• 제목/요약/키워드: Titanium aluminide

검색결과 17건 처리시간 0.018초

Mo, Nb첨가가 TiAl합금의 산화에 미치는 영향 (Effect of Mo and Nb on High Temperature Oxidation of TiAl Alloys)

  • 김재운;이동복
    • 한국재료학회지
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    • 제14권9호
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    • pp.614-618
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    • 2004
  • Alloys of $Ti46\%Al-2\%Mo-2\%Nb$ were oxidized between 800 and $1000^{\circ}C$ in air, and their oxidation characteristics were studied. The alloys displayed good oxidation resistance due mainly to the beneficial effects of Mo and Nb. The oxide scales formed consisted primarily of an outer $TiO_2$ layer, an intermediate $Al_{2}O_3-rich$ layer, and an inner mixed layer of ($TiO_{2}+Al_{2}O_3$). Molybdenum and niobium dissolved in the scale effectively improved oxidation resistance. They were mainly distributed in the inner mixed layer of ($TiO_{2}+Al_{2}O_3$).

열기계적 처리한 Ti-45.4%Al-4.8%Nb 합금의 고온산화 (High Temperature Oxidation of Thermomechanically Treated Ti-45.4%Al-4.8%Nb Alloys)

  • 김재운;이동복
    • 한국재료학회지
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    • 제14권7호
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    • pp.457-461
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    • 2004
  • The thermomechanically treated $Ti-45.4\%Al-4.8\%Nb(at\%)$ alloy was oxidized between 800 and $1000^{\circ}C$ in air, and the oxidation characteristics were studied. The dissolution of Nb in the oxide scale was observed from the TEM study. The Pt marker test revealed that the oxidation process was controlled by the outward diffusion of Ti ions and the inward diffusion of oxygen ions. During oxidation, the evaporation of Nb-oxides was found to occur to a small amount. Niobium tended to pile-up at the lower part of the oxide scale, which consisted primarily of an outer $TiO_2$ layer, and an intermediate $Al_{2}O_{3}-rich$ layer, and an inner mixed layer of ($TiO_{2}+Al_{2}O_{3}$).

Ti-43%Al-2%W-0.1%Si 합금의 고온산화 (High Temperature Oxidation of Ti-43%Al-2%W-0.1%Si Alloys)

  • 심웅식;이동복
    • 한국표면공학회지
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    • 제36권2호
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    • pp.128-134
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    • 2003
  • Alloys of Ti-43%Al-2%W-0.1%Si were oxidized isothermally and cyclically between $900^{\circ}C$ and$ 1050^{\circ}C$, and their oxidation characteristics were studied. During isothermal tests, the alloys oxidized slowly up to 100$0^{\circ}C$, but fast at $1050^{\circ}C$. Though the scale adherence was not good above $900^{\circ}C$, the alloys displayed better oxidation behavior than unalloyed TiAl alloys. The oxide scales consisted primarily of an outer $TiO_2$ layer, intermediate $Al_2$$O_3$-rich layer, and an inner mixed layer of (TiO$_2$ $+Al_2$$O_3$). Tungsten was present mainly at the lower part of the oxide scale, while Si over the whole oxide scale.

Powder Metallurgy for Light Weight and Ultra-Light Weight Materials

  • Kieback, B.;Stephani, G.;Weiβgarber, T.;Schubert, T.;Waag, U.;Bohm, A.;Anderson, O.;Gohler, H.;Reinfried, M.
    • 한국분말재료학회지
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    • 제10권6호
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    • pp.383-389
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    • 2003
  • As in other areas of materials technology, the tendency towards light weight constructions becomes more and more important also for powder metallurgy. The development is mainly driven by the automotive industry looking for mass reduction of vehicles as a major factor for fuel economy. Powder metallurgy has to offer a number of interesting areas including the development of sintered materials of light metals. PM aluminium alloys with improved properties are on the way to replace ferrous pars. For high temperature applications in the engine, titanium aluminide based materials offer a great potential, e.g. for exhaust valves. The PM route using elemental powders and reactions sintering is considered to be a cost effective way for net shape parts production. Furthermore it is expected that lower costs for titanium raw materials coming from metallurgical activities will offer new chances for sintered parts with titanium alloys. The field of cellular metals expands with the hollow sphere technique, that can provide materials of many metals and alloys with a great flexibility in structure modifications. These structures are expected to be used in improving the safety (crash absoption) and noise reduction in cars in the near future and offer great potential for many other applications.

Characterization of rapidly consolidated γ-TiAl

  • Kothari, Kunal;Radhakrishnan, Ramachandran;Sudarshan, Tirumalai S.;Wereley, Norman M.
    • Advances in materials Research
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    • 제1권1호
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    • pp.51-74
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    • 2012
  • A powder metallurgy-based rapid consolidation technique, Plasma Pressure Compaction ($P^2C^{(R)}$), was utilized to produce near-net shape parts of gamma titanium aluminides (${\gamma}$-TiAl). Micron-sized ${\gamma}$-TiAl powders, composed of Ti-50%Al and Ti-48%Al-2%Cr-2%Nb (at%), were rapidly consolidated to form near-net shape ${\gamma}$-TiAl parts in the form of 1.0" (25.4 mm) diameter discs, as well as $3"{\times}2.25"$ ($76.2mm{\times}57.2mm$) tiles, having a thickness of 0.25" (6.35 mm). The ${\gamma}$-TiAl parts were consolidated to near theoretical density. The microstructural morphology of the consolidated parts was found to vary with consolidation conditions. Mechanical properties exhibited a strong dependence on microstructural morphology and grain size. Because of the rapid consolidation process used here, grain growth during consolidation was minimal, which in turn led to enhanced mechanical properties. Consolidated ${\gamma}$-TiAl samples corresponding to Ti-48%Al-2%Cr-2%Nb composition with a duplex microstructure (with an average grain size of $5{\mu}m$) exhibited superior mechanical properties. Flexural strength, ductility, elastic modulus and fracture toughness for these samples were as high as 1238 MPa, 2.3%, 154.58 GPa and 17.95 MPa $m^{1/2}$, respectively. The high temperature mechanical properties of the consolidated ${\gamma}$-TiAl samples were characterized in air and vacuum and were found to retain flexural strength and elastic modulus for temperatures up to $700^{\circ}C$. At high temperatures, the flexural strength of ${\gamma}$-TiAl samples with Ti-50%Al composition deteriorated in air by 10% as compared to that in vacuum. ${\gamma}$-TiAl samples with Ti-48%Al-2%Nb-2%Cr composition exhibited better if not equal flexural strength in air than in vacuum at high temperatures.

$\gamma$-TiAl 합금의 고온변형 및 Cavity 형성 연구 (A Study on the High Temperature Deformation and the Cavity Initiation of Gamma TiAl Alloy)

  • 김정한;하태권;장영원;이종수
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2001년도 춘계학술대회 논문집
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    • pp.172-175
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    • 2001
  • The high temperature deformation behavior of two-phase gamma TiAl alloy has been investigated with the variation of temperature and ${\gamma}/{\alpha}_2$ volume fraction. For this purpose, a series of load relaxation tests and tensile tests have been conducted at temperature ranging from 800 to $1050^{\circ}C$. In the early stage of the deformation as in the load relaxation test experimental flow curves of the fine-grained TiAl alloy are well fitted with the combined curves of two processes (grain matrix deformation and dislocation climb) in the inelastic deformation theory. The evidence of grain boundary sliding has not been observed at this stage. However, when the amount of deformation is large (${\epsilon}{\approx}$ 0.8), flow curves significantly changes its shape indicating that grain boundary sliding also operates at this stage, which has been attributed to the occurrence of dynamic recrystallization during the deformation. With the increase in the volume fraction of ${\alpha}_2$-phase, the flow stress for grain matrix deformation increases since ${\alpha}_2$-Phase is considered as hard phase acting as barrier for dislocation movement. It is considered that cavity initiation is more probable to occur at ${\alpha}_2/{\gamma}$ interface rather than at ${\gamma}/{\gamma}$ interface.

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TiAl 터빈을 적용한 과급 직분식 전기점화 엔진의 과도운전 성능특성 (Characteristics of Transient Performance in a Turbocharged GDI Engine with TiAl Turbine)

  • 박찬수;정진영;배충식
    • 한국자동차공학회논문집
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    • 제23권3호
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    • pp.299-306
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    • 2015
  • Turbocharged gasoline direct injection engine is one of promising technologies in the automotive industry. However, reduction in turbo-lag under transient operation is one of important challenging points to improve drivability. Engine transient performance was investigated in a 4-cylinder 2.0 L turbo-gasoline direct injection (T-GDI) engine using Inconel and TiAl (Titanium Aluminide alloy) turbine wheel turbochargers. The TiAl turbocharger performed superior transient boost pressure and torque rises under various engine transient operation conditions. These were mainly due to lower turbine rotational inertia of TiAl turbocharger. The Maximum boost pressure and torque build up were founded in 1500 rpm and 2000 rpm, instant load change from 20% to 100% of pedal position.