• Journal of the korean society of oceanography
• /
• v.34 no.2
• /
• pp.59-72
• /
• 1999

Cavitating fluid sea ice model of Plato and Hibler (1992) is applied to the Southern Ocean with an idealized, circular Antarctica. Using climatological atmospheric forcing fields averaged in the zonal direction, we show that oceanic heat flux and ice velocity have major effects on the seasonal change of ice edge, as other studies showed. In our model results, there appears a zone of free drift that contains a polynya zone. Thermodynamic forcing functions make dominant contributions to daily increments of ice thickness and compactness, except the zones of ice edge and polynya. The dominant contributions are also shown in distributions of the temperature on ice surface and several to terms in surface heat balance equation, and are also confirmed by those obtained from the thermodynamic-only model with the different locations of ice edge.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2004.05a
• /
• pp.648-651
• /
• 2004

Many damage models has been developed to express the degradation of materials. However, only minor damage model for concrete has been developed because of the heterogeneity of it unlike metals. To model the damaged behavior of concrete, this peculiarity as well as a load-induced anisotropic feature must be considered. In this paper, basic concepts of the thermodynamic theory is investigated to model the behavior of the damaged concrete in the phenomenological viewpoint. And the general constitutive relations and damage evolution equations are investigated too.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.1 no.1
• /
• pp.80-89
• /
• 1993

Performance simulation for a Spark Ignition Wankel rotary Engine is presented in this paper. The volume of chamber at each eccentric shaft angle is evaluated by using geometric models of housing and rotor. A thermodynamic model which includes the first law of thermodynamics, combustion and convective heat transfer from chamber contents to surroundings is imployed. A thermochemical equilibrium model which considers 10 species(CO, $CO_2$, $O_2$, $H_2$, $H_2O$, OH, O, NO, $N_2$) in the burned gas region, is also employed. Four processes of gas exchange, compression, combustion and expansion are considered and the pressure, temperature and composition of chamber gas at each eccentric shaft angle in each process are computed in this performance simulation. This performance simulation must be useful for optimal design of Spark Ignition Wankel Rotray Engine with parametric study for various design parameters and operating conditions.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2003.07a
• /
• pp.77-80
• /
• 2003

Hydrocarbon-hydrocarbon separations are one of the most important processes in petroleum refining. Distillation process has been used for separating hydrocarbons, but this conventional process is very energy consuming. Pervaporation separation through polymeric membranes is an emerging process alternative to distillation because of energy savings, compact system installation, reduced capital investment, and other performance attributes. In hydrocarbon separations, polymeric membranes are easily swollen by hydrocarbons and can lose mechanical strength. Chemically robust membranes are needed for the separation of hydrocarbons. In this study, the blend membrane was applied to separate benzene and cyclohexane. This is a model system for aliphatic and aromatic separation. Cyclohexane is also physically very similar to benzene and as a result of the very closing boiling points (0.6$^{\circ}C$), benzene and cyclohexane form an azetrope. Thus the system provides a good model for azeotrope breaking by pervaporation. The semi-quantitative thermodynamic model predicts that the calculated selectivity increases with increasing Hydrin contents in the blend membranes. Pervaporation experiments utilizing various operating temperatures and feed concentrations with different blend membranes are compared with the result from semi-quantitative thermodynamic calculations.

• International Journal of Automotive Technology
• /
• v.4 no.3
• /
• pp.125-133
• /
• 2003

Several models for the evaluation of Gross Heat Release from the internel combustion engine (ICE) are often used in literature. One of these is the First Law - Single Zone Model (FL-SZM), derived from the First Law of Thermodynamic. This model present a twice advantage: first it describes with accuracy the physic of the phenomenon (charge heat release during the combustion stroke and heat exchange between gas and cylinder wall); second it hat a great simplicity in the mathematical formulation. The evaluation of Heat Release with the FL-SZM is based on pressure experimental measurements inside the cylinder, and ell the assumption of several parameters as the specific heat ratio, wall temperature, polytropic exponent for the motored cycle evaluation, and many others. In this paper the influence of gases thermodynamic properties on Cross Heat Release has been esteemed. In particular the influence of an appropriate equation for k=k(T) (specific heat ratio vs. temperature) which describes the variations of gases thermodynamic properties with the mean temperature inside the cylinder has been evaluated. This equation has been calculated by new V order Logarithmic Polynomials (VoLP), fitting experimental gases properties through the least square methods.

• Membrane and Water Treatment
• /
• v.9 no.2
• /
• pp.79-85
• /
• 2018

In this work, batch adsorption of anionic dye acid green-25 (AG-25) from aqueous solution has been carried out at room temperature using anion exchange membrane (DF-120B) as a noval adsorbent. The effect of various experimental parameters such as contact time, membrane dosage, ionic strength and temperature on the adsorption of dye were investigated. Kinetic models namely pseudo-first-order, pseudo-second-order, Elovich, liquid film diffusion, Bangham and modified freundlich models were employed to evaluate the experimental data. Parameters like adsorption capacities, rate constant and related correlation coefficients for every model are calculated and discussed. It showed that adsorption of AG-25 onto DF-120B followed pseudo-first-order rate expression. Thermodynamic study indicates that adsorption of AG-25 onto DF-120B is an exothermic and spontaneous process.

• Proceedings of the Korean Ceranic Society Conference
• /
• 2002.10a
• /
• pp.16-16
• /
• 2002

• Environmental Mutagens and Carcinogens
• /
• v.21 no.2
• /
• pp.118-121
• /
• 2001

The predictive screening of various molecular descriptors for predicting carcinogenic, mutagenic, teratogenic and alkylation activity of chlorinated disinfection byproducts (DBPs) has been investigated for the application of quantitative structure-activity relationships (QSAR). The toxicity index for 29 compounds were computed by the PASS program and active values were employed in this study. Studies show that different descriptors account for the model equation of each genotoxic endpoint and that thermodynamic descriptors significantly played a major role on prediction of endpoints of chlorinated aliphatic compounds.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.27 no.9
• /
• pp.1238-1247
• /
• 2003

Simplified thermodynamic analysis of high pressure 4-stage reciprocating compressors with 4 inter-coolers has been investigated to predict a behavior of a compressor system for NGV(natural gas vehicles). A computer program has been developed to predict and estimate the performance of high pressure 4-stage reciprocating compressor system. Thermodynamic properties of compressed natural gas(CNG) were calculated by ideal gas theory and compression cycle was assumed as reversible adiabatic compression and expansion processes, and isobaric intake and discharge processes. Comparison between results predicted by calculation model and measured by experimental tests is presented.

• Journal of the Korean Chemical Society
• /
• v.62 no.2
• /
• pp.79-86
• /
• 2018

This study reported the adsorption of Cu(II) ions onto activated carbon prepared from Myristica Fragrans shell (MFS AC) over independent variables of contact time, activating chemical (NaOH) concentration, initial adsorbate concentration, initial pH of adsorbate solution and adsorption temperature. The MFS AC structure, morphology and total surface area were characterized by FTIR, SEM and BET techniques, respectively. The Cu(II) ions adsorption on the MFS AC (activated using 0.5 M NaOH) fitted best to Freundlich adsorption isotherm (FAI), and the FAI constant obtained was 0.845 L/g at $30^{\circ}C$ and pH 4.5. It followed the pseudo first order of adsorption kinetic (PFOAK) model, and the PFOAK based adsorption capacity was 107.65 mg/g. Thermodynamic study confirmed the Cu(II) ions adsorption should be exothermic and non-spontaneous process, physical adsorption should be taken place. The total surface area and pore volume based on BET analysis was $99.85m^2/g$ and 0.086 cc/g, respectively.