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http://dx.doi.org/10.5764/TCF.2012.24.4.239

Interaction between Poly(vinylpyrrolidone) and Ionic Dyes in Aqueous Solution System (I)  

Lee, Sangchul (Department of Organic Material Science and Engineering, Pusan National University)
Kim, Heain (Department of Organic Material Science and Engineering, Pusan National University)
Park, Soomin (Department of Organic Material Science and Engineering, Pusan National University)
Publication Information
Textile Coloration and Finishing / v.24, no.4, 2012 , pp. 239-246 More about this Journal
Abstract
The binding isotherms of ionic dyes with Poly(vinylpyrrolidone) in aqueous solution were determined by the dynamic dialysis technique. The shape of the isotherms of cationic dye, C. I. Basic Red 18 with poly(vinlypyrrolidone) showed a partition type. It suggests that the binding involves a non-cooperative mode. Isotherms of an anion dye, a synthesized dye by coupling of diazotized m-trifluoromethylaniline with 2-naphthol-6-sulfonic acid, were sigmoid type and showed multimode interaction. The results were interpreted by the McGhee von Hippel theory. The thermodynamic parameters for the complex formation of the dyes-polymer were calculated from their temperature dependences of the intrinsic binding constant.
Keywords
poly(vinylpyrrolidone); ionic dye; multimode interaction; binding isotherm; sigmoid type; thermodynamic;
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Times Cited By KSCI : 3  (Citation Analysis)
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