• 제목/요약/키워드: Trace element

검색결과 407건 처리시간 0.025초

남한의 일부 중생대 화강암류의 지구화학적 연구 (Geochemical Study of Some Mesozoic Granitic Rocks in South Korea)

  • 김규한
    • 자원환경지질
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    • 제25권4호
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    • pp.435-446
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    • 1992
  • REE, major and trace elements analyses of the Jurassic Daebo granite and Cretaceous Bulguksa granite were carried out to interpet their petrogenesis and relationships between petrogenesis and tectonics. Analytical results are summarized as follows. (1) $SiO_2$ content of the Bulguksa granite (aver. 74.6%) are significantly higher than those of the Daebo granite (aver. 68.1%). Major elements of $TiO_2$, $Al_2O_3$, $P_2O_5$, CaO, MgO, Total FeO, and trace elements of Co, V and Sr are negatively correlated with $SiO_2$. Incompatible elements such as Ba, Sr, Y, Zr and HREE are contained differently in the Bulguksa granites distributed in between Okchon folded belt and Kyongsang sedimentary basin. (2) Trace element abundances show a good discrimination between two goups of granitic rocks. Ba, Sr and V are enriched in Daebo granites, while Zn and Cr are depleted in them. (3) Jurassic granites have quite different Eu anomalies and REE patterns from those of Cretaceous granites: Large negative Eu anomaly in the former and mild or absent Eu anomaly in the latter. The large Eu negative of Cretaceous granitic rocks are interpreted as a differentiated product of fractional crystallization of granitic magma from the upper mantle. Meanwhile, the Daebo plutonic rocks was resulted from the partial melting of subcrustal material or crustal contamination during ascending granitic magma from the mantle. Senario of igneous activities of Mesozoic age in South Korea was proposed based on Kula-Pacific ridge subduction model.

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통가열도 해저화산 표층 퇴적물 내 열수변질의 화학적 특성 (Chemical Characteristics for Hydrothermal Alteration of Surface Sediments from Submarine Volcanoes of the Tonga Arc)

  • 엄인권;천종화;최헌수;최만식
    • 한국광물학회지
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    • 제26권4호
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    • pp.245-262
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    • 2013
  • 통가열도 내 우리나라 해저열수광상 독점 탐사지역에 위치하는 5개 해저화산(TA12, TA19, TA22, TA25, TA26) 주변 표층 퇴적물의 열수변질 여부를 규명하고, 열수변질 특성을 확인하기 위하여 각 해저화산에서 채취된 29개의 표층 퇴적물에 대해 미량 원소와 희토류 원소 분석을 실시하였다. 분석 결과 TA12, TA19, TA22 해저화산에서는 열수에 의한 퇴적물의 변질작용이 없거나 매우 적은 것으로 나타났으며, TA25와 TA26 해저화산의 일부 지역은 현재에도 열수의 영향을 받고 있는 것으로 나타났다. 열수의 영향이 있는 해저화산 사이에도 부화된 미량 원소의 종류에 차이가 있는데, TA25 해저화산의 경우 주로 Ni, Cu, Sn, Zn, Pb, Cr, Cd, Sb, W, Ba, Ta, Rb, Sr, As가, TA26 해저화산에서는 주로 Cu, Sn, Zn, Pb, Cd, Sb, Ba, Rb, Sr이 부화되어 있다. 미량 원소의 부화가 확인된 지역은 희토류 원소의 부화도 관찰된다. 상부지각 희토류 원소 농도로 표준화된 희토류 원소의 분포형태는 가벼운 희토류 원소(LREE)가 매우 낮고 중간 희토류 원소(MREE)에서 무거운 희토류 원소(HREE)로 갈수록 증가하는 형태를 보이며, TA25와 TA26 해저화산의 일부 정점에서 Eu의 부화가 확인된다. 또한 TA26 해저화산의 일부 정점에서 Ce이 부화가 관찰되었는데, 이는 주변지역에서 채취된 열수 내 희토류 원소의 높은 Ce분포형태와 매우 유사하다. 또한 TA25와 TA26 해저화산은 부화된 원소의 특징이 다르게 나타나는데, TA25 해저화산에서는 Cu를 포함한 미량 원소가, TA26 해저화산에서는 Ce와 Eu를 포함한 희토류 원소가 우세하게 부화되어 있는 것으로 나타났다. 조사결과 나타난 각 해저화산 표층 퇴적물 내 부화된 미량 원소 및 희토류 원소의 종류와 농도는 차후 통가열도 지역의 열수광상 탐사시에 지역적인 열수변질의 지시자로써 유용하게 활용될 것으로 판단된다.

Comparison of Trace Element, Metal, and Metalloid Contents in North and South Korean Plants

  • Park, Jeong-Soo;Chung, Ha-Sook;Lee, Eun-Ju
    • 한국환경과학회지
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    • 제23권6호
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    • pp.995-1001
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    • 2014
  • When relations improve between North and South Korea, there will be demand for North Korean edible plants because of the low labor cost and similar environmental conditions. However, there is no reliable information about trace elements, metals, and metalloids in edible plants from North Korea. Selenium (Se) and germanium (Ge) have positive effects on basic human health and are therapeutical in diverse illnesses. Metal and metalloid (Cd, Pb) poisoning, on the other hand, can cause many health problems. Plants collected from North Korea had higher selenium content than those from South Korea. Although none of the collected species exceeded the permissible levels of cadmium and lead, their content in plants was significantly higher in North Korea than in South Korea. The high metal contents in plants collected from North Korea may be associated with the soil physicochemical properties as well as the accumulated amounts of elements in the soil.

서해안지역의 환경 오염에 의한 수산식품 오염실태 및 예방에 관한 연구(I. 어류) (The study on the Sea Food Pollution According to Environmental pollution of the Western Coast in Korea(I. Fish))

  • 김순경;이종화;김애정
    • 한국식품영양과학회지
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    • 제26권5호
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    • pp.851-859
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    • 1997
  • This study was perfomed to investigate the contamination level of harmful heavy metals and the level of trace elements in 15 kinds of fish collected at the western coast in Korea from July to December in 1996. The levels of total lead, cadmium, mercury, iron, copper and zinc were determined and the results were summarized as follows: The minimum and maximum values(ppm) of fish, mean value bracketed, were ; Pb : 0.02~4.80(2.26), Cd: 0.001~0.54(0.04), Hg: 0.007~1.08(0.52), Fe: 7.76~66.39(25.70), Cu; 0.37~121.6(1.90), Zn:12.01~112.10(54.78). The results show that mean contents of Pb, Cd and Hg in 15 species fish were not yet dangerous levels enough to cause a health problem. But the contents of Pb and Hg tend to increase.

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한국인 모발과 내부장기조직간 Cd, Hg, Pb 및 Zn함량의 상호관련성 (Relationships in Cd, Hg, Pb and Zn Concentrations Between Hair and Internal Organs of Korean)

  • 유영찬;이상기;양자열;김기욱;이수연;정규혁
    • Environmental Analysis Health and Toxicology
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    • 제17권1호
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    • pp.21-27
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    • 2002
  • In order to study the relationships between trace element concentrations of hair and internal organs, autopsy samples of hair, liver, kidney cortex, kidney medulla, heart, lung, spleen, cerebrum, testis and bone from 162 Korean subjects were analyzed for Cd, Hg, Pb and Zn by inductively coupled plasma atomic emission spectrometry. High significant positive correlations were found between the Cd concentration in hair and bone and Pb in hair and lung. Hair Hg levels were highly significantly correlated with organ Hg levels in the liver, kidney cortex, kidney medulla, heart, lung, spleen, cerebrum, testis and bone. And hair Zn levels were highly significantly correlated with organ Zn levels in the kidney cortex, kidney medulla, spleen, testis and bone.

먹는샘물 중의 건강과 맛에 영향을 미치는 화학성분의 분석 (Determination of the Chemical Constituents to Affect the Health and Taste in Bottled Drinking Waters)

  • 이남례;김영만;최범석
    • 분석과학
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    • 제10권6호
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    • pp.459-467
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    • 1997
  • Due to the growing demand for bottled mineral waters, a study was undertaken to determine the quality of the twenty six brands of domestic and imported drinking waters. The quality of water was evaluated by analyzing the twenty four elements including minerals, essential and/or toxic trace elements, and the analytical items to affect the taste of water. The contribution of drinking water to the mineral nutrition of human was calculated in order to investigate the health effect of drinking water. The taste of water was evaluated in terms of minerals, anions, TDS, alkalinity, hardness and pH.

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한국산 김중의 미량금속 함량 조사연구 (A Study of the Trace Elements in Sea-weed (Dried Laver))

  • 윤혜경;노영수
    • Environmental Analysis Health and Toxicology
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    • 제12권3_4호
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    • pp.67-73
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    • 1997
  • This study was carried out to investigate the contents of heavy metals such as iron, copper, lead, cadmium, magnesium, platium in connection with water pollution in sea weed (dried laver) collected from the west, south, south- west, and east coasts of Korea. The results of the study are as follows; Iron was shown the highest value (1.280ppm) in the wild laver from the south coast. Copper was detected in larger qauntities (0.169 ppm) in green laver than in any other kinds of laver observed in this study. Lead was detected in larger quantities (0.195ppm) in the usual laver and green laver from the south-west coast as compared with the other coasts. Although cadmium and platium was also detected from every kind of laver, the concentrations were not over the allowance of the residual.

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균열해석을 위한 겹침확장 유한요소법 (Combined Extended and Superimposed Finite Element Method for Crack Analysis)

  • 이상호;송정훈;허문석
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 2004년도 봄 학술발표회 논문집
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    • pp.341-348
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    • 2004
  • This paper presents a modeling technique of cracks by combined extended and superposed finite element method (XSFEM) which is a combination of the extended finite element method (XFEM) and the mesh superposition method (sversion FEM). In the proposed method, the near-tip field is modeled by a superimposed patch consisting of quarter point elements and the rest of the discontinuity is treated by the XFEM. The actual crack opening in this method is measured by the sum of the crack openings of XFEM and SFEM in transition region. This method retains the strong point of the XFEM so it can avoid remeshing in crack evolution and trace the crack growth by translation or rotation of the overlaid mesh and the update of the nodes to be enriched by step functions. Moreover, the quadrature of the Galerkin weak form becomes simpler. Numerical experiments are provided to demonstrate the effectiveness and robustness of the proposed method.

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호장법을 이용한 공간구조의 기하학적 비선형 해석에 관한 연구 (A Study on the Geometrically Nonlinear Analysis of Spatial Structures by Using Arc Length Method)

  • 한상을;이상주;이경수
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 2007년도 정기 학술대회 논문집
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    • pp.381-386
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    • 2007
  • The present study is concerned with the application of Constant arc-length method that proposed by Crisfield in the investigation of the geometrically nonlinear behaviour of spatial structures composed by truss or beam element. The arc-length method can trace the full nonlinear equilibrium path of Spatial structure far beyond the critical point such as limit or bifurcation point. So, we have developed the constant arc-length method of Crisfield to analysis spatial structure. The finite element formulation is used to develop the 3d truss/beam element including the geometrical nonlinear effect. In an effort to evaluate the merits of the methods, extensive numerical studies were carried out on a number of selected structural systems. The advantages of Constant arc length method in tracing the post-buckling behavior of spatial structures, are demonstrated.

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Flexural Modeling of Strengthened Reinforced Concrete Beam with Nonlinear Layered Finite Element Method

  • Kim, Min-Kyung;Lee, Cha-Don
    • KCI Concrete Journal
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    • 제11권3호
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    • pp.115-126
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    • 1999
  • An analytical method based on the nonlinear layered finite element method is developed to simulate an overall load-deflection behavior of strengthened beams. The developed model distinguishes itself by its capability to trace residual flexural behavior of a beam after the fracture of brittle strengthening materials at peak load. The model. which uses a rather advanced numerical technique for iterative convergence to equilibrium, can be regarded as superior to the two models based on load control and displacement control The model predictions were compared with the experimental results and it was observed that there was good agreement between them.

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