measurements. This paper discusses the effects of additional new civil signals for the high accuracy positioning in urban areas based on simulation using practical raw data. As for constellation, only GPS and GPS+QZS are considered. For positioning, a short distance baseline is assumed in order to disregard atmosphere effects. In this simulation, mask angle and signal conditions were fixed and ambiguity success rates were compared between different triple frequency combination scenarios. The coefficient of reflection was set randomly from 0.05 to 0.5 and the multipath delay was also set randomly from 5-100 m. Visible satellites and signal strength were determined by raw data collected in Tokyo by car. These simulation results have confirmed that the availability of high accuracy positioning will increase in all scenarios if we use GPS+QZS with triple frequencies.

• Journal of the Korean Magnetic Resonance Society
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• v.16 no.2
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• pp.172-184
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• 2012

The prokaryotic molecular chaperone Hsp33 achieves its holdase activity upon response to oxidative stress particularly at elevated temperature. Despite many structural studies of Hsp33, which were conducted mainly by X-ray crystallography, the actual structures of the Hsp33 in solution remains controversial. Thus, we have initiated NMR study of the reduced, inactive Hsp33 monomer and backbone NMR assignments were obtained in the present study. Based on a series of triple resonance spectra measured on a triply isotope-[$^2H/^{13}C/^{15}N$]-labeled protein, sequence-specific assignments of the backbone amide signals observed in the 2D-[$^1H/^{15}N$]TROSY spectrum could be completed up to more than 96%. However, even considering the small portion of non-assigned resonances due to the lack of sequential connectivity, we confirmed that the total number of observed signals was quite smaller than that expected from the number of amino acid residues in Hsp33. Thus, it is postulated that peculiar dynamic properties would be involved in the solution structure of the inactive Hsp33 monomer. We expect that the present assignment data would eventually provide the most fundamental and important data for the progressing studies on the 3-dimensional structure and molecular dynamics of Hsp33, which are critical for understanding its activation process.

• Journal of East Asia Management
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• v.2 no.1
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• pp.63-92
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• 2021

Human activities have been putting a great burden on the earth, leading to many serious problems, such as lack of resources, ecological degradation and air degradation. Although many countries have recognised this circumstance and have developed some sustainable development strategies, the earth still needs research on sustainability in different views and various industries. The nursing industry has grown with the ageing of the global population in recent years, and professional nursing institutions could relieve structural deterioration caused by the ageing population in family, social, economic and cultural. Hence, exploring the key criteria of organisational sustainability in the nursing industry is of the utmost priority. This paper puts forward an evaluation framework to identify the key criteria of organisational sustainability. After connections with nursing homes A and B in China, the author adopts literature research to confirm the criteria system which is based on triple bottom line, utilises analytical network process method to design the network hierarchy analysis model and importance comparison questionnaires to collect experts' first-hand data, and uses technical software - Super Decisions to integrate data and obtain final results. The results recommend three top-ranked criteria in the entire system, eco-recruitment, eco-procurement and corporate social responsibility are discussed with some professional suggestions in the end. The limitations are also extended in the last chapter to provide future research perspectives.

• Current Optics and Photonics
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• v.7 no.6
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• pp.673-682
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• 2023

In this paper, a three-key triple data encryption algorithm (TDEA) of a digital cryptosystem based on phase-shifting interferometry is proposed. The encryption for plaintext and the decryption for the ciphertext of a complex digital hologram are performed by three independent keys called a wavelength key k₁(λ), a reference distance key k₂(d_r) and a holographic encryption key k₃(x, y), which are represented in the reference beam path of phase-shifting interferometry. The results of numerical simulations show that the minimum wavelength spacing between the neighboring independent wavelength keys is about δλ = 0.007 nm, and the minimum distance between the neighboring reference distance keys is about δd_r = 50 nm. For the proposed three-key TDEA, choosing the deviation of the key k₁(λ) as δλ = 0.4 nm and the deviation of the key k₂(d_r) as δd_r = 500 nm allows the number of independent keys k₁(λ) and k₂(d_r) to be calculated as N(k₁) = 80 for a range of 1,530-1,562 nm and N(d_r) = 20,000 for a range of 35-45 mm, respectively. The proposed method provides the feasibility of independent keys with many degrees of freedom, and then these flexible independent keys can provide the cryptosystem with very high security.

• Journal of KIISE:Software and Applications
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• v.32 no.12
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• pp.1238-1246
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• 2005

This thesis is written with web security module for safe data transmission between heterogeneous systems(ex. OS). Web system has allowed users to have great convenience and a lot of information. Though web service business has been progressed much, because of the limitation of it's own system, lots of loss, derived from data spillage which is the weakest point of security, has also followed. Suggested security module is realized by two module. One for server security module for web server, the other is client security module for client. The security structure, suggested on this thesis guarantee safe data transmission by only simple installation of modules in clients and servers. for speed sensitive transmission between web server and browser, Triple-DES, symmetric encryption system suitable for fast encryption communication, is adapted. To solve problems caused from key management, Diffie-Hellman's key exchange algorithm is adapted. By this method, all symmetric encryption troubles from key distribution and management, speed could be work out a solution. And Diffie-Hellman type algorithm secures Authentication for safe data Protection.

• Journal of KIISE
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• v.43 no.4
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• pp.450-459
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• 2016

Every year, RDFS data tends further toward scalability; hence, the manner of SPARQL processing needs to be changed for fast query. The query processing method of SPARQL has been studied using a scalable distributed processing framework. Current studies indicate that the query engine based on the scalable distributed processing framework i.e., Hadoop(MapReduce) is not suitable for real-time processing because of the repetitive tasks; in addition, it is difficult to construct a query engine based on an In-memory Distributed Query engine, because distributed structure on the low-level is required to be considered. In this paper, we proposed a method to construct a query engine for improving the speed of the query process with the mass triple data. The query engine processes the query of SPARQL using the SparkSQL, which is an In-memory based, distributed query processing framework. SparkSQL is a high-level distributed query engine that facilitates existing SQL statement. In order to process the SPARQL query, after generating the Algebra Tree using Jena, the Algebra Tree is required to be translated to Spark Algebra Tree for application in the Spark system, and construction of the system that generated the SparkSQL query. Furthermore, we proposed the design of triple property table based on DataFrame for more efficient query processing in the Spark system. Finally, we verified the validity through comparative evaluation with the query engine, which is the existing distributed processing framework.

• Asian Pacific Journal of Cancer Prevention
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• v.14 no.6
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• pp.3779-3784
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• 2013

Aims: To determine the clinical, pathological and prognostic features associated with triple-negative breast cancer (TNBC). Methods: Clinical and histologic data of 21,749 breast cancer patients who were treated at Tianjin Medical University Cancer Institute and Hospital between July 2002 and December 2011 were collected. Patients were divided into two groups: those with TNBC and those with other types of breast cancer. Patients and tumor characteristics were compared between the two groups using the Chi-square test. The prognostic results of 9,823 patients in the study population were also analyzed to determine long-term survival rates in the two groups of breast cancer patients. Results: Among the breast cancer patients treated in our hospital between 2003 and 2011, 10.4%-13.5% of them had triple-negative breast cancers. Data analyses revealed significant differences in disease onset age, family history of breast cancer, tumor size, tumor histologic grade, lymph note positivity and metastatic status between TNBC and non-TNBC patients. There were also significant differences in 5-year, 7-year and 9-year disease-free and 7-year and 9-year overall survival probability between the groups. Conclusions:TNBC are associated with younger disease onset age, larger tumor size, higher rate of axillary lymph node positivity, and higher tumor histologic grade. TNBC is also related to family history of breast cancer, increased metastatic risk and poor prognosis.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2007.06a
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• pp.837-840
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• 2007

Recently, Not only PC environment but also movile environment using XML for translating data. But the mobile delevopment is more limited but need highler security than PC environment Because there is some important service such as mobile banking. In this paper, We development the system to encrypt and decrypt the XML data in order to protect data, And the system is observing the recommendation of the XML Encryption Syntax and Processing by W3C. When encrypting the data, We use the entryption algorithm DES, Triple-DES, AES, SEED and RSA. and consideration of the mobile environment Last, We test the system at WIPI environment.