• Title/Summary/Keyword: Transferable

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Electrochemical Study of Functional Organic Monomolecular Film prepared by Langmuir-Blodgett Method (기능성 유기 LB단분자막의 전기화학적 연구)

  • 박수길;임기조;전일철;이주성
    • Journal of the Korean institute of surface engineering
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    • v.28 no.1
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    • pp.34-45
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    • 1995
  • An amphiphilic nitroxide radical(2,2'6,6'-tetramethyl-4-octadecyioxy-1-piperidinyloxyl, TEMOPO) or mixture of TEMOPO and arachidic acid(Icosanoic acid, AA), was spread on water surface by the Langmuir-Blodgett(LB) method and surface pressure-area curve was measured. Such monolayer films of TEMOPO were transferred onto surfaces of photo transferable tin oxide electrodes(PTTO) by the LB method under various surface pressure with the transfer ratio of larger than 0.95 at the surface pressure higher than 15mN/m. The electrochemical effect of functional nitroxy radical monolayer onto semi-conductive electrode to electrolyte have been investigated by using LB method. Cyclic voltammetry technique was used for the electrochemical behavior measurement of TEMOPO monolayer onto the PTTO in 0.18 mo1/$dm^3$ $H_2SO_4$ solutions. The shape of voltammograms was found to change from one electrode to another. The amount of charge for the oxidation and the re-reduction of the cation to TEMOPO were evaluated from graphical integration. The amounts of charge were always smaller than those predicted from the $\pi$-$\sigma$ curves though the transfer ratio was unity. The poor reproducibility of the cyclic voltammograms was improved by the mixing with AA. Structure and arrangement of monomolecular layer on water surface and electrode were studied. Characteristics of monolayer film applied for the mediation reaction was also discussed by electrochemical method.

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Spontaneous Release of Glycosylphosphatidylinositol (GPI)-anchored Renal Dipeptidase from Porcine Renal Proximal Tubules

  • Park, Sung-Wook;Kang, Bok-Yun;Yoon, Hyun-Joong;Park, Eun-Mi;Choi, Kyong;Lee, Hwang-Hee Blaise;Hooper, Nigel M.;Park, Haeng-Soon
    • Archives of Pharmacal Research
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    • v.25 no.1
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    • pp.80-85
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    • 2002
  • The incubation of porcine renal proximal tubules (PTs) resulted in the release of the Glycosylphosphatidylinositol (GPI)-anchored renal dipeptidase (RDPase, EC 3. 4. 13. 19) from the membrane after a lag period of approximately 6 hours. This spontaneous release of RDPase from the membrane was inhibited by antibiotics. When the incubation supernatant was added back to fresh PTs, both the antibiotic inhibition of RDPase release and the lag period disappeared. The released RDPase reacted with an anti-cross reacting determinant antibody indicating the presence of the Ins (1, 2-cyc)P. These results suggest that bacteria in the PTs, when incubated, grow find Secrete a phosphatidylinmsitol-specific phospholipase C (PIPLC). This enzyme then hydrolyses the GPI-anchored RDPase and is transferable. RDPase was purified following its release from the membrane by this simple and inexpensive method which may also be applied to other GPI-anchored proteins.

An Amber Force Field for S-Nitrosoethanethiol That Is Transferable to S-Nitrosocysteine

  • Han, Sang-Hwa
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2903-2908
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    • 2010
  • Protein S-nitrosation is common in cells under nitrosative stress. In order to model proteins with S-nitrosocysteine (CysSNO) residues, we first developed an Amber force field for S-nitrosoethanethiol (EtSNO) and then transferred it to CysSNO. Partial atomic charges for EtSNO and CysSNO were obtained by a restrained electrostatic potential approach to be compatible with the Amber-99 force field. The force field parameters for bonds and angles in EtSNO were obtained from a generalized Amber force field (GAFF) by running the Antechamber module of the Amber software package. The GAFF parameters for the CC-SN and CS-NO dihedrals were not accurate and thus determined anew. The CC-SN and CS-NO torsional energy profiles of EtSNO were calculated quantum mechanically at the level of B3LYP/cc-pVTZ//HF/6-$31G^*$. Torsional force constants were obtained by fitting the theoretical torsional energies with those obtained from molecular mechanics energy minimization. These parameters for EtSNO reproduced, to a reasonable accuracy, the corresponding torsional energy profiles of the capped tripeptide ACE-CysSNO-NME as well as their structures obtained from quantum mechanical geometry optimization. A molecular dynamics simulation of myoglobin with a CysSNO residue produced a well-behaved trajectory demonstrating that the parameters may be used in modeling other S-nitrosated proteins.

A Study on Design of Home Energy Management System to Induce Price Responsive Demand Response to Real Time Pricing of Smart Grid (스마트그리드 실시간요금과 연동되는 수요반응을 유도하기 위한 HEMS 설계에 관한 연구)

  • Kang, Dong-Joo;Park, Sun-Joo;Choi, Soo-Jung;Han, Seong-Jae
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.11
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    • pp.39-49
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    • 2011
  • Smart Grid has two main objectives on both supply and demand aspects which are to distribute the renewable energy sources on supply side and to develop realtime price responses on demand side. Renewable energy does not consume fossil fuels, therefore it improves the eco-friendliness and saves the cost of power system operation at the same time. Demand response increases the flexibility of the power system by mitigating the fluctuation from renewable energies, and reduces the capacity investment cost by shedding the peak load to off-peak periods. Currently Smart Grid technologies mainly focus on energy monitoring and display services but it has been proved that enabling technologies can induce the higher demand responses through many pilot projects in USA. On this context, this paper provides a price responsive algorithm for HEMS (home energy management system) on the real time pricing environment. This paper identifies the demand response as a core function of HEMS and classifies the demand into 3 categories of fixed, transferable, and realtime responsive loads which are coordinated and operated for the utility maximization or cost minimization with the optimal usage combination of three kinds of demand.

Multi-Objective Optimization Model of Electricity Behavior Considering the Combination of Household Appliance Correlation and Comfort

  • Qu, Zhaoyang;Qu, Nan;Liu, Yaowei;Yin, Xiangai;Qu, Chong;Wang, Wanxin;Han, Jing
    • Journal of Electrical Engineering and Technology
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    • v.13 no.5
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    • pp.1821-1830
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    • 2018
  • With the wide application of intelligent household appliances, the optimization of electricity behavior has become an important component of home-based intelligent electricity. In this study, a multi-objective optimization model in an intelligent electricity environment is proposed based on economy and comfort. Firstly, the domestic consumer's load characteristics are analyzed, and the operating constraints of interruptible and transferable electrical appliances are defined. Then, constraints such as household electrical load, electricity habits, the correlation minimization electricity expenditure model of household appliances, and the comfort model of electricity use are integrated into multi-objective optimization. Finally, a continuous search multi-objective particle swarm algorithm is proposed to solve the optimization problem. The analysis of the corresponding example shows that the multi-objective optimization model can effectively reduce electricity costs and improve electricity use comfort.

A Study on Image Electronic Money based on Watermarking Technique (워터 마킹 기술을 활용한 이미지 전자화폐에 관한 연구)

  • Lee, Jung-Soo;Kim, Whoi-Yul
    • The KIPS Transactions:PartD
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    • v.11D no.6
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    • pp.1335-1340
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    • 2004
  • This study introduces a technology utilizing digital images as electronic money by inserting watermark into the images. Watermarking technology assign contents ID to images and inserts the contents ID into the images in an unnoticeable way. The server that manages the issue and the usage of mage electronic money (called ‘WaterCash’ hereafter) stores issued contents ID to database and manage them as electronic money. WaterCash guarantees anonymity and prevents the forgery and modification of WaterCash based on semi-fragile watermarking technique. In addition, WaterCash is transferable and the illegal use of WaterCash can be prevented based on the watermarking technology. The watermarking .technology used in this paper was designed to be robust to image compression but vulnerable to intentional or non-intentional Image processing.

Lifetime Management Method of Lithium-ion battery for Energy Storage System

  • Won, Il-Kuen;Choo, Kyoung-Min;Lee, Soon-Ryung;Lee, Jung-Hyo;Won, Chung-Yuen
    • Journal of Electrical Engineering and Technology
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    • v.13 no.3
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    • pp.1173-1184
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    • 2018
  • The lifetime of a lithium-ion battery is one of the most important issues of the energy storage system (ESS) because of its stable and reliable operation. In this paper, the lifetime management method of the lithium-ion battery for energy storage system is proposed. The lifetime of the lithium-ion battery varies, depending on the power usage, operation condition, and, especially the selected depth of discharge (DOD). The proposed method estimates the total lifetime of the lithium-ion battery by calculating the total transferable energy corresponding to the selected DOD and achievable cycle (ACC) data. It is also demonstrated that the battery model can obtain state of charge (SOC) corresponding to the ESS operation simultaneously. The simulation results are presented performing the proposed lifetime management method. Also, the total revenue and entire lifetime prediction of a lithium-ion battery of ESS are presented considering the DOD, operation and various condition for the nations of USA and Korea using the proposed method.

Development of Outage Data Management System to Calculate the Probability for KEPCO Transmission Systems (한전계통의 송전망 고장확률 산정을 위한 상정고장 DB 관리시스텀(ezCas) 개발)

  • Cha S. T.;Jeon D. H.;Kim T. K.;Jeon M. R.;Choo J. B.;Kim J. O.;Lee S .H
    • Proceedings of the KIEE Conference
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    • summer
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    • pp.88-90
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    • 2004
  • Data are a critical utility asset. Collecting correct data on site leads to accurate information. Data, when gathered with foresight & properly formatted, are useful to both existing database and easily transferable to newer, more comprehensive historical outage data. However, when investigating data items options, the task, can be an arduous one, often requiring the efforts of entire committees. This paper firstly discusses the KEPCO's past 10 years of historical outage data which include meterological data, and also by several elements of the National Weather Service, failure rate, outage duration, and probability classification, etc. Then, these collected data are automatically stored in an Outage Data Management System (ODMS), which allows for easy access and display. ODMS has a straight-forward and easy-to-use interface. It lets you to navigate through modules very easily and allows insertion, deletion or editing of data. In particular, this will further provide the KEPCO that not only helps with probabilistic security assessment but also provides a platform for future development of Probability Estimation Program (PEP).

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Langmuir-Blodgett Films of Perfluoroalkyl Monomaleate Copolymers on Porous Substrate

  • Hyein Jeong;Burm-Jong Lee;Young-Soo Kwon
    • Bulletin of the Korean Chemical Society
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    • v.15 no.8
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    • pp.650-654
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    • 1994
  • Stable polyion-complexed polymeric monolayers were prepared by spreading perfluoroalkyl monomaleate copolymers, $C_2F_8MA-VE_2$ and $C_2F_8MA-VE_3$, on a aqueous poly(allylamine) subphase. The monolayer properties have been studied by the surface pressure-area (${\pi}$-A) isotherms. The $C_2F_8MA-VE_3$ containing longer oligoethyleneglycol pendant showed more expanded monolayer phase than the $C_2F_8MA-VE_2$. The polyion-complexed monolayers were transferable on various substrates, and the resulting Langmuir-Blodgett (LB) films were characterized by FT-IR spectroscopy and scanning electron microscopy (SEM). Two-dimensional crosslinking to form a polymer network was achieved by amide formation through heat treatment under vacuum with concurrent removal of perfluoroalkyl tails. SEM observation of this film on a porous membrane filter showed that the four layer film was sufficiently stable to cover the filter pore size of 0.1 ${\mu}$m. The $C_2F_8MA-VE_3$ revealed better covering capability than the $C_2F_8MA-VE_2$. Immersion of this film in water or in benzene did not cause any change in its appearance and in Fl-IR spectra.

Technical and economical feasibility of using GGBS in long-span concrete structures

  • Tang, Kangkang;Millard, Steve;Beattie, Greg
    • Advances in concrete construction
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    • v.3 no.1
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    • pp.1-14
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    • 2015
  • China accounts for nearly half of the global steel production. As a waste material or a by-product in the manufacture process, a large amount of blast furnace slag is generated every year. The majority of recycled blast furnace slag is used as an additive in low-grade blended cement in China (equivalent to the UK CEM II or CEM III depending on the slag content). The cost of using ground granulated blast furnace slag (GGBS) in such low-grade applications may not be entirely reimbursed based on market research. This paper reports an on-going project at Xi'an Jiaotong-Liverpool University (XJTLU) which investigates the feasibility of using GGBS in long-span concrete structures by avoiding/reducing the use of crack control reinforcement. Based on a case study investigation, with up to 50% of CEM I cement replaced with GGBS, a beneficiary effect of reduced thermal contraction is achieved in long-span concrete slabs with no significant detrimental effect on early-age strengths. It is believed that this finding may be transferable from China to other Asian countries with similar climates and economic/environmental concerns.