• Title/Summary/Keyword: Through Pore

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Synthesis of Stepped Carbon Nanotubes in Anodic Aluminum Oxide Templates (알루미나 형틀을 이용한 서로 다른 직경을 갖는 모양을 가진 탄소나노튜브의 합성)

  • Im Wan-soon;Cho You-suk;Choi Gu seok;Kim Dojin
    • Korean Journal of Materials Research
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    • v.14 no.9
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    • pp.664-669
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    • 2004
  • Anodic aluminum oxide (AAO) with pores of various diameter, density, and thickness values was obtained through control of the anodization parameters including voltage, temperature, pore widening time, anodization time, etc. The pore diameter was controlled by a pore widening in an etchant, and alumina templates having stepped nano-channels were fabricated by repetition of anodization and pore widening processes. Stepped carbon nanotubes (CNTs) were then grown on the stepped AAO templates by pyrolysis of acetylene without using the catalyst. High-resolution transmission electron microscopy images revealed that CNTs have a multi-wall structure made of graphite flakes of several nm sizes. The current-voltage characteristic of the sloped and linear CNTs were also examined.

Porosity of Polymer-Modified Mortars Using Methylmethacrylate-Butyl Acrylate Latexes with Various Monomer Ratios (MMA/BA 합성 라텍스 혼입 폴리머 시멘트 모르타르의 세공성상)

  • 형원길;송해룡;김완기;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.87-92
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    • 2002
  • At present, the polymer-modified mortars are used as high-performance as well as multi-functional materials in the construction industry. The purpose of this study is to synthesize polymer to modify in cement mortars and make test samples to understand pore size distribution. This paper deals with the effect of monomer ratio on the typical properties of polymer-modified mortars using Methylmethacrylate-Butyl Acrylate(MMA/BA) latexes synthesized through emulsion polymerization. From the results, we knew that the pore volume of polymer-modified mortars using Methylmethacrylate-Butyl Acrylate latexes at bound MMA contents of 70 and 60 percent is 7.5-75cm$^3$/g and the fine pore volume is increased with an increase in the polymer-cement ratio. The total pore volume of polymer-modified mortars using MMA/BA latexes is linearly reduced with an increase in the bound MMA content and increased in the polymer-cement ratio.

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Syunthesis of Silica Aerogel at Ambient Pressure and Characterization (I) (실리카에어로겔의 상압합성 및 특성연구(I))

  • 강신규;최세영
    • Journal of the Korean Ceramic Society
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    • v.33 no.12
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    • pp.1394-1402
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    • 1996
  • The Silica gel with the density of 0.2g/cm3 and porosity of 90% was synthesized. The silica wet gel was dried and heat-treated under the ambient pressure after modification of the wet gel surface by TMCS. Specific surface area total pore volume and mean pore radius of dried gel were all increased with increasing heat treatment temperature and confirmed about 1400m2/g, 4.5cc/g and 8 nm respectively after heat treatment above 25$0^{\circ}C$. But the pore size distribution of dried gel was in the range of 1-100nm and was almost indepen-dent of temperature. As the result of external shape pore characteristics and microstructure of gel using SEM similar properties were observed between the silica gel synthesized in this study and the silica aerogel through the super critical drying.

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An Experimental Study on the Performance Evaluation of Lightweight Foamed Concrete According to Size and Replacing Ratio of Artificial Lightweight Aggregate (인공경량골재 크기 및 혼입량에 따른 경량기포콘크리트의 물리적 성능 평가에 관한 실험적 연구)

  • Jeong, Seong-Min;Yun, Chang-Yeon;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.162-163
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    • 2017
  • This study investigated the properties of lightweight foamed concrete by using synthetic foaming agent and artificial lightweight aggregate. The effects of artificial lightweight sizes on the compressive strength, density and pore structure of the concrete were investigated. The samples were assessed by MIP analysis and simultaneous SEM was used to study their pore distribution. This study showed the improvement of important properties of lightweight foamed concrete. Lower pore distribution and correspondingly higher compressive strength values were reached. This is for the purpose of providing basic data for the use of lightweight foamed concrete through improvement on the problem such as unstability, falling in fluidity and the strength of existed foaming agent.

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Effect of Carbon Addition and Sintering Temperature on Densification and Microstructural Evolution of Sinter-Hardening Alloys Steels

  • Verma, N.;Anand, S.;Upadhyaya, A.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.557-558
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    • 2006
  • In all conventional sintered PM products, the pores present are of two types, primary and secondary. Primary pores forming during compaction and latter during sintering, due to penetration of formed liquid through the matrix grain boundary. Effect of carbon addition on diffusion of Cu in SH737-2Cu system was investigated. After compaction and transient liquid phase sintering at $1120^{\circ}C$ and $1180^{\circ}C$, samples were characterized for densification, showing rise in sintering density and reduction in swelling on carbon addition. Quantitative microstructural characterization (shape factor and pore size) revealed bimodal distribution for 0% carbon, more rounded pores for 0.9% carbon and higher sintering temperature, and pore coarsening at higher sintering temperature.

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Multi-Region Model of Solute Transport in Soil for the Preferential Flow (Preferential 흐름에 의한 토양내의 다영역 용질이동 모델)

  • 안병기
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.42 no.2
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    • pp.71-77
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    • 2000
  • A multi-region model for solute transport through saturated soils has been developed to describe preferential flow. The model consists of numerous discrete pore groups, which are characterized by a discrete dispersion coefficient, flow velocity, and porosity . The hydraulic properties for each pore group are derived from a soil's hydraluic conductivity and soil water characteristic functions . Flow in pore group is described by the classical advection-disersion equation (ADE). An implict finite difference scheme was applied to the governing equation that results in a block-tridiagonal system of equations that is very efficient and allows the soil to be divided into any number of pore groups. The numerical technique is derived from methods used to solve coupled equations in fluid dynamics problems and can also be applied to the transport of interacting solutes. The results of the model are compared to the experimental data from published papers. This paper contributes on the characteristics of the method when applied to the parallel porosity model to describe preferential flow of solutes in soil.

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Effects of Heat Treatment on Surface Properties of Aluminum 6061 Alloy After Anodization (알루미늄 6061 합금 양극산화 후 열처리에 따른 표면 특성 관찰)

  • Seungmin, Lee;Chanyoung, Jeong
    • Corrosion Science and Technology
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    • v.21 no.6
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    • pp.495-502
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    • 2022
  • Anodization is a representative electrochemical surface treatment method that can improve both heat resistance and corrosion resistance by forming an anodization film on the surface of the aluminum. However, these properties can be changed after an additional heat treatment process. In this study, Al 6061 was subjected to an anodization process at 60 V for 1 hour, 5 hours, or 9 hours. An additional heat treatment process was performed at 500 ℃ for 30 minutes. Field emission scanning electron microscopy (FE-SEM) analysis revealed that the thickness of the anodized film was increased in proportion to the anodization time. Both pore size and pore diameter of the anodized film was also increased after anodization. After an additional heat treatment process, there were no significant changes in the thickness, pore size, or pore diameter of the anodized film. Heat resistance was confirmed through thermal analysis and chemical resistance was evaluated with a potentiodynamic polarization test.

Effect of Porous Membrane on Culture Properties of Blood-Brain Barrier Endothelial Cell (다공성막이 혈액뇌관문 내피세포의 배양에 끼치는 영향)

  • Lee, Keum-Jeong;Cho, Hye-Jin;Choi, Hyung-Taek;Na, O-Soon;Kim, Kyung-Yong
    • Applied Microscopy
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    • v.33 no.4
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    • pp.261-266
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    • 2003
  • The growth patterns of primary culture of bovine brain microvessel endothelial cells (BBMECs) were studied using electron microscopy when grown on $3.0{\mu}m$ and $0.4{\mu}m$ pore Transwell. The capillary fragments and isolated endothelial cells grew on collagen coated culture plate and Transwell membrane. The BBMECs grew only on the upper surface of membrane of $0.4{\mu}m$. But BBMECs on $3.0{\mu}m$ pore membrane migrated through the pore and grew on the opposite side of the membrane. In summary, BBMECs isolated by enzyme digestion could migrate through $3.0{\mu}m$ pore membrane but not through $0.4{\mu}m$ pore membrane. So $0.4{\mu}m$ pore membrane instead of $3{\mu}m$ pore membrane should be used for drug transport experiment or transendothelial electrical resistance measurement.

The Pore-filling Effect of Bulk Graphite According to Viscosity of Impregnant (함침재의 점도에 따른 벌크흑연의 기공 채움 효과)

  • Lee, Sang-Min;Lee, Sang-Hye;Roh, Jae-Seung
    • Korean Journal of Materials Research
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    • v.31 no.2
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    • pp.101-107
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    • 2021
  • Pores produced by carbonization in bulk graphite process degrade the mechanical and electrical properties of bulk graphite. Therefore, the pores of bulk graphite must be reduced and an impregnation process needs to be performed for this reason. In this study, bulk graphite is impregnated by varying the viscosity of the impregnant. The pore volume and pore size distribution, according to the viscosity of the impregnant, are analyzed using a porosimeter. The total pore volume of bulk graphite is analyzed from the cumulative amount of mercury penetrated. The volume for a specific pore size is interpreted as the amount of mercury penetrating into that pore size. This decreases the cumulative amount of mercury penetrating into the recarbonized bulk graphite after impregnation because the viscosity of the impregnant is lower. The cumulative amount of mercury penetrating into bulk graphite before impregnation and after three times of impregnation with 5.1cP are 0.144 mL/g and 0.125 mL/gm, respectively. Therefore, it is confirmed that the impregnant filled the pores of the bulk graphite well. In this study, the impregnant with 5.1 cP, which is the lowest viscosity, shows the best effect for reducing the total pore volume. In addition, it is confirmed by Raman analysis that the impregnant is filled inside the pores. It is confirmed that phenolic resin, the impregnant, exists inside the pores through micro-Raman analysis from the inside of the pore to the outside.

Behavior of Cadmium, Zinc, and Copper in Soils -II. Effect of Organic Matter Treatment on Mobility of Cadmium, Zinc, and Copper in Soils- (토양내(土壤內) 카드뮴 아연(亞鉛) 및 구리의 행동(行動)에 관한 연구(硏究) -II. 토양내(土壤內) 카드뮴 아연(亞鉛) 및 구리의 이동(移動)에 미치는 유기물처리(有機物處理)의 영향(影響)-)

  • Yoo, Sun-Ho;Hyun, Hae-Nam
    • Applied Biological Chemistry
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    • v.28 no.2
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    • pp.76-81
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    • 1985
  • Miscible displacement techniques were used to investigate the influence of the organic matter treatment on the mobility of Cd, Zn, and Cu through soil columns. The heavy metals moved most readily through the Bonryang soil (Typic Udifluvents) of relatively low in CEC, pH, and organic matter content. Most parts of Cd and Zn eluted within 7 pore volumes, but Cu eluted between 5 and 15 pore volumes. Although the Gangseo soil (Aquatic Eutrochrepts) had lower in CEC and organic matter content than the Gyorae soil (Typic Distrandepts), the heavy metals moved faster through the Gyorae soil than through the Gangseo soil. Cu eluted more slowly and in smaller quantities than Cd and Zn from the Bonryang soil, but did not eluted from the Gangseo and the Gyorae soils at all during the experimental period. The motility of the heavy metals from the Bonryang and the Gangseo soils was in the order of Cd>Zn>Cu, but that of the Gyorae soil was in the order of Zn>Cd>Cu. Cd and Zn eluted after 5 and 20 pore volumes respectively, from the Bonryang soil treated with 3% compost but Cu did not elute even after 30 pore volumes were collected. By 7% compost treatment only small amountssof Cd eluted after 20 pore volumes. The liming of the Bonryang soil retarded the mobility of Cd, Zn, and Cu. Humic acid treatment did not reduce the motility of the Cd and Zn to the extent observed in the Bonryang soil with compost, but reduced a little motility of Cu.

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