• Title/Summary/Keyword: Trace Element

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Geochemical Study of Some Mesozoic Granitic Rocks in South Korea (남한의 일부 중생대 화강암류의 지구화학적 연구)

  • Kim, Kyu Han
    • Economic and Environmental Geology
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    • v.25 no.4
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    • pp.435-446
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    • 1992
  • REE, major and trace elements analyses of the Jurassic Daebo granite and Cretaceous Bulguksa granite were carried out to interpet their petrogenesis and relationships between petrogenesis and tectonics. Analytical results are summarized as follows. (1) $SiO_2$ content of the Bulguksa granite (aver. 74.6%) are significantly higher than those of the Daebo granite (aver. 68.1%). Major elements of $TiO_2$, $Al_2O_3$, $P_2O_5$, CaO, MgO, Total FeO, and trace elements of Co, V and Sr are negatively correlated with $SiO_2$. Incompatible elements such as Ba, Sr, Y, Zr and HREE are contained differently in the Bulguksa granites distributed in between Okchon folded belt and Kyongsang sedimentary basin. (2) Trace element abundances show a good discrimination between two goups of granitic rocks. Ba, Sr and V are enriched in Daebo granites, while Zn and Cr are depleted in them. (3) Jurassic granites have quite different Eu anomalies and REE patterns from those of Cretaceous granites: Large negative Eu anomaly in the former and mild or absent Eu anomaly in the latter. The large Eu negative of Cretaceous granitic rocks are interpreted as a differentiated product of fractional crystallization of granitic magma from the upper mantle. Meanwhile, the Daebo plutonic rocks was resulted from the partial melting of subcrustal material or crustal contamination during ascending granitic magma from the mantle. Senario of igneous activities of Mesozoic age in South Korea was proposed based on Kula-Pacific ridge subduction model.

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Chemical Characteristics for Hydrothermal Alteration of Surface Sediments from Submarine Volcanoes of the Tonga Arc (통가열도 해저화산 표층 퇴적물 내 열수변질의 화학적 특성)

  • Um, In Kwon;Chun, Jong-Hwa;Choi, Hunsoo;Choi, Man Sik
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.4
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    • pp.245-262
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    • 2013
  • We analyzed 29 surface sediment samples in five submarine volcanoes (TA12, TA19, TA22, TA25, and TA26) located in the southern part of the Tonga arc for trace elements and rare earth elements to investigate characteristics of the hydrothermal alteration of surface sediments. Based on analytical results of trace element and rare earth element (REE), surface sediments of TA12, TA19, and TA22 submarine volcanoes, which are located in the northern part of the study area, were very little or not influenced by hydrothermal fluids. In contrast, some stations of TA25 and TA26 submarine volcanoes were strongly affected by hydrothermal fluids. However, these two submarine volcanoes showed different features in element concentration in the sediments. Some stations of TA25 submarine volcano showed enrichment of Ni, Cu, Sn, Zn, Pb, Cr, Cd, Sb, W, Ba, Ta, Rb, Sr, and As, however, those of TA26 submarine volcano showed enrichment of Sn, Zn, Pb, Cd, Sb, Ba, Rb, and Sr. Stations which enriched trace elements were observed, enriched REEs were also observed. Average upper continental crust (UCC)-normalized REE patterns of the surface sediments generally showed low light REE (LREE) abundances and increased heavy REE (HREE) abundances. Eu enrichment was identified at several stations of TA25 and TA26 submarine volcanoes. In addition, enrichment of Ce was found at some stations of TA26 submarine volcano and these enrichment patterns were similar with hydrothermal fluid of near stations. Furthermore, TA25 and TA26 submarine volcanoes showed different enrichment characteristics of trace elements and REE. Trace elements were concentrated at TA25 submarine volcano. TA26 submarine volcano, on the other hand, observed highly enrichment of REE especially, Eu and Ce. As a result of the investigation, the characteristics and concentrations of REEs and trace elements in the surface sediments of each submarine volcano can be applied to identify hydrothermal alteration of sediments during exploration for hydrothermal deposits.

Comparison of Trace Element, Metal, and Metalloid Contents in North and South Korean Plants

  • Park, Jeong-Soo;Chung, Ha-Sook;Lee, Eun-Ju
    • Journal of Environmental Science International
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    • v.23 no.6
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    • pp.995-1001
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    • 2014
  • When relations improve between North and South Korea, there will be demand for North Korean edible plants because of the low labor cost and similar environmental conditions. However, there is no reliable information about trace elements, metals, and metalloids in edible plants from North Korea. Selenium (Se) and germanium (Ge) have positive effects on basic human health and are therapeutical in diverse illnesses. Metal and metalloid (Cd, Pb) poisoning, on the other hand, can cause many health problems. Plants collected from North Korea had higher selenium content than those from South Korea. Although none of the collected species exceeded the permissible levels of cadmium and lead, their content in plants was significantly higher in North Korea than in South Korea. The high metal contents in plants collected from North Korea may be associated with the soil physicochemical properties as well as the accumulated amounts of elements in the soil.

The study on the Sea Food Pollution According to Environmental pollution of the Western Coast in Korea(I. Fish) (서해안지역의 환경 오염에 의한 수산식품 오염실태 및 예방에 관한 연구(I. 어류))

  • 김순경;이종화;김애정
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.5
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    • pp.851-859
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    • 1997
  • This study was perfomed to investigate the contamination level of harmful heavy metals and the level of trace elements in 15 kinds of fish collected at the western coast in Korea from July to December in 1996. The levels of total lead, cadmium, mercury, iron, copper and zinc were determined and the results were summarized as follows: The minimum and maximum values(ppm) of fish, mean value bracketed, were ; Pb : 0.02~4.80(2.26), Cd: 0.001~0.54(0.04), Hg: 0.007~1.08(0.52), Fe: 7.76~66.39(25.70), Cu; 0.37~121.6(1.90), Zn:12.01~112.10(54.78). The results show that mean contents of Pb, Cd and Hg in 15 species fish were not yet dangerous levels enough to cause a health problem. But the contents of Pb and Hg tend to increase.

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Relationships in Cd, Hg, Pb and Zn Concentrations Between Hair and Internal Organs of Korean (한국인 모발과 내부장기조직간 Cd, Hg, Pb 및 Zn함량의 상호관련성)

  • 유영찬;이상기;양자열;김기욱;이수연;정규혁
    • Environmental Analysis Health and Toxicology
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    • v.17 no.1
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    • pp.21-27
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    • 2002
  • In order to study the relationships between trace element concentrations of hair and internal organs, autopsy samples of hair, liver, kidney cortex, kidney medulla, heart, lung, spleen, cerebrum, testis and bone from 162 Korean subjects were analyzed for Cd, Hg, Pb and Zn by inductively coupled plasma atomic emission spectrometry. High significant positive correlations were found between the Cd concentration in hair and bone and Pb in hair and lung. Hair Hg levels were highly significantly correlated with organ Hg levels in the liver, kidney cortex, kidney medulla, heart, lung, spleen, cerebrum, testis and bone. And hair Zn levels were highly significantly correlated with organ Zn levels in the kidney cortex, kidney medulla, spleen, testis and bone.

Determination of the Chemical Constituents to Affect the Health and Taste in Bottled Drinking Waters (먹는샘물 중의 건강과 맛에 영향을 미치는 화학성분의 분석)

  • Lee, Nam-Rae;Kim, Young-Man;Choi, Beom-Suk
    • Analytical Science and Technology
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    • v.10 no.6
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    • pp.459-467
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    • 1997
  • Due to the growing demand for bottled mineral waters, a study was undertaken to determine the quality of the twenty six brands of domestic and imported drinking waters. The quality of water was evaluated by analyzing the twenty four elements including minerals, essential and/or toxic trace elements, and the analytical items to affect the taste of water. The contribution of drinking water to the mineral nutrition of human was calculated in order to investigate the health effect of drinking water. The taste of water was evaluated in terms of minerals, anions, TDS, alkalinity, hardness and pH.

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A Study of the Trace Elements in Sea-weed (Dried Laver) (한국산 김중의 미량금속 함량 조사연구)

  • 윤혜경;노영수
    • Environmental Analysis Health and Toxicology
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    • v.12 no.3_4
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    • pp.67-73
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    • 1997
  • This study was carried out to investigate the contents of heavy metals such as iron, copper, lead, cadmium, magnesium, platium in connection with water pollution in sea weed (dried laver) collected from the west, south, south- west, and east coasts of Korea. The results of the study are as follows; Iron was shown the highest value (1.280ppm) in the wild laver from the south coast. Copper was detected in larger qauntities (0.169 ppm) in green laver than in any other kinds of laver observed in this study. Lead was detected in larger quantities (0.195ppm) in the usual laver and green laver from the south-west coast as compared with the other coasts. Although cadmium and platium was also detected from every kind of laver, the concentrations were not over the allowance of the residual.

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Combined Extended and Superimposed Finite Element Method for Crack Analysis (균열해석을 위한 겹침확장 유한요소법)

  • 이상호;송정훈;허문석
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2004.04a
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    • pp.341-348
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    • 2004
  • This paper presents a modeling technique of cracks by combined extended and superposed finite element method (XSFEM) which is a combination of the extended finite element method (XFEM) and the mesh superposition method (sversion FEM). In the proposed method, the near-tip field is modeled by a superimposed patch consisting of quarter point elements and the rest of the discontinuity is treated by the XFEM. The actual crack opening in this method is measured by the sum of the crack openings of XFEM and SFEM in transition region. This method retains the strong point of the XFEM so it can avoid remeshing in crack evolution and trace the crack growth by translation or rotation of the overlaid mesh and the update of the nodes to be enriched by step functions. Moreover, the quadrature of the Galerkin weak form becomes simpler. Numerical experiments are provided to demonstrate the effectiveness and robustness of the proposed method.

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A Study on the Geometrically Nonlinear Analysis of Spatial Structures by Using Arc Length Method (호장법을 이용한 공간구조의 기하학적 비선형 해석에 관한 연구)

  • Han, Sang-Eul;Lee, Sang-Ju;Lee, Kyoung-Soo
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2007.04a
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    • pp.381-386
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    • 2007
  • The present study is concerned with the application of Constant arc-length method that proposed by Crisfield in the investigation of the geometrically nonlinear behaviour of spatial structures composed by truss or beam element. The arc-length method can trace the full nonlinear equilibrium path of Spatial structure far beyond the critical point such as limit or bifurcation point. So, we have developed the constant arc-length method of Crisfield to analysis spatial structure. The finite element formulation is used to develop the 3d truss/beam element including the geometrical nonlinear effect. In an effort to evaluate the merits of the methods, extensive numerical studies were carried out on a number of selected structural systems. The advantages of Constant arc length method in tracing the post-buckling behavior of spatial structures, are demonstrated.

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Flexural Modeling of Strengthened Reinforced Concrete Beam with Nonlinear Layered Finite Element Method

  • Kim, Min-Kyung;Lee, Cha-Don
    • KCI Concrete Journal
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    • v.11 no.3
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    • pp.115-126
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    • 1999
  • An analytical method based on the nonlinear layered finite element method is developed to simulate an overall load-deflection behavior of strengthened beams. The developed model distinguishes itself by its capability to trace residual flexural behavior of a beam after the fracture of brittle strengthening materials at peak load. The model. which uses a rather advanced numerical technique for iterative convergence to equilibrium, can be regarded as superior to the two models based on load control and displacement control The model predictions were compared with the experimental results and it was observed that there was good agreement between them.

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