• 한국생물공학회:학술대회논문집
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• 2005.10a
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• pp.511-516
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• 2005

Sorbitan methacrylate was synthesized from sorbitan dehydrated from D-sorbitol using an immobilized lipase. To optimize the enzymatic synthesis of sorbitan methacrylate, response surface methodology was applied to determine the effects of five-level-four-factors and their reciprocal interactions on sorbitan methacrylate biosynthesis. A total of 30 individual experiments were performed, which were designed to study reaction temperature, reaction time, enzyme amount and substrate molar ratio. A statistical model predicted that the highest conversion yield of sorbitan methacrylate was 100%, at the following optimized reaction conditions: a reaction temperature of 43.06 $^{\circ}C$, a reaction time of 164.25 mins., an enzyme amount of 7.47%, and a substrate molar ratio of 3.98:1. Using these optimal factor values under experimental conditions in four independent replicates, the average conversion yield reached 98.7%${\pm}$1.2% and was well within the value predicted by the model.

• Proceedings of the KIPE Conference
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• 2008.06a
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• pp.382-384
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• 2008

Hold-up time is a special requirement for the front end DC/DC converter in a server power supply. It forces the converter with the variable switching frequency to operate in a wide switching frequency range, which makes the regulation difficult and reduces the power density. In this paper a novel frequency controlled half bridge converter with the hold-up time extension circuit is proposed. During the hold-up time, the auxiliary switches are turned on, thus the resonant inductance is reduced and the voltage conversion ratio is increased. Therefore, the output capacitor of the power factor correction (PFC) circuit can be decreased, and the converter can have high power density. The proposed converter is verified by experimental results from a prototype with 700W, 400V input, and 12V output.

• Polymer(Korea)
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• v.25 no.2
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• pp.168-176
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• 2001

The effect of novel N-crotyl-N,N-dimethyl-4-methylanilinium hexafluoroantimonate (CMH) curing agent as a thermal latent initiator on thermal behaviors, rheological properties, and thermal stability of diglycidylether of bisphenol A (DGEBA) epoxy cationic system was investigated. From DSC measurements of DGEBA/CMH system, it was shown that this system exhibits an excellent thermal latent characteristic at a given temperature. The conversion and conversion rate of DGEBA/CMH system increased with increasing the concentration of initiator, due to high activity of CMH. Rheological properties of the system were investigated under isothermal condition using a rheometer The gelation time was obtained from the analysis of storage modulus (G'), loss modulus (G"), and damping factor (tan $\delta$). As a result, the reduction of gelation time was affected by high curing temperature and concentration of CMH, resulting in high degree of network formation in cationic polymerization, due to difference of activity. The thermal stability of the cured epoxy resin was discussed in terms of the activation energy for decomposition and thermal factors determined from TGA measurements.ents.

• Proceedings of the KSRS Conference
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• 2007.10a
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• pp.410-413
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• 2007

Water vapor in the atmosphere is an influential factor of the hydrosphere cycle, which exchanges heat through phase change and is essential to precipitation. Because of its significance in altering weather, the estimation of water vapor amount and distribution is crucial to determine the precision of the weather forecasting and the understanding of regional/local climate. It is shown that it is reliable to measure precipitable water (PW) using long baseline (500-2000km) GPS observations. However, it becomes infeasible to derive absolute PW from GPS observations in Taiwan due to geometric limitation of relatively short-baseline network. In this study, a method of deriving Near-Real-Time PW from short baseline GPS observations is proposed. This method uses a reference station to derive a regression model for wet delay, and to interpolate the difference of wet delay among stations. Then, the precipitable water is obtained by using a conversion factor derived from radiosondes. The method has been tested by using the reference station located on Mt. Ho-Hwan with eleven stations around Taiwan. The result indicates that short baseline GPS observations can be used to precisely estimate the precipitable water in near-real-time.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.20 no.1
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• pp.34-40
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• 2006

This paper proposed power system for new DC 49[V] telecommunication using forward three-phase PWM rectifier power factor and efficiency for improvement of ripple voltage. Proposed power system for DC 48[V] telecommunication that consists of power conversion devices including switch, inductor and condenser were made between each line, in power inverter device of each switch control turn-on in period of continuity time control to get power factor '1' of sine wave current and on-off of switch lessens peak current that was happened and got conversion efficiency 92.1[%] composing in PWM rectifier of forward form instead of general PWM rectifier. Also, harmonic input regulation value(IEC61000-3-2 Class-As) satisfy input current and reduce ripple factor of output voltage in state that distortion of three-phase supply is overlapped each other.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.49 no.5
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• pp.345-351
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• 2000

To improve the current waveform of diode rectifiers, we propose a new operating principle of the voltage diode rectifiers. In the conventional voltage rectifier circuit, relatively large capacitors are used to boost the output voltage, while the proposed circuit uses ones and a small reactor not boost the output voltage but improve the input current waveform. A circuit design method is shown and confirmed simulation. It explained that compared conventional PWM(Pulse-width modulated)inverter with HPWM(Half Pulse-width modulated)inverter. Proposed HPWM inverter eliminated dead-time by lowering switching loss and holding over-shooting. Output voltage and current of this paper were applied for real air-conditioner.

• BMB Reports
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• v.40 no.5
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• pp.832-838
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• 2007

A novel inhibitory protein against blood coagulation factor Va (FVa) was purified from muscle protein of granulated ark (Tegillarca granosa, order Arcoida, marine bivalvia) by consecutive FPLC method using anion exchange and gel permeation chromatography. In the results of ESI-QTOF tandem mass analysis and database research, it was revealed that the purified T. granosa anticoagulant protein (TGAP) has 7.7 kDa of molecular mass and its partial sequence, HTHLQRAPHPNALGYHGK, has a high identity (64%) with serine/threonine kinase derived from Rhodopirellula baltica (order Planctomycetales, marine bacteria). TGAP could potently prolong thrombin time (TT), corresponding to inhibition of thrombin (FIIa) formation. Specific factor inhibitory assay showed that TGAP inhibits FVa among the major components of prothrombinase complex. In vitro assay for direct-binding affinity using surface plasmon resonance (SPR) spectrometer indicated that TGAP could be directly bound with FVa. In addition, the binding affinity of FVa to FII was decreased by addition of TGAP in dose-dependant manner ($IC_{50}$ value = 77.9 nM). These results illustrated that TGAP might interact with a heavy chain of FVa ($FVa_H$) bound to FII in prothrombin complex. The present study elucidated that non-cytotoxic T. granosa anticoagulant protein (TGAP) bound to FVa can prolong blood coagulation time by inhibiting conversion of FII to FIIa in blood coagulation cascade. In addition, TGAP did not significantly (P < 0.05) show fibrinolytic activity and cytotoxicity on venous endothelial cell line (ECV 304).

• Bulletin of the Korean Chemical Society
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• v.32 no.8
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• pp.2743-2750
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• 2011

Lanthanide(III)-cored complex as a wavelength conversion material has been successfully designed and synthesized for highly efficient dye-sensitized solar cells, for the first time, since light with a short wavelength has not been effectively used for generating electric power owing to the limited absorption of these DSSCs in the UV region. A black dye (BD) was chosen and used as a sensitizer, because BD has a relatively weak light absorption at shorter wavelengths. The overall conversion efficiency of the BD/WCM device was remarkably increased, even with the relatively small amount of WCM added to the device. The enhancement in $V_{oc}$ by WCM, like DCA, could be correlated with the suppression of electron recombination between the injected electrons and $I_3{^-}$ ions. Furthermore, the short-circuit current density was significantly increased by WCM with a strong UV light-harvesting effect. The energy transfer from the Eu(III)-cored complex to the $TiO_2$ film occurred via the dye, so the number of electrons injected into the $TiO_2$ surface increased, i.e., the short-circuit current density was increased. As a result, BD/WCM-sensitized solar cells exhibit superior device performance with the enhanced conversion efficiency by a factor of 1.22 under AM 1.5 sunlight: The photovoltaic performance of the BD/WCM-based DSSC exhibited remarkably high values, $J_{sc}$ of 17.72 mA/$cm^2$, $V_{oc}$ of 720 mV, and a conversion efficiency of 9.28% at 100 mW $cm^{-2}$, compared to a standard DSSC with $J_{sc}$ of 15.53 mA/$cm^2$, $V_{oc}$ of 689 mV, and a conversion efficiency of 7.58% at 100 mW $cm^{-2}$. Therefore, the Eu(III)-cored complex is a promising candidate as a new wavelength conversion coadsorbent for highly efficient dye-sensitized solar cells to improve UV light harvesting through energy transfer processes. The abstract should be a single paragraph which summaries the content of the article.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.24 no.2
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• pp.113-121
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• 2014

Objectives: This study is intended to seek credible and efficient measurements on airborne asbestos concentrations that allow immediate action by establishing complementary data through comparative analysis with existing PCM and KF-100 method real-time monitoring equipment in working areas in Seoul where asbestos-containing buildings are being demolished, including living environment surroundings. Materials: We measured airborne asbestos concentrations using PCM and KF-100 at research institutes, monitoring networks, subway stations and demolition sites of asbestos-containing buildings. Through this measurement data and KF-100 performance testing, we drew a conversion factor and applied it via KF-100. Finally we verified the relationship between PCM and KF-100 with statistical methods. Results: The airborne asbestos concentrations by PCM for the objects of study were less than the detection limit(7 fiber/$mm^2$) in three (20%) out of 15 samples. The highest concentration was 0.009 f/cc. The airborne asbestos concentrations by PCM in laboratories, monitoring networks, subway stations and demolition sites of asbestos-containing buildings were respectively $0.002{\pm}0.000$ f/cc, $0.004{\pm}0.001$ f/cc, $0.009{\pm}0.001$ f/cc, and $0.002{\pm}0.000$ f/cc. As a result of KF-100 performance testson rooftops, the conversion factor was 0.1958. Applying the conversion factor to KF-100 for laboratories, the airborne asbestos concentrations ratio of the two ways was nearly 1:1.5($R^2$=0.8852). Also,the airborne asbestos concentration ratio of the two ways was nearly 1:1($R^2$=0.9071) for monitoring networks, subway stations, and demolition sites of asbestos-containing buildings. As a result of independent sample t-tests, there was no distinction between airborne asbestos concentrations monitored in the two ways. Conclusions: In working areas where asbestos-containing buildings are being demolished, including living environment surroundings, quickly and accurately monitoring airborne asbestos scattered in the air around the working area is highly important. For this, we believea mutual interface of existing PCM and a real-time monitoring equipment method is possible.

• Proceedings of the KIEE Conference
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• 1996.07a
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• pp.518-520
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• 1996

High frequency switching converters are becoming more popular because of several benefits which are essential in power conversion system. This paper introduces a high speed digital controller using TMS320C40 DSP chip which can be used for high frequency switching converters and demonstrates its performance by operating three-phase PWM AC/DC converter with unity power factor at 20kHz sampling frequency. TMS320C40 DSP chip operates with 40-ns instruction cycle times and is capable of 275 MOPS. The running time of real time control loop at the three-phase PWM AC/DC converter is $44.6{\mu}sec$.