• Title/Summary/Keyword: TiC Addition

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Machinable SiC Ceramics with Addition of Al2TiO5 (Al2TiO5가 첨가된 쾌삭(快削) SiC 세라믹스)

  • Kim, Il Soo;Park, Jeong Hyun;Lee, Won Jae;Lee, Kang Ho
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.372-377
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    • 2013
  • Machinable SiC ceramics are prepared with the addition of $Al_2TiO_5$. Ready-to-press SiC and $Al_2TiO_5$ powders are mixed and pressureless sintered at $1750^{\circ}C$ and $1850^{\circ}C$ for 1 h. The weight ratios of the SiC and $Al_2TiO_5$ powders are 100 : 0, 100 : 10, and 100 : 20. After sintering, only SiC peaks are detected in the X-ray diffraction analyses. The density, strength, and grain size of the SiC increase with increases in the $Al_2TiO_5$ content and sintering temperature. The $Al_2TiO_5$-doped specimens are easy to micro-hole machine. Based on the density and strength data, the ceramics sintered at $1850^{\circ}C$ can be used as machinable ceramics.

Effects of Ti Addition and Homogenizing Heat Treatment on the Mechanical Properties of Centrifugal Cast Cu-Zn-Al Alloy (원심주조한 Cu-Zn-Al계 합금의 기계적 성질에 미치는 Ti 첨가와 균질화 처리의 영향)

  • Kwon, Young-Hwan;Jea, Chang-Wooing;Yoon, Jae-Hong;Kang, Chang-Yong;Kim, Chang-Gyu
    • Journal of Korea Foundry Society
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    • v.17 no.5
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    • pp.450-457
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    • 1997
  • Effects of Ti addition and homogenizing heat treatment on the mechanical properties in Cu-Zn-Al alloy (high strength yellow brass) were investigated. Grain refinement was successfully achieved by Ti addition. The microstructure, which was composed of island or fine feather-like branched Ti compounds was changed to feather-like eutectic microstructure as the content of Ti increased. The highest hardness value was obtained for 0.5 wt.% Ti specimen and the second was Ti non-added specimen in as-cast condition. The highest tensile strength was obtained for 0.5 wt.% Ti specimen. Because of the presence of cast defects and worse castability, tensile strength decreased as the content of Ti increased. Elongation increased with increasing homogenizing time and temperature; remarkable increase was obtained for $400^{\circ}C$ homogenizing temperature in the 0.5 wt.% Ti specimen. For $500^{\circ}C$ and $600^{\circ}C$ homhgenizing, temperature, high elongation was obtained in 2 and 4 wt.% Ti specimen.

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Crystallization of 90wt% Cordierite-10wt% Enstatite Melt by $TiO_2$ Addition (90wt% Cordierite-10wt% Enstatite 총체의 $TiO_2$ 첨가에 의한 결정화)

  • Rhee, Jhun;Han, Duck-Huyn;Jo, Dong-Soo;Jun, Jong-Pil
    • Journal of the Korean Ceramic Society
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    • v.23 no.5
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    • pp.9-16
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    • 1986
  • The effect of $TiO_2$ addition to the 90wt% Cordierite-10wt% Enstatite base glass was investi-gated to understand the crystallization behavior of the glass. Glasses with addition of $TiO_2$ less than 7, 5wt% had a tendency of surface crystallization and were cracked when heat treated and in this case the crystalline phase formed was indialite. glasses with addition of $TiO_2$ more than 10wt% to 15wt% were crystallized in bulk when heat treated and were suitable for glass-ceramics. The highest microhardness 1640kg/$mm^2$ was obtained when the glass of 12.5wt% $TiO_2$ addition was heat treated at 762$^{\circ}C$ for 60 minutes for nucleation and at 1135$^{\circ}C$ for 20 minutes for crystal growth and in general higher microhardness was obtained when crystalline phase of magnesium aluminum titanate and $\mu$-cordierite were developed. Avrami equation for crystal growth kinetics was applicable in glasses of less than 7.5 wt% $TiO_2$ addition and in case of glasses of more than 10wt% $TiO_2$ addition it was not applicable because of too fast crystal growth.

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A study on the hardening characterstics of the TiC layer formed by the reactive deposition technique (반응석출법에 의해 피복된 TiC의 경화거동에 관한 연구)

  • Nam, K.S.;Byon, E.S.;Lee, G.H.;Kim, D.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.4
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    • pp.288-297
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    • 1994
  • In this study, lattice parameter, binding energy and microstructures of TiC layer according to the addition of Fe, Cr were investigated in the reactive deposition coating. From the results, the lattice parameters of the TiC layers by using ferro-titanium as a precursor were 4.329~4.339A but the lattice parameters of the TiC layers formed by ferro-titanium and ferro-chromium decreased to 4.316~4.330A. The hardness of the former's was HV(100g) 3,000~3,400kg/mm and the hardness of the latter's was HV (100g) 3,800~3,900. But, regardless of Cr and Fe, the binding energy of TiC layers were 454.75 eV for $Ti2p_{3/2}$ and were 281.85 eV for Cls. Meanwhile, the TiC layers were densified by addition of Fe, Cr and internal defects were reduced Therefore. it can be concluded that the remarkable hardness increment was obtained by the improvement of microstructures of TiC rather than the increase of bond strength or Peierls stress.

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Friction and Wear of Pressureless Sintered Ti(C,N)-WC Ceramics

  • Park, Dong-Soo;Yun, Shin-Sang;Han, Byoung-Dong;Kim, Hai-Doo
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.211-212
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    • 2002
  • Friction and wear of pressureless sintered Ti(C,N)-WC ceramics were studied using a ball-on-reciprocating flat apparatus in open air. The silicon nitride ball and the cemented carbide (WC-Co) ball were used against the Ti(C,N)-WC plate samples. The friction coefficients of the Ti(C,N)-WC samples against the silicon nitride ball and the cemented carbide ball were about 0.57 and 0.3, respectively. The wear coefficient of the sample without WC addition was 5 times as large as that of the sample with 10 mole % WC addition when tested against the silicon nitride ball under 98 N. The higher wear coefficient of Ti(C,N)-0WC was explained in part by larger grain size. Wear occurred mainly by grain dislodgment after intergranular cracking mainly caused by the accumulated stress within the grains.

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Effects of Processing Parameters on the Fabrication of in-situ Al/TiC Composites by Thermally Activated Combustion Reaction Process in an Aluminium Melt using Al-TiO2-C Powder Mixtures (알루미늄 용탕에서 Al-TiO2-C의 연소합성반응에 의한 in-situ Al/TiC 복합재료의 제조에 미치는 공정변수의 영향)

  • Kim, Hwa-Jung;Lee, Jung-Moo;Cho, Young-Hee;Kim, Jong-Jin;Kim, Su-Hyeon;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.50 no.9
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    • pp.677-684
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    • 2012
  • A feasible way to fabricate in-situ Al/TiC composites was investigated. An elemental mixture of $Al-TiO_2-C$ pellet was directly added into an Al melt at $800-920^{\circ}C$ to form TiC by self-combustion reaction. The addition of CuO initiates the self-combustion reaction to form TiC in $1-2{\mu}m$ at the melt temperature above $850^{\circ}C$. Besides the CuO addition, a diluent element of excess Al plays a significant role in the TiC formation by forming a precursor phase, $Al_3Ti$. Processing parameters such as CuO content, the amount of excess Al and the melt temperature, have affected the combustion reaction and formation of TiC, and their influences on the microstructures of in-situ Al/TiC composites are examined.

The effects of brazing conditions on the bond strength of the SiC/SiC and SiC/mild steel joints brazed by Ag-Ti based alloys (Ag-Ti계 합금을 사용한 SiC/SiC 및 SiC/연강 브레이징에서 브레이징 조건이 접합강도에 미치는 영향의 연구)

  • 이형근;이재영
    • Journal of Welding and Joining
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    • v.15 no.5
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    • pp.104-114
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    • 1997
  • The microstructure and bond strength were investigated on the SiC/SiC and SiC/mild steel joints brazed by Ag-5at%Ti alloy. Ag-5at%Ti-2at%Fe and -5at%Fe brazing alloys were also used to see the effects of Fe addition on the bond strength of SiC/SiC brazed joints. Brazing temperature and brazing gap were selected and examined as brazing variables. The microstructure of SiC/SiC brazed joints was affected by Fe addition to the Ag-5at%Ti alloy, but the bond strength was not. Increasing brazing temperature also changed the microstructure of $Ti_5Si_3$ reaction layer and brazing alloy matrix of the SiC/SiC and SiC/mild steel joints, but not the bond strength. Brazing gap had a great effects on the bond strength. Decreasing brazing gap from 0.2 mm to 0.1 mm in SiC/SiC brazing increased the bond strength from 187 MPa to 263 MPa and, in SiC/mild steel brazing, from 189 MPa to 212 MPa. It was concluded that the most important parameter on the bond strength in SiC/SiC and SiC/mild steel brazing was the relative ratio between brazing gap and specimen size.

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Behaviors of Grain Growth in Carbide Added TiC Matrix Cermets (탄화물첨가 TiC기지 서멧의 입성장 거동)

  • Shin, Soon-GI;Lee, Jun-Hee;Lee, Hwa-Sang
    • Korean Journal of Materials Research
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    • v.12 no.10
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    • pp.825-830
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    • 2002
  • The growth rate of solid grains in TiC-XC-2vol% and TiC-XC-30vo1% Ni cermets, where X=Zr, W or Mo, was fitted to an equation of the form $d^3$-$do^3$=Kt. The grain growth behavior during liquid phase sintering at 1673K decreased markedly with addition of $Mo_2$C or WC and increased with addition of ZrC. The contiguity ratio was greater in the alloys with smaller growth rate constant and decreased with increasing Ni content in the $TiC-Mo_2$C-Ni cermet. The grain growth mechanism could be explained by the effect of contiguous grain boundaries in restricting the overall grain growth.