• 한국재료학회지
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• 제30권9호
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• pp.480-488
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• 2020

The electrocaloric effect can be observed in pyroelectric materials based on conversion between electrical and thermal energy, and can be utilized for the future environment-friendly refrigeration technology. Especially, a strong electrocaloric effect is expected in materials in which field-induced phase transition can be achieved. Emerging fluorite-structure ferroelectrics such as doped hafnia and zirconia, first discovered in 2011, are considered the most promising materials for next-generation semiconductor devices. Besides application of fluorite-structure ferroelectrics for semiconductor devices based on their scalability and CMOS-compatibility, field-induced phase transition has been suggested as another interesting phenomenon for various energy-related applications such as solid-state cooling with electrocaloric effect as well as energy conversion/storage and IR/piezoelectric sensors. Especially, their giant electrocaloric effect is considered promising for solid-state-cooling. However, the electrocaloric effect of fluorite-structure oxides based on field-induced phase transition has not been reviewed to date. In this review, therefore, the electrocaloric effect accompanied by field-induced phase transition in fluorite-structure ferroelectrics is comprehensively reviewed from fundamentals to potential applications.

• Applied Microscopy
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• 제48권2호
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• pp.43-48
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• 2018

Transition metal dichalcogenide (TMD) materials have distinctive structures in comparison with other two-dimensional materials. TMD materials' structure is held together by van der Waals and covalent intralayer interactions; consequently, TMDs exhibit multiple phases and properties depending on their structure. This article reviews some of the research currently being undertaken to control TMD phases to utilize their different properties. This review introduces some trials for changing the phase of TMDs.

• 한국결정성장학회지
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• 제14권2호
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• pp.63-67
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• 2004

층상 구조의 cobalt dedecanesulfate 화합물을 합성하였다. 여러 온도 영역에서 상 전이가 일어나면서 층간 거리의 큰 변화가 생겼다. 상온에서 단일 층 구조의 cobalt dodecanesulfate 화합물이 고온에서 탈수된 화합물의 이중층의 구조로 변화되었다.

• Journal of electromagnetic engineering and science
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• 제17권1호
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• pp.29-33
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• 2017

This paper proposes a half-mode substrate integrated waveguide (HMSIW) amplifier using lumped-element transition. The input and output impedances of this amplifier are matched by the lumped-element transition structure. This structure provides compact impedance and mode matching circuits between the HMSIW and a stand-alone amplifier. Surface mount technology inductors and capacitors are implemented to realize the lumped-element transition. A prototype of the proposed HMSIW amplifier shows 15 dB gain with 3 dB bandwidth of 4 to 7.05 GHz in a simulation and measurement.

• 한국세라믹학회지
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• 제34권7호
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• pp.713-721
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• 1997

Molecular dynamic (MD) simulations with new interatomic potential function including the covalent bond were performed on the phase transition of $\alpha$-quartz-type GeO2 under high pressure. The optimized crystal structure and the pressure dependence of the lattice constant showed higher reproducibility than the previous models and were in very good agreement with the experimental data. A phase transition of $\alpha$-quartz and $\alpha$-quartz-type GeO2 by simulation was found approximately 24 GPa and 6-7 GPa, respectively. This phase transition involved an abrupt volume shrinkage and showed 4-6 coordination mixed structure with the increasing in the coordination number of cation.

• 대한기계학회논문집
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• 제14권5호
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• pp.1234-1243
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• 1990

본 연구에서는 선회가 없는 중심기류와 주위기류의 난류 전단층에서 형성되는 난류확산화염의 천이영역(transition region)에 주목하여 전단층내의 혼합작용과 화염 구조와의 상호작용을 규명하기 위해 거시적 및 순간적인 화염구조에 대해 실험적으로 조사 연구한 결과를 보고한다.

• 대한전자공학회논문지TC
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• 제45권7호
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• pp.67-71
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• 2008

본 논문에서는 Ka 대역에서 동작하는 송수신기에 쉽게 집적화 할 수 있는 프로브 구조를 이용한 도파관-마이크로스트립 트랜지션을 설계 및 제작하였다. 도파관-마이크로스트립 트랜지션은 프로브, 인덕턴스 선로, ${\lambda}/4$ 임피던스 변환기, 그리고 $50{\Omega}$ 마이크로스트립 선로로 구성되어있으며, 각 구성 요소들의 특성 임피던스 및 길이를 시뮬레이션을 통해 최적화하였다. 제작된 트랜지션의 측정결과, $30{\sim}40GHz$ 대역 내에서 평균 1.3 dB의 삽입손실 특성, 14 dB이하의 입출력 반사 손실특성을 나타내었다. 마이크로스트립 선로 및 입출력 도파관의 손실을 고려하여 하나의 변환 구조 당 삽입 손실은 $0.5{\sim}0.6dB$ 정도이다.

• 한국산학기술학회논문지
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• 제13권4호
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• pp.1915-1922
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• 2012

본 연구는 SBA-15, MCM-41, MCM-48, KIT-6와 같은 메조포러스실리카를 다양한 조건에서 합성하고 이를 이용하여 CMK(Carbon Mesoporous Korea)를 합성한다. 합성된 CMK를 이용하여 메조포러스 구조의 전이금속체를 제조하였다. 각각의 메조포러스실리카에 따라 합성된 CMK의 특성을 분석하고 이를 이용하여 합성된 메조포러스 전이금속체의 특성을 질소흡탈착 등온선, SEM, 저각 X-선 회절분석으로 분석하므로써 최적의 메조포러스 전이금속체의 합성조건을 도출하였다, 실험 결과 가장 우수한 특성을 나타내는 메조실리카는 SBA-15이며, BET 분석으로 SBA-15로부터 합성된 메조포러스 구리 분자체의 비표면적은 $225m^2/g$, 기공크기는 2.91nm로 나타났다.

• Bulletin of the Korean Chemical Society
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• 제2권2호
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• pp.48-55
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• 1981

A new approach in calculating the dipole moments for transition metal complexes has been proposed and the calculated results are tabulated with the experimental values. The calculated dipole moments are applied to the theoretical prediction or confirmation of the geometric structure for the transition metal complexes.

• Bulletin of the Korean Chemical Society
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• 제24권6호
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• pp.805-808
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• 2003

Fundamental ideas of the free energy gradient method are briefly reviewed with three applications: the stable structures of glycine and ammonia-water molecule pair in aqueous solution and the transition state (TS) structure of a Menshutkin reaction $NH_3 + CH_3Cl → CH_3NH_3^+ + Cl^-$ in aqueous solution, which is the first example of full TS optimization of all internal degrees of freedom.