• Macromolecular Research
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• 제13권3호
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• pp.187-193
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• 2005

The TEMPO-mediated living free-radical bulk and dispersion polymerization of styrene in the presence of camphorsulfonic acid (CSA) are investigated. In the absence of TEMPO and CSA in the bulk polymerization, a conversion of $93\%$ is achieved within 6 hr of polymerization. When only TEMPO is involved in this polymerization, the pseudo-living free-radical polymerization is well achieved, however, the polymerization rate becomes quite slow. This retardation of the polymerization rate is solved by the addition of a low concentration of CSA. In the TEMPO-mediated dispersion polymerization in the presence of CSA, similar trends in the conversion, kinetics, and PDI are observed as those observed in the case of bulk polymerization. When only TEMPO is used in the dispersion polymerization, the resulting particle size becomes quite broad, due to the prolonged polymerization time. However, when a 1.0 molar ratio of CSA to TEMPO is added to the TEMPO-mediated dispersion polymerization, fairly mono-disperse PS microspheres having an average size of 5.83 $\mu$m and a CV of 3.4$\%$ are successfully obtained, due to the narrow molecular weight distribution of the intermediate oligomers and shortening of the polymerization time. This result indicates that the addition of CSA to the TEMPO-mediated bulk and the use of dispersion polymerization not only shortens the polymerization time, but also greatly improves the uniformity of the microspheres.

• 한국안전학회지
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• 제30권1호
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• pp.14-20
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• 2015

A Large Eddy Simulation(LES) was performed for the prediction of unsteady dispersion behavior of hydrogen fluoride (HF). The HF leakage accident occurred at the Gumi fourth industrial complex was numerically investigated using the Fire Dynamics Simulator (FDS) based on the LES. The accident area was modeled three-dimensionally and time-varying boundary conditions for wind were adopted in the simulation for considering the realistic accident conditions. The Message Passing Interface (MPI) parallel computation technique was used to reduce the computational time. As a result, it was found that the present LES simulation could predict the unsteady dispersion features of HF near the accident area effectively. The dispersion behaviors of the leaked HF was much affected by the unsteady wind direction. The LES could predict the time variation of the HF concentration reasonably and give an useful information for the risk analysis while the prediction with the time-averaging concept of HF concentration had a limitation for the amount of HF concentration at specific location point. It was identified that the LES is very useful to predict the dispersion characteristics of hazardous chemicals.

• 약학회지
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• 제34권3호
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• pp.192-198
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• 1990

Three sugar glass dispersions of sulfamerazine were prepared using dextrose, galactose and sucrose as the carriers, with the ratio of the drug to the carrier was 1:9. The chemical stability of sulfamerazine in the glass dispersion system was studied using TLC. TLC revealed no additional spot and there was good correspondence with the Sulfamerazine itself. While time required to dissolve 50%($T_{50%}$) of sulfamerazine powder was 390 min that of dextrose glass dispersion system was 1.5 min. and galactose system was 4.0 min. in distilled water. 23) $T_{50%}$ of physical mixture with dextrose, galactose and sucrose were 26.4 min., 26.5 min., and 26.0 min. respectively in distilled water. $T_{50%}$ of control was 54 min. and those of all of the glass dispersion systems were within 1 min. in 0.1N HCl. The dissolution rates of sulfamerazine from sugar glass dispersion system in distilled water was greater than that in 0.1N HCl.

• 대한수학회보
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• 제54권4호
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• pp.1195-1219
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• 2017

In this paper, the limit behavior of solution for the $Schr{\ddot{o}}dinger$ equation with random dispersion and time-dependent nonlinear loss/gain: $idu+{\frac{1}{{\varepsilon}}}m({\frac{t}{{\varepsilon}^2}}){\partial}_{xx}udt+{\mid}u{\mid}^{2{\sigma}}udt+i{\varepsilon}a(t){\mid}u{\mid}^{2{\sigma}_0}udt=0$ is studied. Combining stochastic Strichartz-type estimates with $L^2$ norm estimates, we first derive the global existence for $L^2$ and $H^1$ solution of the stochastic $Schr{\ddot{o}}dinger$ equation with white noise dispersion and time-dependent loss/gain: $idu+{\Delta}u{\circ}d{\beta}+{\mid}u{\mid}^{2{\sigma}}udt+ia(t){\mid}u{\mid}^{2{\sigma}_0}udt=0$. Secondly, we prove rigorously the global diffusion-approximation limit of the solution for the former as ${\varepsilon}{\rightarrow}0$ in one-dimensional $L^2$ subcritical and critical cases.

• 대한전자공학회논문지TC
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• 제37권8호
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• pp.45-51
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• 2000

본 논문에서는 지수형, 삼각형 및 체비쉐브 테이퍼 전송선로에서 디지털 펄스가 전송될 때 분산과 반사에 의해 나타나는 펄스의 왜곡 특성을 시간영역에서 해석하여 그 전송특성을 비교하여 나타내었다. 그리고 테이퍼 선로에서 전압과 전류의 전달함수를 구하여 상승과 하강 시간을 갖는 비이상형 구형 펄스를 입력했을 때 왜곡 특성을 해석하고, 선로에서 나타나는 분산과 반사가 파형의 왜곡에 미치는 영향을 분석하였다. 주파수 분산에 의한 왜곡은 파형에 오버슈트와 기울림이 나타났고, 반사에 의한 왜곡은 꼬리 부분에 잔류 특성이 나타났다.

• 한국광학회지
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• 제12권6호
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• pp.479-484
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• 2001

광자 크리스탈의 광자 밴드갭이나 비정상적인 광 분산 현상 등의 특성을 분석하려면 광자 크리스탈 구조에 따른 밴드 구 조와 분산 곡선의 계산이 필요하다. 본 논문에서는 시간 영역에서의 계산 방법인 Finite-Difference Time-Domain방법과 주기적 경계 조건을 이용하여 밴드 구조와 분산 곡선을 계산하였으며, 몇 가지 간단한 2차원 크리스탈 구조에 대하여 그 계산 결과를 제시하였다. 또한 밴드갭 내부에 존재하고, 공간적으로 지역화된 디펙트 모드를 계산하였다.

• 한국수자원학회논문집
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• 제34권4호
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• pp.289-301
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• 2001

비보존성 오염물질의 종확산에 관한 단계분리 유한차분 모형을 낙동강에 적용하여, 1991년에 발생한 페놀누출 사고에 따른 종확산 모의계산을 수행하였다. Preissmann의 4점 음해법에 근거한 부정류 계산모형으로부터 산정된 계산결과를 종확산 모형의 입력자료로 사용하였다. 종확산계수의 산정을 위한 경험식 및 1차 반응의 감쇠계수에 따른 종확산 계산결과의 민감도를 분석하였다. 하류 지점에서의 첨두농도 발생 시각은 사용된 종확산계수 식에 따라 상당히 달라짐을 알 수 있었다. 또한 농도 분포형은 감쇠계수에 따라 변하지 않는 반면, 농도값은 감쇠계수에 상당히 좌우되는 것으로 나타났다. 최적화 기법을 사용하여 흐름 모형 및 종확산 모형을 보정하였으며, 낙동강에 위치한 주요 취수지점들에 대한 첨두농도 발생시각을 모의하여 제시하였다.

• 한국안전학회지
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• 제37권2호
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• pp.1-9
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• 2022

Most factories deal with toxic or flammable chemicals in their industrial processes. These hazardous substances pose a risk of leakage due to accidents, such as fire and explosion. In the event of chemical release, massive casualties and property damage can result; hence, quantitative risk prediction and assessment are necessary. Several methods are available for evaluating chemical dispersion in the atmosphere, and most analyses are considered neutral in dispersion models and under far-field wind condition. The foregoing assumption renders a model valid only after a considerable time has elapsed from the moment chemicals are released or dispersed from a source. Hence, an initial dispersion model is required to assess risk quantitatively and predict the extent of damage because the most dangerous locations are those near a leak source. In this study, the dispersion model for initial consequence analysis was developed with three-dimensional unsteady advective diffusion equation. In this expression, instantaneous leakage is assumed as a puff, and wind velocity is considered as a coordinate transform in the solution. To minimize the buoyant force, ethane is used as leaked fuel, and two different diffusion coefficients are introduced. The calculated concentration field with a molecular diffusion coefficient shows a moving circular iso-line in the horizontal plane. The maximum concentration decreases as time progresses and distance increases. In the case of using a coefficient for turbulent diffusion, the dispersion along the wind velocity direction is enhanced, and an elliptic iso-contour line is found. The result yielded by a widely used commercial program, ALOHA, was compared with the end point of the lower explosion limit. In the future, we plan to build a more accurate and general initial risk assessment model by considering the turbulence diffusion and buoyancy effect on dispersion.

• 한국자기학회지
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• 제5권5호
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• pp.383-386
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• 1995

A universal dispersion equation for magnetostatic waves(MSW) propagating in the film with arbitrary-multiple magnetic layers magnetized in an arbitrary direction was derived with a matching boundary condition method. The computing result curves of delay time were shown.

• 한국대기환경학회지
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• 제15권6호
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• pp.767-777
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• 1999

In the coastal region air flow changes due to the abrupt change of surface temperature between land and sea. So a numerical simulation for atmospheric flow fields must be considered the correct fields of sea surface temperature(SST). In this study, we used variables such as latent heat flux, sensible heat flux, short and long wave radiation of ocean and atmosphere which exchanged across the sea surface between atmosphere and ocean model. We found that this consideration simulated the more precise SST fields by comparing with those of the observated results. Simulated horizontal SST differences in season were 2.5~4$^{\circ}C$. Therefore we simulated the more precise atmospheric flow fields and the movement and dispersion of the pollutants with the Lagrangian particle dispersion model. In the daytime dispersion pattern of the pollutants emitted from ship sources moved toward inland, in the night time moved toward sea by land/sea breeze criculation. But air pollutants dispersion can be affected by inland topography, especially Yangsan and coastal area because of nocturnal wind speed decrease.