• Title/Summary/Keyword: Thermally Stimulated Current(TSC)

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The Characteristics of Termally Stimulated Current for Epoxy Composites : The effects of Curing Agents and Fillers (에폭시 복합재료의 열자격전류(TSC) 특성: - 경화제와 충진제의 영향)

  • Wang, Jong-Bae;Park, Jun-Bum;Lee, Joon-Ung;Kim, Hong-Chul
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1162-1164
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    • 1993
  • The Thermally Stimulated Current(TSC) spectroscopy has been applied to study the influence of the structual cahange and interface on the electrical properties of epoxy composites. Three DGEBA-MeTHPA matrix model samples mixed different ratios and silica($SiO_2$) filled sample and silaln treating-filled sample has been studied. Above room temperature, the relaxation mode $\alpha$ peak associated with Tg has been located at $110^{\circ}C$. Below glass transition temperature(Tg), three relaxation modes are observed in all samples: a $\beta$ mode situated at $10^{\circ}C$, a $\gamma$ mode located at $-40^{\circ}C$ and a $\delta$ mode appeared in $-120^{\circ}C$. The analysis of its fine structure indicates that constitution of elementary processes is characterized by the activation energy and relaxation time. Also the dielectric relaxation properties have been investigated to compare the the change of the molecular structure and motion to the relaxation properties and conduction mechanism in TSC spectra.

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Oprical Properties of $\alpha$-Sulfur Single Crystal ($\alpha$-sulfur 단결정의 광학적 특성에 관한 연구)

  • 송호준;김화택;이정순
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.6
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    • pp.442-446
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    • 1998
  • $\alpha$--sulfur single crystal which has orthorohmbic structure was grown using Bridgman method. The indirect optical energy band gap of this crystal are 2.65 and 2.82 eV at 10 and 300K, respectively. The wavelengths of photoluminecence(PL) peaks are 543 and 596 nm at 10k, By thermally stimulated current (TSC) method, two electron traps($D_1,D_2$) located at 0/23 and 0.43eV below the conduction band and a hole trap(A) located at 0.31 eV above the valence band are observed. PL mechanism of $\alpha$-sulfur single crystal is analyzed using the values of optical energy band gap at 10k two electron traps and a hole trap.

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Characteristics of Thermally Stimulated Current in the ZnO varister (ZnO 바리스터의 TSC 특성)

  • 안용모;이성일;이상석;박춘배;이준용
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1989.06a
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    • pp.101-104
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    • 1989
  • Thermal Electet of the Zinc Oxide varistor has been studied in the temperature range of -130~200[$^{\circ}C$] and the electric field of 6[kV/m]. It appears that there are four peaks of thermally stimulated current; $\alpha$, $\beta$, ${\gamma}$ and $\delta$ spectra appearing at the temperature range of 160, 130, 20 and -30[$^{\circ}C$], respectively. It seems that the origin of $\alpha$, $\beta$, ${\gamma}$ and $\delta$ peaks are associated with the depolarization of donor ions in the depletion layer, the detrapping of trapped electron in the surface, the detrapping of trapped electron in the donor level and the detrapping of trapped electron between grain and intergranular, respectively.

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Simulation of Charging Process in Forming Electret for Sensor Material (센서재료용 일렉트렛트 형성에 대전과정 시뮬레이션)

  • Park, Geon-Ho
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2011.01a
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    • pp.185-188
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    • 2011
  • In order to estimate spatial charging process in the corona charging which has been used to make polymer electret, the electrical properties of polypropylene film were obtained from Thermally Stimulated Current(TSC) measurements after corona charging between knife electrode and cylinder electrode with the voltages of -5, -6, -7 and -8[kV], respectively. And then the electrostatic contour and the electric field vector were also simulated by using Finite Element Method(FEM). The edge effect around edge of knife electrode affected the electrostatic contour on surface of specimen and the electric field concentration inside specimen. The uneven charging state in the electret due to the mistake on design could be calculated and so the optimal design of corona charging device which is appropriate to various materials is come to be practicable.

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The Analysis of TSC Equation by Asymptotic Estimation (점근해법에 의한 열자격 전류식의 분석)

  • Oh, Yong-Cheul;Hong, Jin-Woong;Kim, Ki-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05d
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    • pp.96-99
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    • 2003
  • In this paper, it presents a method to calculate the escape frequency factor$(\nu)$ and its verification from TSC(Thermally Stimulated Current) equation and their simulation curves. To apply calculation method of $\nu$ using asymptotic estimation, it utilized TSC data with 1K interval. This method enables one to get the exact value of $\nu$ and activation energy at the same time by using computer programming. So, it regards their calculation method as a useful process to obtain the value of physical behavior.

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The origin of thermally stimulated current in zinc oxide varistors with $TiO_2$ additions ($TiO_2$를 첨가한 산화 아연 바리스터에 대한 열자격전류의 기원)

  • 장경욱;이성일;이준웅
    • Electrical & Electronic Materials
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    • v.6 no.2
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    • pp.161-167
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    • 1993
  • ZnO 바리스터의 비선형 전도특성은 입자의 구조로부터 설명할 수 있다. 본 논문에서는 ZnO 바리스터의 입자구조에 트랩된 캐리어를 분석하기 위해서 TSC 측정 기법을 사용하였다. 측정 결과로 부터 네개의 TSC피크를 얻었다. 고온으로 부터 첫번째 두번째와 세번째 TSC피크의 기원은 각각 트랩, 도너 밀도 및 입계층의 트랩으로 나타나고 네번째 피크의 기원은 공핍층에 있는 도너 이온의 탈분극에 의해서 기인하는 것으로 사료된다. .alpha.$_{1}$피크의 활성화 에너지는 약 0.33-1.42eV였다. 또한 바리스터의 예비동작 영역에서의 전도특성은 .alpha.$_{1}$과 .alpha.$_{2}$피크의 값에 지배된다는 것을 확인하였다.

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The Properties of Thermally Stimulated Currents according to Electrical Stress in Epoxy Composites (전기적 스트레스에 따른 에폭시 복합체의 열자격전류 특성)

  • Oh, Hyun-Seok;Kim, Jin-Sa;Park, Geon-Ho;Lee, Joon-Ung
    • Proceedings of the KIEE Conference
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    • 1995.11a
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    • pp.401-403
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    • 1995
  • The degradation phenomena according to electrical stress in epoxy composites were studied. The formation of electrets were observed by appling high voltages, 22.9[kW/cm], during 5[hr] to five kinds of specimens for a given mixing rate, and then TSC(thermally stimulated current) values were measured at the temperature range of $-160\sim200[^{\circ}C]$.

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Polarity of Charged Particles n XLPE Measured by Temperature Gradient Thermally Stimulated Surface Potential (온도 구배열자극측정법의한 XLPE하전입자의 극성판정)

  • Kook, Sang-Hoon
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.34 no.4
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    • pp.144-152
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    • 1985
  • This paper temperature gradient thermally stimulated surface potentian (TG-TSSP) in measurements are applied to the study of the polarity of trapped and ionic carriers in cross-linked polyethylene (XLPE) filsm. In the thermally stimulated current in uniform temperature (TSC) of XLPE five peaks appear as indicated of the A B C D and E. In this paper A (at about -120$^{\circ}C$) D (at about 70$^{\circ}C$) and E (at about 110$^{\circ}C$) peaks are investigated. A peak is due to the biassing voltage and biassing temperature. Appear in to the glass transition temperature territory and caused in to the polarization of dipole. D peak is due to the depolarization of ionic space charge and E peak due to the detrapping of carriers injected from the electrodes. TG-TSSP and TSSP are measured to study the polarity of ionic carrier (D peak). In the unsatureated region of ionic space charge polarization, TG-TSSP is lower than TSSP during the initial stage of heating. Result of the experiment for E peak, TG-TSSP is higher than TSSP during the initial stage of heating and these results do not depend on the polarity of biassing voltage, and E peak is concerned with positive carriers (Holes).

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A Estimation of Ionic Space Charge Polarization in Polyimide by TSC (폴리이미드에서 TSC에 의한 이온성 공간전하분극의 평가)

  • Lee, Won-Jae;Lee, Sung-Il;Lee, Ho-Sik;Jang, Kyung-Uk;Choi, Myong-Kyu;Kim, Tae-Wan;Kang, Dou-Yol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.10a
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    • pp.15-20
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    • 2000
  • In this paper. Thermally Stimulated Current spectra have been measured in the Polypy - romellitimide (polyimide). As a result of the investigation. three peaks have been observed: $A(50^{\circ}C)$, $B(120^{\circ}C)$, $C(200^{\circ}C)$. Among three peaks, C peak has been observed in detail. The C peak is shown to be created due to the polarization of ionic space charge from the experimental results which were measured as a function of forming time, forming temperature. forming voltage and collecting voltage. As a result, we have measured the TSC in ion ($Na^+$) implanted - Polyimide, also found the peak at $215^{\circ}C$. Therefore, TSC characteristics in the C peak is probably caused by residual impurity. And The activation energy caculated by means of initial rising method 1.8eV, hopping distance. $90{\AA}$. and the mobility. $2.88{\times}10^{-11}cm^2/v.s$

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A study on the behavior of charge particles of $(SR.Ca)TiO_3$ ceramic ($(SR.Ca)TiO_3$세라믹의 하전입자 거동에 관한 연구)

  • 김진사;최운식;신철기;김성열;박현빈;김태성;이준응
    • Electrical & Electronic Materials
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    • v.10 no.2
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    • pp.97-104
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    • 1997
  • In this paper, in order to investigate the behavior of charged particles on (Sr.Ca)TiO$_{3}$ ceramics with paraelectric properties, the characteristics of electrical conduction and thermally stimulated current was measured respectively. As a result, the conduction mechanism is divided into three regions having different mechanism as the current increased. The region I below 200[V/Cm] shows the ohmic conduction. The region B between 200[V/cm] and 2000[V/cm] can be explained by the Poole-Frenkel emission theory, and the region III above 2000[V/cm] is dominated by the tunneling effect. The three peaks of TSC were obtained at the temperature of -20[.deg. C], 20[.deg. C] and 80[.deg. C], respectively. The origins of these peaks are that the .alpha. peak observed at -20[.deg. C] looks like to be ascribed to the ionization excitation from donor level in the grain, and the .alpha.' peak observed at 20 [.deg. C] appears to show up by hopping conduction of the trapped carrier of border between the oxidation layer and the grain, and the .betha. peak observed at 80[.deg. C] seems to be resulted from hopping conduction of existing carrier in the trap site of the border between the oxidation and second phase.

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