• Korean Journal of Metals and Materials
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• v.50 no.2
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• pp.116-121
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• 2012

Equilibria between Mn-Si melts and $MnO-SiO_2$ slags were studied at 1673 K and 1773 K in MnO crucibles to accurately determine the thermodynamic property of the Mn-Si melts. The Unified Interaction Parameter Formalism (UIPF) was used to describe the thermodynamic property of the Mn-Si liquid. Using the UIPF, the experimental results obtained in the present study were thermodynamically analyzed to determine the activity coefficient of Si at infinite dilution and the 1st- and 2nd-order self-interaction parameters of Si in the Mn-Si melts.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.6
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• pp.649-655
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• 2021

The recently proposed Kalina based power and cooling cogeneration cycles (KPCCCs) have shown improvement in the energy utilization of the system compared to the basic Kalina cycle. This paper suggests a combined tri-cogeneration system for power, heating and cooling based on the Kalina cycle. And thermodynamic performances of the suggested system based on the first and second thermodynamic laws are parametrically investigated with respect to the ammonia mass fraction and the boiler pressure. Results showed that the thermodynamic performance of the system could be greatly improved compared to the former KPCCCs.

• Bulletin of the Korean Chemical Society
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• v.27 no.1
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• pp.31-32
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• 2006

• Bulletin of the Korean Chemical Society
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• v.22 no.7
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• pp.779-781
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• 2001

• Proceedings of the Korean Magnestics Society Conference
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• 2008.12a
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• pp.265.1-265.1
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• 2008

• Nuclear Engineering and Technology
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• v.25 no.2
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• pp.265-275
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• 1993

A vapor explosion has been a concern in nuclear reactor safety due to its potential for a destructive mechanical energy release. In order to properly assess the hazard of a vapor explosion, it is necessary to accurately estimate the conversion efficiency of the thermal energy to mechanical energy. In the absence of a complete model to determine the explosive energy yield, one may have to rely on a simpler upper bound estimate such as a thermodynamic model. This paper discusses various thermodynamic models and presents a clarification of each model in their mathematical formulation and the thermodynamic work conversion. It is shown that the work release in the shock adiabatic model of Board and Hall is essentially equal to that of Hicks-Menzies thermodynamic model. The effect of coolant void fraction on the explosion efficiency is also predicted based on these thermodynamic models. Finally, the Hicks-Menzies model is modified to account for the chemical reaction between a metallic fuel and water and the resultant effects on the explosion expansion work are discussed.

• Plant Journal
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• v.17 no.1
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• pp.50-57
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• 2021

It is very difficult to accurately calculate efficiency of each accessory device constituting the pump system and pump efficiency by the Conventional efficiency measurement method only. Therefore, this study introduced the lastest Thermodynamic pump efficiency measurement method in the district heating pump system for the first time in Korea. As a result, data uncertainty was high by the Conventional method, but the pump and Hydraulic Coupling efficiency values applied the Thermodynamic and Conventional method parallel measurement data were able to derive meaningful results that verified the reliability and adequancy of the pump performance measurement method by performing complementary roles. In additon, as a result of applying the Thermodynamic method to the distirct heating pump system, despite the high temperature environment of up to 120 ℃, it was possible to verify the reliability of the Thermodynamic method, such as high stable data mesurement, and durability of the measurement equipment.

• Structural Engineering and Mechanics
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• v.81 no.2
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• pp.205-217
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• 2022

The thermodynamic properties of shaft lining concrete (SLC) are important evidence for the design and construction, and the spatial variability of concrete materials can directly affect the stochastic thermal analysis of the concrete structures. In this work, an array of field experiments of the concrete materials are carried out, and the statistical characteristics of thermophysical parameters of SLC are obtained. The coefficient of variation (COV) and scale of fluctuation (SOF) of uncertain thermophysical parameters are estimated. A three-dimensional (3-D) stochastic thermal model of concrete materials with heat conduction and hydration heat is proposed, and the uncertain thermodynamic properties of SLC are computed by the self-compiled program. Model validation with the experimental and numerical temperatures is also presented. According to the relationship between autocorrelation functions distance (ACD) and SOF for the five theoretical autocorrelation functions (ACFs), the effects of the ACF, COV and ACD of concrete materials on the uncertain thermodynamic properties of SLC are analyzed. The results show that the spatial variability of concrete materials is subsistent. The average temperatures and standard deviation (SD) of inner SLC are the lowest while the outer SLC is the highest. The effects of five 3-D ACFs of concrete materials on uncertain thermodynamic properties of SLC are insignificant. The larger the COV of concrete materials is, the larger the SD of SLC will be. On the contrary, the longer the ACD of concrete materials is, the smaller the SD of SLC will be. The SD of temperature of SLC increases first and then decreases. This study can provide a reliable reference for the thermodynamic properties of SLC considering spatial variability of concrete materials.

• Bulletin of the Korean Chemical Society
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• v.32 no.3
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• pp.1030-1032
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• 2011

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.6
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• pp.476-483
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• 2016

An organic Rankine cycle for ocean thermal energy conversion system is a generating cycle using the temperature difference between surface water and deep water of the ocean. The working fluid is an important factor in the thermodynamic performance of an organic Rankine cycle. There is pinch point analysis as thermodynamic analysis of an organic Rankine cycle. This study performed a thermodynamic performance analysis according to variation in the pinch point temperature difference in heat exchangers and variation of outlet temperature of heat source and heat sink. It analyzed the thermodynamic performance by applying seven types of simple working fluids in a simple Rankine cycle for ocean thermal energy conversion that was designed according to pinch point analysis. As a result of the performance analysis, cycle irreversibility and total exergy destruction factor more decreased, and second law efficiency more increased in the lower pinch point temperature difference and temperature variation of heat source and heat sink in heat exchangers. In addition, the irreversibility changed greatly at a point that occurred in the thermodynamic variation. Among the selected working fluids, RE245fa2 showed the best thermodynamic performance, and the performance of all working fluids was observed to be similar. It needs a strict theoretical basis about diverse factors with thermodynamic performances in selecting heat exchangers and working fluids.