• Title/Summary/Keyword: Transport Property

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ANALYSIS OF CHARGE COLLECTION EFFICIENCY FOR A PLANAR CdZnTe DETECTOR

  • Kim, Kyung-O;Kim, Jong-Kyung;Ha, Jang-Ho;Kim, Soon-Young
    • Nuclear Engineering and Technology
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    • v.41 no.5
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    • pp.723-728
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    • 2009
  • The response property of the CZT detector ($5{\times}5{\times}5\;mm^3$), widely used in photon spectroscopy, was evaluated by considering the charge collection efficiency, which depends on the interaction position of incident radiation, A quantitative analysis of the energy spectra obtained from the CZT detector was also performed to investigate the tail effect at the low energy side of the full energy peak. The collection efficiency of electrons and holes to the two electrodes (i.e., cathode and anode) was calculated from the Hecht equation, and radiation transport analysis was performed by two Monte Carlo codes, Geant4 and MCNPX. The radiation source was assumed to be 59.5 keV gamma rays emitted from a $^{241}Am$ source into the cathode surface of this detector, and the detector was assumed to be biased to 500 V between the two electrodes. Through the comparison of the results between the Geant4 calculation considering the charge collection efficiency and the ideal case from MCNPX, an pronounced difference of 4 keV was found in the full energy peak position. The tail effect at the low energy side of the full energy peak was confirmed to be caused by the collection efficiency of electrons and holes. In more detail, it was shown that the tail height caused by the charge collection efficiency went up to 1000 times the pulse height in the same energy bin at the calculation without considering the charge collection efficiency. It is, therefore, apparent that research considering the charge collection efficiency is necessary in order to properly analyze the characteristics of CZT detectors.

Preparation of Anion Exchange Membranes of Cross-linked Poly((vinylbenzyl)trimethylammonium chloride-2-hydroxyethyl methacrylate)/Poly(vinyl alcohol) (가교결합한 Poly((vinylbenzyl)trimethylammonium chloride-2-hydroxyethyl methacrylate)/poly(vinyl alcohol) 음이온 교환막 제조)

  • Kim, Mi-Yang;Kim, Kwang-Je;Kang, Ho
    • Applied Chemistry for Engineering
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    • v.21 no.6
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    • pp.621-626
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    • 2010
  • Anion exchange membranes can be used for reverse electrodialysis for electric energy generation, and capacitive deionization for water purification, as well as electrodialysis for desalination. In this study, anion exchange membranes of poly((vinylbenzyl) trimethylammonium chloride-2-hydroxyethyl methacrylate)/poly(vinyl alcohol) were prepared through the polymerization of (vinylbenzyl)trimethylammonium chloride and 2-hydroxyethyl methacrylate in aqueous poly(vinyl alcohol) solutions, esterification with glutaric acid, and cross-linking reaction with glutaraldehyde. We investigated electrochemical properties for the anion exchange membranes prepared according to experimental conditions. Ion exchange capacity and electrical resistance for the membranes were changed with a variation in the monomer ratio in polymerization. Water uptake and conductivity for the membranes decreased with an increase in the content of glutaric acid in esterification. The change in the time of crosslinking reaction with the formed film and glutaraldehyde affected electrochemical properties such as water uptake, conductivity, or transport number for the membranes. Chronopotentiometry and limiting current density for the anion exchange membranes prepared were measured.

Relationships Between Urban Infrastructure and Travel by the Elderly: Based on the Public Transit Trip Attraction Model for Dong (도시기반시설과 고령자 통행의 상관관계 분석: 행정동 단위 대중교통 통행유입 모형을 중심으로)

  • LEE, Soong-bong;JUNG, Dongjae;CHANG, Justin S.
    • Journal of Korean Society of Transportation
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    • v.33 no.3
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    • pp.268-275
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    • 2015
  • As Korea is predicted to be a super-aged society in the near future, transport policies that internalize the elderly have also drawn attentions. Even though some studies have examined the travel by the elderly with various motives, it is, however, difficult to find references that deal with the unique spatio-temporal characteristics of senior trips. For example, the models by time period have represented the temporal property while a set of independent variables associated with urban infrastructure have addressed the spatial feature. This study was conducted under a trip attraction model for transit. The result shows that transit facilities, commercial areas, and hospitals are the dominant factors to explain the travel by the elderly, particularly during 09:00-17:00.

Thermoelectric Properties of n-Type Half-Heusler Compounds Synthesized by the Induction Melting Method

  • Du, Nguyen Van;Lee, Soonil;Seo, Won-Seon;Dat, Nguyen Minh;Meang, Eun-Ji;Lim, Chang-Hyun;Rahman, Jamil Ur;Kim, Myong Ho
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.6
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    • pp.342-345
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    • 2015
  • The n -type Hf0.25Zr0.25Ti0.5NiSn0.998Sb0.002 Half-Heusler (HH) alloy composition was prepared by using the induction melting method in addition to the mechanical grinding, annealing, and spark plasma sintering processes. Analysis of X-ray diffraction (XRD) results indicated the formation of a pure phase HH structured compound. The electrical and thermal properties at temperatures ranging from room temperature to 718 K were investigated. The electrical conductivity increased with increasing temperatures and demonstrated nondegenerate semiconducting behavior, and a large reduction in the thermal conductivity to the value of 2.5 W/mK at room temperature was observed. With the power factor and thermal conductivity, the dimensionless figure of merit was increased with temperature and measured at 0.94 at 718 K for the compound synthesized by the induction melting process.

Inverted CdSe@ZnS Quantum Dots Light-Emitting Diode using Low-Work Function Polyethylenimine Ethoxylated (PEIE) modified ZnO

  • Kim, Choong Hyo;Kim, Hong Hee;Hwang, Do Kyung;Suh, Kwang S;Park, Cheol Min;Choi, Won Kook
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.148-148
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    • 2015
  • Over the past several years, Colloidal core/shell type quantum dots lighting-emitting diodes (QDLEDs) have been developed for the future of optoelectronic applications. An inverted-type quantum-dot light-emitting-diode (QDLED), employing low work function organic material polyethylenimine ethoxylated(PEIE) (<10 nm)[1] modified ZnO nanoparticles (NPs) as electron injection and transport layer, was fabricated by all solution processing method, instead of electrode in the device. The PEIE surface modifier incorporated on the top of the ZnO NPs film, facilitates the enhancement of both electorn injection into the CdSe-ZnS QD emissive layer by lowering the workfunction of ZnO from 3.58eV to 2.87eV and charge balance on the QD emitter. In this inverted QDLEDs, blend of poly (9,9-di-n-octyl-fluorene-alt-benzothiadiazolo) and poly(N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)benzidine] are used as hole transporting layer (HTL) to improve hole transporting property. At the operating voltage of 7.5 V, the QDLED device emitted spectrally orange color lights with high luminance up to 11110 cd/m2, and showed current efficiency of 2.27 cd/A.[2]

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EO Performances of the Ion Beam Aligned TN-LCD on a Carbon Nitride Thin Film Surface

  • Park, Chang-Joon;Hwang, Jeoung-Yeon;Kang, Hyung-Ku;Seo, Dae-Shik;Ahn, Han-Jin;Kim, Jong-Bok;Kim, Kyung-Chan;Baik, Hong-Koo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1121-1124
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    • 2004
  • Carbon Nitride exhibits high electrical resistivity and thermal conductivity that are similar to the properties shown by diamond-like carbon (DLC) films. These diamond-like transport properties in Carbon Nitride come in a material consisting of $sp^2$-bonded carbon versus the $sp^3$-carbon of DLC. The diamond-like properties and nondiamond-like bonding make NDLC an attractive candidate for applications. Liquid crystal (LC) alignment capabilities with ion beam exposure on carbon nitride thin films and Electro-Optical (EO) performances of the ion-beam aligned twisted nematic liquid crystal display (TN-LCD) with oblique ion beam exposure on the Carbon Nitride thin film surface were studied. An excellent uniform alignment of the nematic liquid crystal (NLC) alignment with the ion beam exposure on the Carbon Nitride thin films was observed. In addition, the good EO properties of the ion-beam-aligned TN-LCD were achieved. Finally, we achieved the residual DC property of the ion-beam- aligned TN-LCD on the Carbon Nitride thin film.

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The Effect of Hydrogen on Mechanical Properties of Gas Pipeline Material: I Tensile property (가스배관 재료의 기계적특성에 미치는 수소의 영향: I 인장특성)

  • Kim, Woo-Sik;Jang, Jae-Il
    • Journal of the Korean Institute of Gas
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    • v.15 no.3
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    • pp.67-73
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    • 2011
  • One of the important topics to prepare the up-coming era of so-called ‘hydrogen economy’ is hydrogen transmission. Pipeline is conceivably the most economic way to consistently and safely transport a large amount of hydrogen over a long distance, which may be strongly requested in hydrogen economy era. As a good starting point for the purpose, one might wonder whether conventional API pipeline steels as designed for natural gas transmission can be used as the hydrogen pipeline materials or not. To answer the question, here we performed a series of micro-/nano-indentations together with tensile tests on the hydrogen-charged API X65, X70 and X100 steels having different strength level. In this paper, from the results of tensile tests, the hydrogen effects on the mechanical behavior in the API steels are systematically evaluated.

Flow Characteristics of R600a in an Adiabatic Capillary Tube (단열 모세관내 R600a의 유동 특성)

  • Ku, Hak-Geun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.2
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    • pp.449-454
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    • 2010
  • In this paper, flow characteristics of R600a in an adiabatic capillary tube were investigated employing the homogeneous flow model. The model is based on fundamental equations of mass, energy and momentum which are solved simultaneously. Two friction factors(Churchill) and viscosity(McAdams) are comparatively used to investigate the flow characteristics. Thermodynamic and transport properties of R600a are calculated employing EES property code. Flow characteristics analysis of R600a in an adiabatic capillary tube is presented to offer the basic design data for the operating parameters. The operating parameters considered in this study include condensation temperature, evaporation temperature, subcooling degree and inner diameter tube of the adiabatic capillary tube. The main results were summarized as follows: condensation and evaporation temperature, inlet subcooling degree and inner diameter tube of an adiabatic capillary tube using R600a have an effect on length of an adiabatic capillary tube. The length of an adiabatic capillary tube using R600a is expressed to the correlation shown in Eq. (15).

Analysis of Subthreshold Swing for Ratio of Channel Length and Thickness of Asymmetric Double Gate MOSFET (비대칭 DGMOSFET의 채널길이와 두께 비에 따른 문턱전압이하 스윙 분석)

  • Jung, Hakkee
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.3
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    • pp.581-586
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    • 2015
  • This paper has analyzed the variation of subthreshold swing for the ratio of channel length and thickness for asymmetric double gate MOSFET. The asymmetric double gate MOSFET has the advantage that the factors to control the short channel effects increase since top and bottom gate structure can be fabricated differently. The degradation of transport property due to rapid increase of subthreshold swing can be specially reduced in the case of reduction of channel length. However, channel thickness has to be reduced for decrease of channel length from scaling theory. The ratio of channel length vs. thickness becomes the most important factor to determine subthreshold swing. To analyze hermeneutically subthreshold swing, the analytical potential distribution is derived from Poisson's equation, and conduction path and subthreshold swing are calculated for various channel length and thickness. As a result, we know conduction path and subthreshold swing are changed for the ratio of channel length vs. thickness.

Photocatalytic Efficiency and Bandgap Property of the CdS Deposited TiO2 Photocatalysts (TiO2/CdS 복합광촉매의 밴드갭 에너지 특성과 광촉매 효율)

  • Lee, Jong-Ho;Heo, Sujeong;Youn, Jeong-Il;Kim, Young-Jig;Suh, Su-Jeong;Oh, Han-Jun
    • Korean Journal of Materials Research
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    • v.29 no.12
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    • pp.790-797
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    • 2019
  • To improve photocatalytic performance, CdS nanoparticle deposited TiO2 nanotubular photocatalysts are synthesized. The TiO2 nanotube is fabricated by electrochemical anodization at a constant voltage of 60 V, and annealed at 500 for crystallization. The CdS nanoparticles on TiO2 nanotubes are synthesized by successive ionic layer adsorption and reaction method. The surface characteristics and photocurrent responses of TNT/CdS photocatalysts are investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), UV-Vis spectrometer and LED light source installed potentiostat. The bandgaps of the CdS deposited TiO2 photocatalysts are gradually narrowed with increasing of amounts of deposited CdS nanoparticles, which enhances visible light absorption ability of composite photocatalysts. Enhanced photoelectrochemical performance is observed in the nanocomposite TiO2 photocatalyst. However, the maximum photocurrent response and dye degradation efficiency are observed for TNT/CdS30 photocatalyst. The excellent photocatalytic performance of TNT/CdS30 catalyst can be ascribed to the synergistic effects of its better absorption ability of visible light region and efficient charge transport process.