• Title/Summary/Keyword: Total organic carbon(TOC)

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Nitrate Removal by Immobilized Denitrifying Bacteria in Recirculating Aquaculture System (순환여과식 양식 시스템에 있어서의 고정화 탈진균에 의한 질산염 제거)

  • 김상희;김필균;김중균
    • Journal of Life Science
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    • v.9 no.6
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    • pp.698-703
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    • 1999
  • For the nitrate removal in recirculating aquaculture system, a denitrifying bacterium, Pseudomonas fluorescens, was isolated from municipal sewage and the cells were immobilized in modified-polyvinly alchol (PVA) gel beads. The immobilized cells in both the fixed-and fluidized-bed reactors showed 98% of denitrification efficiency with 6hr HRT, and the removal efficiency of total organic carbon (TOC) was above 90%. Form scanning electron microscopy (SEM) observation, it was known that biofilm formed in fixed-bed reactor was thicker than that formed in fluidized-bed reactor as operation time passed.

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Pollution Status of Surface Sediment in Jinju Bay, a Spraying Shellfish Farming Area, Korea (살포식 패류양식해역인 진주만 표층 퇴적물의 오염도)

  • Lee, Garam;Hwang, Hyunjin;Kim, Jeong Bae;Hwang, Dong-Woon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.4
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    • pp.392-402
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    • 2020
  • We investigated the concentrations of acid volatile sulfide (AVS), ignition loss (IL), total organic carbon (TOC), total nitrogen (TN), and metallic elements (As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, and Zn), in August 2015, to determine the spatial distribution and pollution status of organic matter and metals in the surface sediment of Jinju Bay, a spraying shellfish farming area, Korea. The concentrations of organic matter and metallic elements were significantly higher in the southern part of the bay than in the mouth and center of the bay. The C/N ratio (5.7~8.0) in the sediment represents the dominance of organic matter of oceanic origin in the surface sediment of the study area. The concentrations of AVS, TOC, and metals (As, Cd, Cr, Cu, Hg, Pb, and Zn) were much lower than the values of the sediment quality guidelines applied in Korea. Based on the results of the pollution load index (PLI) and ecological risk index (ERI), the metal concentrations in the surface sediment of Jinju Bay have a weakly negative ecological effect on benthic organisms although the sediments with high metal pollution status are distributed in the southern parts of the bay, with high dense shellfish farming areas. Thus, the surface sediments in Jinju Bay are not polluted with organic matter and are slightly polluted with metallic elements.

Analyzing the Influence of Biomass and Vegetation Type to Soil Organic Carbon - Study on Seoseoul Lake Park and Yangjae Citizen's Forest - (바이오매스량과 식생구조가 토양 탄소함유량에 미치는 영향 분석 - 서서울호수공원과 양재 시민의 숲을 대상으로 -)

  • Tanaka, Riwako;Kim, Yoon-Jung;Ryoo, Hee-Kyung;Lee, Dong-Kun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.17 no.1
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    • pp.123-134
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    • 2014
  • Identification of methods to optimize the growth of a plant community, including the capacity of the soil to further sequester carbon, is important in urban design and planning. In this study, to construct and manage an urban park to mitigate carbon emissions, soil organic carbon of varying biomass, different park construction times, and a range of vegetation types were analyzed by measuring aboveground and belowground carbon in Seoseoul Lake Park and Yangjae Citizen's Forest. The urban parks were constructed during different periods; Seoseoul Lake Park was constructed in 2009, whereas Yangjae Citizen's Forest was constructed in 1986. To identify the differences in soil organic carbon in various plant communities and soil types, above and belowground carbon were measured based on biomass, as well as the physical and chemical features of the soil. Allometric equations were used to measure biomass. Soil total organic carbon (TOC) and chemical properties such as pH, cation exchange capacity (CEC), total nitrogen (TN), and soil microbes were analyzed. The analysis results show that the biomass of the Yangjae Citizen's Forest was higher than that of the Seoseoul Lake Park, indicating that older park has higher biomass. On the other hand, TOC was lower in the Yangjae Citizen's Forest than in the Seoseoul Lake Park; air pollution and acid rain probably changed the acidity of the soil in the Yangjae Citizen's Forest. Furthermore, TOC was higher in mono-layered plantation area compared to that in multi-layered plantation area. Improving the soil texture would, in the long term, result in better vegetation growth. To improve the soil texture of an urban park, park management, including pH control by using lime fertilization, soil compaction control, and leaving litter for soil nutrition is necessary.

Effect of Light/dark Cycles on Wastewater Treatments by Microalgae

  • Lee, Kwangyong;Lee, Choul-Gyun
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.3
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    • pp.194-199
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    • 2001
  • Chlorella kessleri cultivated in artificial wastewater using diurnal illumination of 12h light/12h dark (L/D) cycles. The inoculum density was 10(sup)5 cells/mL and the irradiance in light cycle was 45$\mu$mol㎡s(sup)-1 at the culture surface. As a control culture, another set of flasks was cultivated under continuous illumination. Regardless of the illumination scheme, the total organic carbon (TOC) and chemical oxygen demand (COD) was reduced below 20% of the initial concentration within a day. However, cell concentration under the L/D lighting scheme was lower tan that under the continuous illuminating scheme. Thus the specific removal rate of organic carbon under L/D cycles was higher than that under continuous illumination. This result suggested that C. kessleri grew chemoorganotrophically in the dark periods. After 3 days, nitrate was reduced to 136.5 and 154.1mg NO$_3$-N/L from 168.1mg NO$_3$-N/L under continuous illumination and under diurnal cycles, respectively. These results indicate nitrate removal efficiency under continuous light was better than that under diurnal cycles. High-density algal cultures using optimized photobioreactors with diurnal cycles will save energy and improve organic carbon sources removal.

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Effect of Mercury and Lead on the Biochemical Oxygen Demand (BOD) (수중(水中) 수은(水銀) 및 鉛(연)의 농도(濃度)가 BOD값에 미치는 영향(影響)에 관(關)하여)

  • Moon, Jai-Dong
    • Journal of Preventive Medicine and Public Health
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    • v.17 no.1
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    • pp.217-221
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    • 1984
  • In order to estimate interfering effects of mercury and lead on biochemical oxygen demand (BOD), BOD in 18 effluent samples were measured under three different concentrations of mercury and lead. The results obtained were as follows: 1. Biochemical oxygen demand(BOD) was decreased under the presence of mercury and lead, with parallel correlation of mercury concentration. 2. High correlations were noted between original BOD concentration and decreasing amount of BOD when concentrations of mercury or lead were increased. 3. When the lead concentration was high, the close correlation was observed between total organic carbon(TOC) and decreasing amount of BOD. 4. There was a negative correlation between TOC/BOD ratio and decreasing amount of BOD when the mercury concentrations were high.

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The decolorization treatment of dye solutions by ozone (Ozone을 이용한 염료용액의 탈색 처리)

  • Lee, Soo-Kyung;Cho, Hwan;Jeong, Hee-Cheon
    • Textile Coloration and Finishing
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    • v.8 no.5
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    • pp.17-24
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    • 1996
  • Dye solutions were tested in order to find the optimal condition of ozonation and determine the progress of degradation, i.e., change of the parameters characterizing the dye solutions. From the results of our experiment we can conclude that almost all of the color was removed within a 10 minute time period. An ozone oxidation results in the effective removal of COD(60%). but the elimination of the total organic carbon(TOC) was not successful, only about 15~40% of TOC was removed from dyeing wastewater in 30 minutes. The color removal is much effective in using ozonation method.

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Changes in temporal and spatial stream water concentrations and analysis on nonpoint source runoff in forested watersheds on non rainfall days (산림소유역 유출수의 비강우일 비점오염물질 농도 변화 및 유출 특성 분석)

  • Yoo, Hyeon-Ju;Choi, Hyung-Tae;Kim, Jae-Hoon;Lim, Hong-Geun;Yang, Hyun-Je
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.23 no.6
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    • pp.137-149
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    • 2020
  • This study was carried out to analyze the monthly runoff concentration on non rainfall days in order to prepare basic data to compare the runoff concentration on rainfall days in 7 forest watersheds in the Republic of Korea. Forest stream water has been collected through 15 times of sampling in each watershed and analyzed based on the changes in concentration of Biochemical Oxygen Demand(BOD), Chemical Oxygen Demand(COD), Total Organic Carbon(TOC), Total Nitrogen(TN), and Total Phosphorus(TP). The average concentration was 0.8 mg/L for BOD, 1.4 mg/L for COD, 0.8 mg/L for TOC, 1.85 mg/L for TN and 0.002 mg/L for TP during non rainfall days. Coniferous forested watersheds showed higher value of TN and TP concentration. Concentrations of BOD and TP in early March (p<0.01) were affected by melt water flow input in spring season. Significant differences (p<0.01) in concentrations were observed in BOD and TOC, indicating seasonal rainfall and vegetation growth impacts on forest stream quality. Concentration of TN and TP showed significant positive correlation, and weak negative correlation was found in the concentration of BOD and TOC. It is expected that result of forest stream water on non rainfall days could be basic information in managing non-point source from forest watersheds.

Distributions of Organic Matter and Heavy Metals in the Surface Sediment of Jaran Bay, Korea (자란만 표층 퇴적물 중 유기물과 중금속 농도분포)

  • Hwang, Hyunjin;Hwang, Dong-Woon;Lee, Garam;Kim, Hyung-Chul;Kwon, Jung-No
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.1
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    • pp.78-91
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    • 2018
  • In order to understand the distributions of organic matter and heavy metal concentrations in the surface sediment of Jaran Bay, we measured the grain size, total organic carbon (TOC), total nitrogen (TN), and heavy metals (As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, and Zn) in surface sediments collected at 15 stations in this bay in November 2014. The sediment consisted of finer sediment such as mud and clay, with 8.6-9.8Ø($9.3{\pm}0.3$Ø) of mean grain size. The concentrations of TOC and TN in the sediment ranged from 1.51-2.39 % ($1.74{\pm}0.22%$) and 0.20-0.33 % ($0.23{\pm}0.03%$), respectively, and did not show spatial difference. The carbon to nitrogen ratio (C/N ratio) ranged from 5-10, indicating that organic matter in the sediment originated from oceanic sources such as animal by-products from fish and shellfish farms. The concentrations of Cr, Fe, and Mn were much higher in the mouth of the bay than in the inner bay, and the concentrations of As, Cd, Cu, Hg, Pb, and Zn showed an opposite distribution pattern. Based on the results of the sediment quality guidelines (SQGs), enrichment factor (EF), geoaccumulation index ($I_{geo}$), pollutant load index (PLI), and ecological risk index (ERI), the surface sediment in Jaran Bay is not polluted or only slightly polluted with Cd, Cr, Cu, Hg, Pb, and Zn, whereas it is moderately to strongly polluted with As. In particular, some regions in the bay were identified as having a considerable risk status, indicating that metal concentration in the sediment could impact benthic organisms. Thus, the systematic management for marine and land sources of organic matter and heavy metals around Jaran Bay is necessary in order to ensure seafood safety and maintain sustainable production on shellfish farms.

Treatment of Pharmaceutical Wastewaters by Hydrogen Peroxide and Zerovalent Iron

  • Jeon, Byeong-Cheol;Nam, Se-Yong;Kim, Young-Kwon
    • Environmental Engineering Research
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    • v.19 no.1
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    • pp.9-14
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    • 2014
  • Fenton reaction with zerovalent iron (ZVI) and $Fe^{2+}$ ions was studied to treat pharmaceutical wastewaters (PhWW) including antibiotics and non-biodegradable organics. Incremental biodegradability was assessed by monitoring biochemical oxygen demand (BOD) changes during Fenton reaction. Original undiluted wastewater samples were used as collected from the pharmaceutical factory. Experiments were carried out to obtain optimal conditions for Fenton reaction under different $H_2O_2$ and ion salts (ZVI and $Fe^{2+}$) concentrations. The optimal ratio and dosage of $H_2O_2$/ZVI were 5 and 25/5 g/L (mass basis), respectively. Also, the optimal ratio and dosage of $H_2O_2/Fe^{2+}$ ions were 5 and 35/7 g/L (mass basis), respectively. Under optimized conditions, the chemical oxygen demand (COD) removal efficiency by ZVI was 23% better than the treatment with $Fe^{2+}$ ion. The reaction time was 45 min for ZVI and shorter than 60 min for $Fe^{2+}$ ion. The COD and total organic carbon (TOC) were decreased, but BOD was increased under the optimal conditions of $H_2O_2$/ZVI = 25/5 g/L, because organic compounds were converted into biodegradable intermediates in the early steps of the reaction. The BOD/TOC ratio was increased, but reverse-wise, the COD/TOC was decreased because of generated intermediates. The biodegradability was increased about 9.8 times (BOD/TOC basis), after treatment with ZVI. The combination of chemical and biological processes seems an interesting combination for treating PhWW.

Composition of Organic Compounds in the Ambient PM10 of the Anmyon Island (안면도 미세먼지 내 유기성분들의 분포 특성)

  • Lee, Ji Yi;Hwang, Eun Jin;Lim, Hyung Bae;Kim, Yu Won;Kim, Eun Sil;Kim, Yong Pyo
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.187-197
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    • 2013
  • To understand the characteristics of organic aerosol(OA) at the background atmosphere of Korea, an observation of atmospheric PM10 was conducted at a Global Atmospheric Watch(GAW) station operated by the Korean Meteorological Administration at Anmyon Island during 2010. Various organic compounds were analyzed from 26 samples by using a gas chromatography-mass spectrometer. Water soluble organic carbon(WSOC) was also analyzed by using a total organic carbon(TOC) analyzer. Among 6 classes with 68 target compounds detected, the classes of n-alkanoic and alkenoic acids ($326.67{\pm}75.40ngm^{-3}$) and dicarboxylic acids ($323.74{\pm}361.89ngm^{-3}$) were found to be major compound classes in the atmosphere of Anmyon Island. Compared to the previous results reported for 2005 spring samples at Gosan site, the concentrations of organic compounds at Anmyon Island were 3-10 times higher than Gosan site due to the difference of location and sampling period. The concentrations of organic compounds were varied with the atmospheric conditions. Significant increase of the concentrations of dicarboxylic and carboxylic acids in the smog episode indicated that secondary oxidation of organic compounds was major factor to increase OA concentration during smog episode in the Anmyon Island. It was found that the compositions of the OA measured at Anmyon Island were dependent on the air parcel trajectories.