• Title/Summary/Keyword: Transference Number

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Effects of Sintering Conditions on the Electrical Conductivity of 1 wt% Y2O3-Doped AlN Ceramics (1 wt% Y2O3 첨가계 AlN 세라믹스의 소결 조건에 따른 전기전도도)

  • Lee, Won-Jin;Lee, Sung-Min;Shim, Kwang-Bo;Kim, Hyung-Tae
    • Journal of the Korean Ceramic Society
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    • v.44 no.2 s.297
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    • pp.116-123
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    • 2007
  • Electrical properties of AlN ceramics sintered with 1 wt% $Y_2O_3$ have been investigated. From the impedance spectroscopy, electrical conductivity of grain boundary was found to be much lower than that of grain. DC conductivity measurement showed the electrode polarization effects caused by blocking electrode. The heat-treatment at $1700^{\circ}C$ of the specimen sintered at $1850^{\circ}C$ transformed continuous pain boundary phases along triple boundary junctions into isolated particles in grain comers. The heat-treatment induced decreases both in grain and grain boundary conductivity, and in DC electrical conductivities. From the analysis on the transference number, ionic conductivity was shown to be more dominant than electron conductivity, which was due to ion compensation mechanism during oxygen incorporation into grain.

Studies on the Nutritional Physiology of Soybeans. -3. Relation between growth and phosphorus nutrition with the fertilizational period (대두(大豆)의 영양생리(榮養生理)에 관(關)한 연구(硏究) (제(第)3보(報)) - 시비(施肥) 시기(時期)에 따른 인(燐)의 영향(影響) -)

  • Kang, Y.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.2 no.1
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    • pp.45-48
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    • 1969
  • In an effort to determine the effect of the physiological function of phosphorus in higher plants, soybean have been used as samples in an attempt to compare them with rice on which there have been a number of reports of research. The absorptive and metabolic process phosphorus in each separate manuring period has been studied. It has iefluenced enhancement of vitality in the plants whether manuring is conducted earlier or later. These phenomena have greatly concerned with the absorption and transference of phosphorus in the process of growth are done more slowly than those of nitrogen and phosphorus from stems and leaves to pods.

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The Electrical Behavior of Plasma Sprayed Al2O3-TiO2 Coatings (플라즈마 용사된 Al2O3-TiO2 코팅의 전기적 특성)

  • Park, Sang-Jun;Lee, Sung-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.12
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    • pp.788-793
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    • 2017
  • Electrical behaviors of plasma-sprayed $Al_2O_3-TiO_2$ coatings have been investigated in terms of their $TiO_2$ content. On increasing the $TiO_2$ content from 6 to 30 wt%, the DC electrical conductivity increased by several orders of magnitude. From impedance spectroscopy analysis, the total conductivity of the grains and grain boundaries and their respective activation energies were determined without the electrode effects that could impede ionic transfer. An electron transference number was also estimated, ranging between 6.5% and 7.3% for 13 wt% $TiO_2$ and between 0.4% and 0.7% for 30 wt% $TiO_2$ in the coating. Because of the high electronic contribution to the total conductivity, the $Al_2O_3-TiO_2$ coating could be a new candidate material to obtain superior electrical conductivity as well as corrosion and wear resistances.

Electrical Behavior of Aluminum Nitride Ceramics Sintered with Yttrium Oxide and Titanium Oxide

  • Lee, Jin-Wook;Lee, Won-Jin;Lee, Sung-Min
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.635-640
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    • 2016
  • Electrical behavior of AlN ceramics sintered with $Y_2O_3$ as a sintering aid has been investigated with respect to additional $TiO_2$ dopant. From the impedance spectroscopy, it was found that the grain and grain boundary conductivities have greatly decreased with addition of $TiO_2$ dopant. The $TiO_2$ dopant also increased the activation energy of the grain conductivity by about 0.37 eV; this increase was attributed to the formation of an associate between Al vacancies and Ti ions at the Al sites. Similarly, the electronic conductivity was reduced by $TiO_2$ addition. However, $TiO_2$ solubility in AlN grains was below the detection limit of typical EDX analysis. Grain boundary was clean, without liquid films, but did show yttrium segregation. The transference number of ions was close to 1, showing that AlN is a predominantly ionic conductor. Based on the observed results, the implications of using AlN applications as insulators have been discussed.

Electrochemical Properties of $Li_xV_3O_8$ Composite Cathode for All-solid state Rechargeable Battery (고체전지용 $Li_xV_3O_8$ Composite 정극의 전기화학적 특성)

  • 김종욱;성창호;구할본;박복기
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.9
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    • pp.733-738
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    • 1998
  • 본 논문에서는 고체 리듐 전지를 개발하기 위하여 poly(ethylene oxide) [PEO] 에 $LiClO_4$, poly (vinylidene fluoride) [PVDF] 및 가소제로 propylene carbonate [PC] 와 ethylene carbonate[EC] 등을 혼합여 고분자 저해질을 제조하였다. 또한 고체 리듐 전지용 정극으로써 우수한 특성이 기대되는 $Li_xV_3O_8$을 졸-겔법에 의해 합성하여 $Li_xV_3O_8$SPE/Li cell 의 전기화학적 특성을 측정하였다. 고분자 matrix는 PEO와 PVDE를 혼합 사용한 결과 $PEO_4 PVDF_4LiCIO_4PC_5EC_5$ 고분자 전해질이 상온에서 $5.2 {\times} 10{-3}$ S/cm 의 높은 이온 전도도를 나타냈으며 리듐 이온 transference number는 0.3이었다. 졸-겔법에 의해 제조된 $Li_xV_3O_8$을 사용한 $Li_xV_3O_8$SPE/Li cell의 방전시 cell 저항이 방전 초기에는 비소한 증가를 하다가 방전 말기 전압인 2.0V에서 크게 증가하였다. $Li_xV_3O_8$ composite 정극의 첫 번째 방전 용량은 295㎃h/g이었으며 8번째 충방전 싸이클부터 방전 용량이 안정화 되었고 15번째 방전 용량도 212㎃h/g으로 고체 전지용 정극으로써 우수한 특성을 보였다.

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Empirical Analysis of the Effect of Avatars on Learner's e-Learning Performance : Emphasis on Trust Transference between Avatars and Contents (아바타가 학습자 이러닝 성과에 미치는 영향에 관한 실증연구:아바타와 학습내용간 신뢰전이를 중심으로)

  • Chae, Seong-Wook;Lee, Kun-Chang;Lee, Keun-Young
    • Asia pacific journal of information systems
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    • v.19 no.4
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    • pp.149-176
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    • 2009
  • In the recent e-learning environment, avatars are often used to help learners get familiar with the contents, which is ultimately to motivate them to study more. Therefore, it is important to investigate whether avatars have actually the desirable effect on users of e-learning materials. Surprisingly, however, no extensive study has been conducted on this crucial issue Accordingly, main objectives this study are summarized as follows. First, we need to gain better understanding of how much learners' trust towards avatars (termed as "avatar trust") is transferred to learners' trust towards e-learning contents (termed as "contents trust"). Second, we need to investigate how much learners' personal relationships with avatars as well as learning behaviors change depending on avatar types (attractive vs. professional) and contents complexity (easy vs. difficult). As described in the study objectives, in order for us to analyze empirical data more systematically, we classified avatar types into two: "attractive" and "professional;" the contents are categorized as either "easy" or "difficult." Therefore, it is essential for this study to build a prototype e-learning website on which our research purpose can be realized and tested effectively with proper avatar types and e-learning contents. For this purpose, we built a prototype e-learning website, in which avatars are invited from currently working avatar instructors used in real-world e-learning websites, and e-learning contents are adapted from real-world contents about Java programming topic, which have been proved to have shown high quality and reliability. Our research method includes questionnaire survey by inviting a number of valid respondents comprised of office workers who are believed to have high demands for the e-learning contents as well as those who have previous experience with avatar instructors. Respondents were given one of the four e-learning experiment conditions (2 avatar types x 2 contents types) on a random basis. Each experimental e-learning condition is framed to have the same quality but different avatar type and content complexity. Then the respondents are asked to fill out the survey form which has questions about avatar trust, contents trust, personal relationships with avatar, and learning behavior, among others. Regarding the constructs used in research model, we based them rigorously on previous studies. For example, we used six constructs such as behavior to give information (BGI), behavior to obtain information (BOI), need for inclusion wanted, need for control wanted, contents trust, and avatar trust. To measure them, 7-Likert scales were used in the questionnaire. E-learning performance was measured indirectly through two constructs such as BGI and BOI. Six constructs used in the research model were adopted and revised from the FIRO-B model suggested by Schutz. Empirical results are as follows: First, professional avatars are more effective for difficult contents, while attractive avatars were not as effective for easy contents. Second, our study results ascertained that avatar trust transfers to contents trust regardless of avatar types and contents complexity.

Seasonal Variations of Digestive Diverticula in the Scallop, Patinopecten yessoensis (가리비, Patinopecten yessoensis 소화맹낭의 계절변화)

  • Chang, Young-Jin
    • Journal of Aquaculture
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    • v.4 no.1
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    • pp.19-30
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    • 1991
  • The seasonal variations of digestive diverticula in the scallop, Patinopecten yessoensis culturing by sowing method were studied by microscopic observations and individual measuring of the shells collected monthly from Abashiri Bay located in Hokkaido, Japan. Digestive diverticula index revealed the seasonal variations which showed the highest value in May and July, and the lowest value in December through April. The highest number of tubules per $mm^{2}$in the preparation of digestive diverticula was counted in March. But, in September and October the number of tubules decreased to the lowest value. The relationship between gonad index(X) and percent of lipid tubule(Y) as an indicator for the transference of lipid in digestive diverticula into the gonad was expressed by an exponential equation, $Y=145.6X^{-0793}$. It was suggested that the lipid in digestive diverticula showed the seasonal variations might be transferred into the gonad.

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A Study on the Design and Development of Interactive Non-Face-to-Face Real-Time Classes using EduTech : A Case Study of Christian Education Class (에듀테크를 활용한 상호작용적 비대면 실시간 수업 설계 및 개발 연구 : 기독교교육과 수업 사례를 중심으로)

  • Nam, Sunwoo
    • Journal of Christian Education in Korea
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    • v.66
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    • pp.343-382
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    • 2021
  • This study is a case study in which the interactive non-face-to-face classes using Edutech were applied to the Department of Christian Education. The subjects were 20 students from the Christian education department of A University located in the metropolitan area. The course was 'Instructional Methods and Educational Technology' in the first semester of 2020. In theory, I studied non-face-to-face classes and interaction, and edutech and interaction. Afterward, it designed and developed interactive non-face-to-face classes using edutech. The interactive non-face-to-face classes using edutech were developed as a process of applying Flipped-PBL based interactive edutech. In addition, Edutech was selected for active interaction according to the Flipped-PBL process to be carried out in a non-face-to-face situation. In particular, in the process of developing the problem of PBL, it was built around the situation of the church. As a result of applying the class, first, learners showed high satisfaction and interest in the class. Second, positive transference appeared in the space of learning and the space of living. Third, interactive non-face-to-face classes using Edutech have generated active interaction. In particular, interactive edutech and learning methods have become the main factors enabling active interaction. Through this, learners have improved learning efficiency, immersion, and satisfaction. Also, as an alternative to face-to-face classes, I was able to experience online classes. In other words, the satisfaction and interest of learning, and the transference of learning space, were also possible through active interactions generated through learning methods using interactive Edutech used in class. Furthermore, disabilities in the online communication(Internet) environment and learners' unfamiliarity with the online environment have been found as factors that hinder learning satisfaction and interaction. During learning, obstacles to the online communication environment hinder the utilization of interactive Edutech, preventing active interactions from occurring. This results in diminishing satisfaction and interest in learning. Therefore, we find that designing interactive non-face-to-face classes using Edutech requires sufficient learner learning and checking of the online communication(Internet) environment in advance for Edutech and learning methods. In response, this study confirmed the possibility by applying interactive non-face-to-face classes using Edutech to Christian education classes as an alternative method of education that allows active interaction and consistent transference of learning and life. Although it is a case study with limited duration and limitations of the number of people, I would like to present the possibility as an alternative Christian education method of an era where the direction of online classes should be presented as an alternative to a face-to-face class.

Phase Transfer Polymerization. Two Phase Polycondensation of Diphenoxides and 1,6-Dibromohexane in the Presence of Tetrabutylammonium Bromide (狀移動重合. Tetrabutylammonium Bromide 존재하에서 Diphenoxides와 1,6-Dibromohexane의 二狀重縮合反應)

  • Jung-Il Jin;Yong-Woon Jung;Kwang-Sup Lee;Keun-Woo Chung
    • Journal of the Korean Chemical Society
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    • v.23 no.4
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    • pp.259-266
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    • 1979
  • Linear polyethers were prepared by the reaction of diphenoxide anions from 2,2-bis (4-hydroxyphenyl) propane, bis (4-hydroxylphenyl) sulfide, and bis (khydroxyphenyl) sulfone with 1,6-dibromohexane in aqueous/nitrobenzene heterogeneous phases. Tetrabutylammonium bromide was employed as a phase transfer catalyst. The polymerizations were dependent both on stirring speed and catalyst level, but only up to certain maximum values. Distribution studies demonstrated transference of diphenoxide anions from aqueous phase into nitrobenzene in the presence of the catalyst. Some of polymers were characterized with respect to their intrinsic viscosities (0.09-O.16), number average molecular weight (2400-4800)) and thermal properties. The use of a new terminology, 'phase transfer polymerization?, is proposed to differentiate this type of polymerizations from interfacial polycondensations.

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Quality Characteristics of Tofu Prepared with Tomatoes and Strawberries (토마토즙과 딸기즙을 첨가한 두부의 품질특성)

  • Kim, Mi-Ja;Park, Geum-Soon
    • Korean journal of food and cookery science
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    • v.31 no.2
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    • pp.185-192
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    • 2015
  • This research tried to contribute to the diversification and the high quality of tofu products by adding the natural colors from tomatoes and strawberries, thus providing more attractive colors, greater antioxidative activity, and higher palatability The quality characteristics of tofu with 4%, 8%, and 12% strawberry juice and 5%, 10%, and 15% of tomato juice were analyzed. Tofu with tomato juice was found to be higher in transference number, and pH showed a significant decrease as the rate of the addition increased, The antioxidant activity of tofu with strawberry juice is 37.76~52.12%, and tofu with tomato juice is 41.79~51.51%, with tofu with tomato juice is being higher than tofu with strawberry juice in antioxidant status DPPH radical scavenging ability. In chromaticity, the L-value and b-value showed significant decreases as tomato juice was added and when strawberry juice are was added and the values increased. In texture, the hardness of tofu with tomato juice was found to be significantly more solid than tofu with strawberry juice. For the test of springiness, the order was as follows: control group> tomato juice 5%> tomato juice 10%. The result of the organoleptic test of tofu showed, tofu with tomato juice to be significantly brighter in exterior color than tofu with strawberry juice (p<0.001), in for savory flavor, the result shows that tofu with 12% strawberry juice added and that with 10% tomato juice added had better flavor. For the test of beany flavor, the control group is higher than tofu with strawberry juice and tomato juice, and tofu with 10% of tomato juice added was lowest in beany flavor. In the preference investigation, tofu with 10% tomato juice showed the highest preference after swallowing and in overall status.