• 전기화학회지
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• 제9권1호
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• pp.19-28
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• 2006

The phase-shift method for determining the Langmuir, Frumkin, and Temkin adsorption isotherms ($\theta_H\;vs.\;E$) of H for the cathodic $H_2$ evolution reaction (HER) at a Pt/0.1 M KOH solution interface has been proposed and verified using cyclic voltammetric, differential pulse voltammetric, and electrochemical impedance techniques. At the Pt/0.1 M KOH solution interface, the Langmuir and Temkin adsorption isotherms ($\theta_H\;vs.\;E$), the equilibrium constants ($K_H=2.9X10^{-4}mol^{-1}$ for the Langmuir and $K_H=2.9X10^{-3}\exp(-4.6\theta_H)mol^{-1}$ for the Temkin adsorption isotherm), the interaction parameters (g=0 far the Langmuir and g=4.6 for the Temkin adsorption isotherm), the rate of change of the standard free energy of $\theta_H\;with\;\theta_H$ (r=11.4 kJ $mol^{-1}$ for g=4.6), and the standard free energies (${\Delta}G_{ads}^{\circ}=20.2kJ\;mol^{-1}$ for $k_H=2.9\times10^{-4}mol^{-1}$, i.e., the Langmuir adsorption isotherm, and $16.7<{\Delta}G_\theta^{\circ}<23.6kJ\;mol^{-1}$ for $K_H=2.9\times10^{-3}\exp(-4.6\theta_H)mol^{-1}$ and $0.2<\theta_H<0.8$, i.e., the Temkin adsorption isotherm) of H for the cathodic HER are determined using the phase-shift method. At intermediate values of $\theta_H$, i.e., $0.2<\theta_H<0.8$, the Temkin adsorption isotherm ($\theta_H\;vs.\;E$) corresponding to the Langmuir adsorption isotherm ($\theta_H\;vs.\;E$), and vice versa, is readily determined using the constant conversion factors. The phase-shift method and constant conversion factors are useful and effective for determining the Langmuir, Frumkin, and Temkin adsorption isotherms of intermediates for sequential reactions and related electrode kinetic and thermodynamic data at electrode catalyst interfaces.

• 한국지반공학회논문집
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• 제28권4호
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• pp.55-65
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• 2012

본 연구는 지반조건에 따른 효과적인 마이크로 파일의 설치방법을 제안하기 위해 실트 또는 모래지반에서 모형시험을 수행하였다. 시험결과, 관입 전단파괴가 발생한 실트지반은 압축변위에 저항하도록 마이크로 파일을 엇갈리게 설치(${\theta}$ < $0^{\circ}$)하는 것이 효과적이며, 전면 또는 국부전단파괴가 발생한 모래인 경우 횡 방향 변위에 저항하도록 마이크로 파일을 경사지게 설치(${\theta}$ > $0^{\circ}$ 또는 ${\theta}$ < $0^{\circ}$) 하는 것이 효과적인 것으로 나타났다.

• Communications for Statistical Applications and Methods
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• 제5권3호
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• pp.847-853
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• 1998

Suppose we want to compare following non-hierarchical log-linear models, $H_0:f(x, heta inTheta_a)$ vs H_1:g(x, heta inTheta_eta); for; Theta_a,;Theta_etasubsetTheta;such;that;Theta_$\alpha$/ Theta_eta$. The goodness of fit test using the likelihood ratio test statistic for comparing these models could not be acceptable. By using the polyhedrons plots of Choi and Hong (1995), we propose a method to decide a better model between two non-hierarchical log-linear models $f(x: heta inTheta_a) and g(x: heta inTheta_eta)$.

• Journal of the Korean Statistical Society
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• 제34권2호
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• pp.85-98
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• 2005

A Bayesian analysis for the product of different powers of k independent Poisson rates, written ${\theta}$, is developed. This is done by considering a prior for ${\theta}$ that satisfies the differential equation due to Tibshirani and induces a proper posterior distribution. The Gibbs sampling procedure utilizing the rejection method is suggested for the posterior inference of ${\theta}$. The procedure is straightforward to specify distributionally and to implement computationally, with output readily adapted for required inference summaries. A salient feature of the procedure is that it provides a unified method for inferencing ${\theta}$ with any type of powers, and hence it solves all the existing problems (in inferencing ${\theta}$) simultaneously in a completely satisfactory way, at least within the Bayesian framework. In two examples, practical applications of the procedure is described.

• 정보보호학회논문지
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• 제12권5호
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• pp.3-14
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• 2002

Rijndael 유사 구조는 SPN 구조의 특수한 형태이다 Rijndael 유사 구조의 확산 단계는 두 가지 종류의 확산 단계의 결합으로 구성되는데, 그중 하나는 바이트 치환 $\pi$이고, 다른 하나는 확산 단계 $\theta$＝ ($\theta_1, \theta_2, \theta_3, \theta_4$)로서, 각 $\theta_i$는 라운드 입력의 4개의 행 각각에 적용된다. 블록 암호 Rijndael은 Rijndael 유사 구조의 하나의 예가 된다. 본 논문에서는 Rijndael 유사 구조의 최대 차분 확률과 최대 선형 hull 확률의 상한을 구하는 알고리즘을 제안한다.

• Communications for Statistical Applications and Methods
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• 제7권2호
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• pp.533-540
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• 2000

The problem of information related to I poission experiments, each having a distinct failure rate $\theta$i I=1,2,…,I, is considered. Instead of using a standard exchangeable prior for $\theta$=($\theta$1,$\theta$2,…,$\theta$I), we consider a partition of the experiments and take the $\theta$i's belonging to the same partition subgroup to be exchangeable and the $\theta$i's belonging to distinct subgroups to be independent. And we perform Gibbs sampling approach for Bayesian inference on $\theta$ conditional on a partition. Numerical study using real data is provided.

• 대한의용생체공학회:의공학회지
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• 제17권4호
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• pp.469-478
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• 1996

In the conventional digital ultrasound scanner, the reflected signal is sampled either in polar coordinates of R-$\theta$ method, or in Cartesian coordinates of uniform ladder algorithm (ULA). The R-$\theta$ scan method necessitates a coordinate transform process which makes hardware complex in comparison with ULA scan mrthoA In spite of this complexity, R-$\theta$ method has a good resolution in ultrasonographic (US) image, since scan direction of the US imaging is a radial direction. In this paper, a new digital scan converter is proposed, which is named the radius uniform ladder algorithm (RULA). The RULA has the rome scan direction as the US scanning in the radial direction and as the display space in the $\theta$ direction. In tllis new approach, sampled points we uniformly distributed in each horizontal line i.n well as in each radial ray so that the data are displayed in the Cartesian coordinates by the 1-D interpolation process. The propped algorithm has an uniform resolution in the periphery and the center field in comparison with equi-angle ULA and equi-interval ULA. To extend the scan angle, concentric square raster sampling (CSRS) is adopted with reduction of discontinuities on the junctions between horizontal scan and vertical scan. The discontinuities are reduced by using the hmction filtering along the $\theta$ direction.

• 전기화학회지
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• 제15권1호
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• pp.54-66
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• 2012

The phase-shift method and correlation constants, which are unique electrochemical impedance spectroscopy techniques for studying the linear relationship between the phase shift ($90^{\circ}{\geq}-{\varphi}{\geq}0^{\circ}$) vs. potential (E) behavior for the optimum intermediate frequency ($f_o$) and the fractional surface coverage ($0{\leq}{\theta}{\leq}1$) vs. E behavior, are proposed and verified to determine the Frumkin, Langmuir, and Temkin adsorption isotherms and the related electrode kinetic and thermodynamic parameters. At Ni/0.5 M $H_2SO_4$ and 0.1M LiOH aqueous solution interfaces, the Frumkin and Temkin adsorption isotherms (${\theta}$ vs. E) of H for the cathodic hydrogen ($H_2$) evolution, interaction parameters (g), equilibrium constants (K), standard Gibbs energies (${\Delta}G^0_{\theta}$) of H adsorption, and rates of change (r) of ${\Delta}G^0_{\theta}$ with ${\theta}$ have been determined using the phase-shift method and correlation constants. A lateral repulsive interaction (g>0) between the adsorbed H species appears. The value of K in the alkaline aqueous solution is much greater than that in the acidic aqueous solution.

• 물과 미래
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• 제26권3호
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• pp.137-148
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• 1993

종확산 방정식에 대한 유한차분 모형으로서, 5차의 보간다항식을 사용한 Holly-Preissmann 기법과 Generalized Crank-Nicholson 기법을 결합한 혼합모형을 개발하였다. 순간적으로 부하된 오염원의 종확산문제에 본 모형 및 특성곡선을 고려한 다른 수치기법들을 적용하여 정확해와 비교하였다. 보 모형에 의한 계산결과, Courant 수에 관계없이 수치진동이 전혀 발생하지 않았으며, 최대농도 발생지점도 정확해와 일치하였다. 모형의 적용에 있어서 시간가중치 $\theta$의 값이 작을수록 계산의 정확성이 전반적으로 향상되는 것으로 나타났으며, $\theta$의 값을 크게 할수록 최대농도값을 과대평가하는 경향을 보였다. 전반적으로 Courant 수가 작을수록 정확한 계산결과를 나타내고 있으나 그 민감도는, 특히 $\theta$의 값이 작을수록, 매우 작게 나타났다. 3차의 보간다항식을 사용하는 혼합모형 및 연산자 분리방법들과의 비교결과, 이송항이 지배적일수록 본 모형이 정확해와 가장 근사한 계산결과를 보임을 알 수 있었다.

• 대한간호학회지
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• 제32권6호
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• pp.878-887
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• 2002

This study was to explore lived experience of middle-aged women with aging. The ultimate purpose of this inquiry was to discover the essence of middle-aged women's experience of aging and to promote understanding. Method: This inquiry was performed by using Van Manen's hermeneutical phenomenological approach to make more plausible interpretation of experience. First-handed experiences were explored through multi-stage in-depth interview with 6 women aged between 40 and 64. Second- handed experiences were explored with text such as essay, novel, and photographs. Result: As the process of reflecting and analysing the data of experience were performed, essential themes were emerged: striking onset of event, discomfort and tired body and mind, everything in ones mind, age of harvest gaining much more than loss. Conclusion: This inquiry would be a cornerstone for humanistic nursing care for the mid-aged women.