• Title/Summary/Keyword: Transformation constant

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Microstructures and Dielectric Properties of Nanocrystalline $\textrm{La}^{3+}$-doped $\textrm{BaTiO}_3$ Ceramics (초미립 $\textrm{La}^{3+}$-doped $\textrm{BaTiO}_3$세라믹스의 미세구조 및 유전특성)

  • Cho, Ji-Man;Kim, Byong-Ho;Kim, Gyeung-Ho;Je, Hae-June;Lee, Hae-Won;Kim, Byung-Kook
    • Korean Journal of Materials Research
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    • v.9 no.10
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    • pp.956-961
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    • 1999
  • When the 0-2 mol% of $\textrm{La}_{3+}$ were added to the nanocrystalline $BaTiO_3$ powders and sintered at $1200~1400^{\circ}C$, the nanocrystailine $BaTiO_3$ ceramics having the average grain size of 110-240 nm were obtained except for when no $\textrm{La}_{3+}$ was added and sintered at > $1350^{\circ}C$. As the average grain size decreased from 240 nm to 110 nm, the tetragonality (c/a) and volume fraction of the $90^{\circ}$ domain decreased, and all the properties such as relative dielectric constant at room temperature, maximum relative dielectric constant at the temperature of phase transformation $\textrm{T}_{c}$ and diffuseness of phase transformation at $\textrm{T}_{c}$ also decreased. The results were attributed to the internal stress induced by inhibition of the $90^{\circ}$ domain formation in the case of finer grain size.

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Property of Nickel Silicides with Hydrogenated Amorphous Silicon Thickness Prepared by Low Temperature Process (나노급 수소화된 비정질 실리콘층 두께에 따른 저온형성 니켈실리사이드의 물성 연구)

  • Kim, Jongryul;Choi, Youngyoun;Park, Jongsung;Song, Ohsung
    • Korean Journal of Metals and Materials
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    • v.46 no.11
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    • pp.762-769
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    • 2008
  • Hydrogenated amorphous silicon(a-Si : H) layers, 120 nm and 50 nm in thickness, were deposited on 200 $nm-SiO_2$/single-Si substrates by inductively coupled plasma chemical vapor deposition(ICP-CVD). Subsequently, 30 nm-Ni layers were deposited by E-beam evaporation. Finally, 30 nm-Ni/120 nm a-Si : H/200 $nm-SiO_2$/single-Si and 30 nm-Ni/50 nm a-Si:H/200 $nm-SiO_2$/single-Si were prepared. The prepared samples were annealed by rapid thermal annealing(RTA) from $200^{\circ}C$ to $500^{\circ}C$ in $50^{\circ}C$ increments for 30 minute. A four-point tester, high resolution X-ray diffraction(HRXRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and scanning probe microscopy(SPM) were used to examine the sheet resistance, phase transformation, in-plane microstructure, cross-sectional microstructure, and surface roughness, respectively. The nickel silicide on the 120 nm a-Si:H substrate showed high sheet resistance($470{\Omega}/{\Box}$) at T(temperature) < $450^{\circ}C$ and low sheet resistance ($70{\Omega}/{\Box}$) at T > $450^{\circ}C$. The high and low resistive regions contained ${\zeta}-Ni_2Si$ and NiSi, respectively. In case of microstructure showed mixed phase of nickel silicide and a-Si:H on the residual a-Si:H layer at T < $450^{\circ}C$ but no mixed phase and a residual a-Si:H layer at T > $450^{\circ}C$. The surface roughness matched the phase transformation according to the silicidation temperature. The nickel silicide on the 50 nm a-Si:H substrate had high sheet resistance(${\sim}1k{\Omega}/{\Box}$) at T < $400^{\circ}C$ and low sheet resistance ($100{\Omega}/{\Box}$) at T > $400^{\circ}C$. This was attributed to the formation of ${\delta}-Ni_2Si$ at T > $400^{\circ}C$ regardless of the siliciation temperature. An examination of the microstructure showed a region of nickel silicide at T < $400^{\circ}C$ that consisted of a mixed phase of nickel silicide and a-Si:H without a residual a-Si:H layer. The region at T > $400^{\circ}C$ showed crystalline nickel silicide without a mixed phase. The surface roughness remained constant regardless of the silicidation temperature. Our results suggest that a 50 nm a-Si:H nickel silicide layer is advantageous of the active layer of a thin film transistor(TFT) when applying a nano-thick layer with a constant sheet resistance, surface roughness, and ${\delta}-Ni_2Si$ temperatures > $400^{\circ}C$.

The Origins and Changes of One Chulmok-One Ikgong Bracket-Sets in the Joseon Dynasty (일출목 초익공 공포의 기원과 변천)

  • Chun, Hae-Wan;Ryoo, Seong-Lyong
    • Journal of architectural history
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    • v.29 no.3
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    • pp.79-90
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    • 2020
  • In Korean traditional architecture, the Gong-po style is divided into the Jusimpo, Dapo and Ikgong. Jusimpo and Chulmok-Ikong, where only Gong-po is placed on the column, differ in form of Gong-po depending on the viewpoint. Since 'Chulmok-Ikgong' has been generally regarded as 'One Chulmok-Two Ikgong', the precedent researches have been conducted mainly on 'One Chulmok-Two Ikgong' in the Gong-po style classification. However, when it comes to 'One Chulmok', the style of Ikgong can be organized from the one to three steps and this study is particularly for examining the occurrence and transformation of 'One Chulmok-One Ikgong'. One of the case study sites, Bonghwa Cheongamjeong was originally built in the 16th century, and is believed to have been repaired from 'Non Chulmok-One Ikgong' to 'One Chulmok-One Ikgong'. Since the beam linked directly to the upper part of a capital, it does not connect the eave trave(architrave) in between. Also, Soro which supports Jangyeo(the architrave strip) has been placed and linked in comparatively lower position. It is confirmed by the signigicant difference in the hierarchy of Gong-po forms in one architecture. The Jeonju-Hyanggyo Daeseongjeon, which was built in the 17th century among the subjects, was similar with 'One Chulmok-One Ikgong', but it was found to be the type of Jusimpo form because the bottom of the beam and the top of the Ikong are apart. And Gongan is confirmed at Cheomcha. In the 17th century, it can be seen that Heot-Cheomcha disappeared and Ikgong was started to use as a constant figure. The end of the 18th century, it can be seen that it was changed into a ornament added on Haeng-gong, being seen in the case of Hwaseong Dongjangdae. In conclusion, it can be seen that 'One Chulmok-One Ikgong' were developed in both the Jusimpo and Ikong style. The transformation into 'One Chulmok-One Ikgong' was inevitable consequence related with an elevation difference between the eave trave and the column trave.

The Formation and Crystallization of Amorphous Ti50Cu50Ni20Al10 Powder Prepared by High-Energy Ball Milling

  • Viet, Nguyen Hoang;Kim, Jin-Chun;Kim, Ji-Soon;Kwon, Young-Soon
    • Journal of Powder Materials
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    • v.16 no.1
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    • pp.9-15
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    • 2009
  • Amorphization and crystallization behaviors of $Ti_{50}Cu_{50}Ni_{20}Al_{10}$ powders during high-energy ball milling and subsequent heat treatment were studied. Full amorphization obtained after milling for 30 h was confirmed by X-ray diffraction and transmission electron microscope. The morphology of powders prepared using different milling times was observed by field-emission scanning electron microscope. The powders developed a fine, layered, homogeneous structure with prolonged milling. The crystallization behavior showed that the glass transition, $T_g$, onset crystallization, $T_x$, and super cooled liquid range ${\Delta}T=T_x-T_g$ were 691,771 and 80 K, respectively. The isothermal transformation kinetics was analyzed by the John-Mehn-Avrami equation. The Avrami exponent was close to 2.5, which corresponds to the transformation process with a diffusion-controlled type at nearly constant nucleation rate. The activation energy of crystallization for the alloy in the isothermal annealing process calculated using an Arrhenius plot was 345 kJ/mol.

Free vibration analysis of a non-uniform beam with multiple point masses

  • Wu, Jong-Shyong;Hsieh, Mang
    • Structural Engineering and Mechanics
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    • v.9 no.5
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    • pp.449-467
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    • 2000
  • The natural frequencies and the corresponding mode shapes of a non-uniform beam carrying multiple point masses are determined by using the analytical-and-numerical-combined method. To confirm the reliability of the last approach, all the presented results are compared with those obtained from the existing literature or the conventional finite element method and close agreement is achieved. For a "uniform" beam, the natural frequencies and mode shapes of the "clamped-hinged" beam are exactly equal to those of the "hinged-clamped" beam so that one eigenvalue equation is available for two boundary conditions, but this is not true for a "non-uniform" beam. To improve this drawback, a simple transformation function ${\varphi}({\xi})=(e+{\xi}{\alpha})^2$ is presented. Where ${\xi}=x/L$ is the ratio of the axial coordinate x to the beam length L, ${\alpha}$ is a taper constant for the non-uniform beam, e=1.0 for "positive" taper and e=1.0+$|{\alpha}|$ for "negative" taper (where $|{\alpha}|$ is the absolute value of ${\alpha}$). Based on the last function, the eigenvalue equation for a non-uniform beam with "positive" taper (with increasingly varying stiffness) is also available for that with "negative" taper (with decreasingly varying stiffness) so that half of the effort may be saved. For the purpose of comparison, the eigenvalue equations for a positively-tapered beam with five types of boundary conditions are derived. Besides, a general expression for the "normal" mode shapes of the non-uniform beam is also presented.

A Calculation Method for the Nonlinear Crowbar Circuit of DFIG Wind Generation based on Frequency Domain Analysis

  • Luo, Hao;Lin, Mingyao;Cao, Yang;Guo, Wei;Hao, Li;Wang, Peng
    • Journal of Power Electronics
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    • v.16 no.5
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    • pp.1884-1893
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    • 2016
  • The ride-through control of a doubly-fed induction generator (DFIG) for the voltage sags on wind farms utilizing crowbar circuits by which the rotor side converter (RSC) is disabled has being reported in many literatures. An analysis and calculation of the transient current when the RSC is switched off are of significance for carrying out the low voltage ride through (LVRT) of a DFIG. The mathematical derivation is highlighted in this paper. The zero-state and zero-input responses of the transient current in the frequency domain through a Laplace transformation are investigated, and the transient components in the time domain are achieved. With the characteristics worked out from the linear resolving without modeling simplification, the selection of the resistance in the linear crowbar circuit and the value conversion from a linear circuit to a nonlinear one is proposed to setup the attenuation rate. In terms of grid code requirements, the theoretical analysis for the time constant of the transient components attenuation insures the controllability when the excitation of the RSC is resumed and it guarantees the reserved time for the response of the reactive power compensation. Simulations are executed in MATLAB/SIMPOWER and experiments are carried out to validate the theoretical analysis. They indicate that the calculation method is effective for selection of the resistance in a crowbar circuit for LVRT operations.

The Study for Process Capability Analysis of Software Failure Interval Time (소프트웨어 고장 간격 시간에 대한 공정능력분석에 관한 연구)

  • Kim, Hee-Cheul;Shin, Hyun-Cheul
    • Convergence Security Journal
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    • v.7 no.2
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    • pp.49-55
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    • 2007
  • Software failure time presented in the literature exhibit either constant, monotonic increasing or monotonic decreasing. For data analysis of software reliability model, data scale tools of trend analysis are developed. The methods of trend analysis are arithmetic mean test and Laplace trend test. Trend analysis only offer information of outline content. From the subdivision of this analysis, new attemp needs the side of the quality control. In this paper, we discuss process capability analysis using process capability indexs. Because of software failure interval time is pattern of nonnegative value, instead of capability analysis of suppose to normal distribution, capability analysis of process distribution using to Box-Cox transformation is attermpted. The used software failure time data for capability analysis of process is SS3, the result of analysis listed on this chapter 4 and 5. The practical use is presented.

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The Effects of Charge Transfer Complex on the Reaction of Aniline and Iodine (Aniline과 Iodine간의 반응에 있어서 전하이동 착물의 영향)

  • Oh-Yun Kwon;U-Hyon Paek;Eung-Ryul Kim
    • Journal of the Korean Chemical Society
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    • v.36 no.2
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    • pp.174-179
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    • 1992
  • Reaction of aniline and iodine in$CHCl_3,\;CH_2Cl_2 : CHCl_3$(1 : 1), and $CH_2Cl_2$ has been studied kinetically by using conductivity method, Pseudo first-order rate constants ($k_{obs}$) and second-order rate constants ($k_{obs}$/[aniline]) are dependent on the aniline concentration. Second-order rate constants obtained were increased with increasing aniline concentration. We analysed these results on the basis of formation of charge transfer complex as reaction intermediate. From the construction of react ion scheme and derivation of rate equation, we calculated equilibrium constants and activation parameters for the formation and transformation of charge transfer complex. The equilibrium constants were decreased by an increase in the dielectric constant of the solvent and the value is 1.7-3.7$M^{-1}$. The rate of transformation are markedly affected by the solvent polarity. ${\Delta}H^{\neq}$ is about 14.2kJ/mol, and ${\Delta}S^{\neq}$ is large negative value of -243J/mol K.

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Tailoring the Dielectric and Mechanical Properties of Si3N4 Ceramics (질화규소 세라믹의 유전 및 기계적 특성 제어에 관한 연구)

  • Lee, Seung Jun;Yong, Seok-Min;Park, Jin-Woo;Choi, Jaeho;Baek, Seungsu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.21 no.6
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    • pp.760-766
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    • 2018
  • The present study investigates the effect of PMMA and BN content on microstructure, mechanical and dielectric properties of silicon nitride($Si_3N_4$) ceramics in $Y_2O_3-Al_2O_3$ additive system. The total additive content was fixed at 8 wt.% and the amount of PMMA varies from 0 to 40 wt.% and BN varies from 0 to 36 wt.%, respectively. The crystalline phases of the samples were determined by X-ray diffraction analysis. All the sintered sample shows complete transformation of ${\alpha}$ to ${\beta}-Si_3N_4$ during the sintering process indicated that the phase transformation was unaffected by the PMMA or BN content. However, the microstructure shows that the residual porosity increased with increasing PMMA and BN content. In addition, the flexural strength and the dielectric constant decrease with addition of PMMA and BN due to the residual porosity. This article provides empirical study of design parameters for $Si_3N_4$-based radome materials.

A Study of Building Digital Capacity of Museum Professionals through the Use of Virtual Museum (가상박물관 활용을 통한 박물관 전문인력의 디지털 역량 강화 방안 연구)

  • Kim, Seon-Mi;Lee, Jong-Wook
    • The Journal of the Korea Contents Association
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    • v.22 no.10
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    • pp.39-46
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    • 2022
  • The overall digital transformation in society is rapidly progressing with the corona virus epidemic. In particular, in the field of cultural heritage and museums, digital transformation is taking place throughout the preservation, management, and utilization of cultural heritage. To respond to this, the importance of cultivating the digital literacy of museum professionals to select and utilize digital cultural heritage information is increasing. However, the current digital capacity education of museum professionals has not reached the cultivation of digital literacy due to one-way theory and one-way practical education. To overcome this, we propose a digital capacity building program using virtual museums. We propose a curriculum based on participatory museums, cooperative learning, and project-based learning theories. Learners experience the entire process of acquiring, selecting, and utilizing digital cultural heritage information through individual, cooperative, constant, exhibitions, and project-based learning programs. We were evaluated by experts in terms of education, museum education, and ICT technology education to prove its usability and derive improvements. This study will contribute to building the digital capacity of museum professionals.