• Transactions of the Korean Society of Automotive Engineers
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• v.1 no.1
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• pp.80-89
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• 1993

Performance simulation for a Spark Ignition Wankel rotary Engine is presented in this paper. The volume of chamber at each eccentric shaft angle is evaluated by using geometric models of housing and rotor. A thermodynamic model which includes the first law of thermodynamics, combustion and convective heat transfer from chamber contents to surroundings is imployed. A thermochemical equilibrium model which considers 10 species(CO, $CO_2$, $O_2$, $H_2$, $H_2O$, OH, O, NO, $N_2$) in the burned gas region, is also employed. Four processes of gas exchange, compression, combustion and expansion are considered and the pressure, temperature and composition of chamber gas at each eccentric shaft angle in each process are computed in this performance simulation. This performance simulation must be useful for optimal design of Spark Ignition Wankel Rotray Engine with parametric study for various design parameters and operating conditions.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.6
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• pp.413-420
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• 2011

Thermodynamic cycles using binary mixtures as working fluids offer a high potential for utilization of low-temperature heat sources. This paper presents a thermodynamic performance analysis of Goswami cycle which was recently suggested to produce power and cooling simultaneously and combines the Rankine cycle and absorption refrigeration cycle by using ammoniawater mixture as working fluid. Effects of the system parameters such as concentration of ammonia and turbine inlet pressure on the system are parametrically investigated. Results show that refrigeration capacity or thermal efficiency has an optimum value with respect to ammonia concentration as well as to turbine inlet pressure.

• 제어로봇시스템학회:학술대회논문집
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• 2005.06a
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• pp.129-133
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• 2005

In this paper, first the thermodynamic model is presented to one of the super heaters and sprays of the Nekka power plant and then its unknown parameters are identified according to the registered data of the power plant. SCO control method is introduced to control the external steam temperature of super heater. Finally the conventional method in power plant for controlling external steam temperature of super heater is compared with new method and their performances are presented..

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.7
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• pp.649-658
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• 2000

Thermodynamic modeling of low-pressure scroll compressor was developed by combining continuity and energy conservation equation. Suction gas heating was considered using energy balance inside the low pressure shell. Pressure, temperature and mass of refrigerant-22 as a function of orbiting angle were calculated by solving the governing equations using fourth order Rung-Kutta scheme. Motor efficiency was taken by experiments with a variation of frequency. The developed model was applied to the analysis of an inverter driven scroll compressor with a variation of frequency, pressure ratio and operating conditions. The model was verified with the experimental results at the same operating conditions. The developed model was adequate to predict performance of the inverter driven scroll compressor as a function of operating conditions. Calculated parameters from the model were discharge temperature, mass flow rate, power input, COP, and thermodynamic properties with respect to orbiting angle. To enhance the performance of a scroll compressor, it is essential to diminish leakage at low frequency level and improve the mechanical efficiency at high frequency level.

• Journal of Energy Engineering
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• v.23 no.4
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• pp.215-222
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• 2014

A theory-based methodology for describing the thermodynamic properties of molecular nitrogen is presented. The results obtained indicate a successful application of a fully consistent statistical method for the description of a molecular system in different phase states. The method employs a density of states equation for solid nitrogen and a perturbation potential for gaseous and liquid nitrogen. The main characteristics of the calculation method include the need for a minimal number of initial data and the absence of fitting parameters. The adequacy of the physical model that is the basis for the method allows a description of existing experimental data and the peculiarities of the thermodynamic properties.

• Korean Chemical Engineering Research
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• v.55 no.4
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• pp.490-496
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• 2017

We have designed an extractive distillation for separating maximum boiling azeotrope of acetone-chloroform system. PRO/II 9.4 was used to simulate the overall process. The VLE data adopted from Dortmund data bank was regressed to obtain a new set of binary interaction parameters. Three different entrainers were used for the separation process--dimethyl sulfoxide (DMSO), ethylene glycol (EG) and benzene--to test their viability for the acetone-chloroform system. Thermodynamic feasibility analysis was done through ternary map diagrams. Two different thermodynamic models, NRTL and UNIQUAC, were explored for the study of overall process.

• Textile Coloration and Finishing
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• v.24 no.4
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• pp.239-246
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• 2012

The binding isotherms of ionic dyes with Poly(vinylpyrrolidone) in aqueous solution were determined by the dynamic dialysis technique. The shape of the isotherms of cationic dye, C. I. Basic Red 18 with poly(vinlypyrrolidone) showed a partition type. It suggests that the binding involves a non-cooperative mode. Isotherms of an anion dye, a synthesized dye by coupling of diazotized m-trifluoromethylaniline with 2-naphthol-6-sulfonic acid, were sigmoid type and showed multimode interaction. The results were interpreted by the McGhee von Hippel theory. The thermodynamic parameters for the complex formation of the dyes-polymer were calculated from their temperature dependences of the intrinsic binding constant.

• Bulletin of the Korean Chemical Society
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• v.17 no.2
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• pp.131-138
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• 1996

The conformational transition of oligopeptide multimer,-(HPPHPPP)n-, is studied (H:hydrophobic amino acid, P:hydrophilic amino acid). The helix/coil transitions are detected in the multimer. The transition depends on the number of amino acid in the sequence, the concentration of the oligopeptide, and temperature which affects helix stability constant (${\xi}$) and hydrophobic interaction parameter (wj). In the thermodynamic equilibrium system jA${\rightarrow}$Aj (where A stands for oligopeptide monomer), Skolnick et al., explained helix/coil transition of dimer by the matrix method using Zimm-Bragg parameters ${\xi}$ and $\sigma$ (helix initiation constant). But the matrix method do not fully explain dangling H-bond effects which are important in oligopeptide systems. In this study we propose a general theory of conformational transitions of oligopeptides in which dimer, trimer, or higher multimer coexists. The partition of trimer is derived by using zipper model which account for dangling H-bond effects. The transitions of multimers which have cross-linked S-S bonds or long chains do not occur, because they keep always helical structures. The transitions due to the concentration of the oligopeptides are steeper than those due to the chain length or temperature.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.499-502
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• 2008

This paper presents on research findings of how Visual C++ program can be used to generate codes capable of performing ramjet engine simulation To understand the diversity and applicability of this tool an arbitrary ramjet model will be considered for which generated output values will be compared with those from a commercial program GASTURB 9 iterated under the same input parameters. Several governing thermodynamic equations will first be discussed in order that we understand the fundamental idea behind values printed out on the GUI. C++ compiler was chosen as a tool of use due to its availability, ease of use, ability to compute functions faster and uniquely possible to make a stand alone GUI executable in DOS mode. The program is developed in such a way that given the ambient flight conditions, burner exit temperature and several geometry areas the program generates its own input values used in the succeeding stations. A close resemblance of output values that define performance and thermodynamic state of the engine was realized between GASTURB 9 and using this code made from C++ compiler.

• Journal of the Korean Chemical Society
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• v.37 no.4
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• pp.442-447
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• 1993

The thermodynamic parameters (${\Delta}$G, ${\Delta}$H and ${\Delta}$S) of lanthanides(III)-benzoylformate complexes in aqueous solution have been determined in the ionic medium of 0.1M $NaClO_4$ at 25$^{\circ}C$, using pH and enthalpy titration method. The stability constants of the lanthanide(III)-benzoylformate complexes (1 : 1) agree well with the general relationships for the bidentate ligands (e.g., log${\beta}_1$ vs. p$K_a$). Thermodynamic evidences show that the oxygen atom in ketone group is coordinated along with the carboxylate group. It is ascribed to the increasing charge density on the oxygen atom in ketone group due to the conjugation effect in the benzoylformate ligand. Thermodynamic results also indicate that the complexes are stabilized by the enthalpy effect caused by the ionic interaction of metal-oxygen bond as well as the entropy effect.