• Title/Summary/Keyword: Thermal processes

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Study of Low Temperature Solution-Processed Al2O3 Gate Insulator by DUV and Thermal Hybrid Treatment (DUV와 열의 하이브리드 저온 용액공정에 의해 형성된 Al2O3 게이트 절연막 연구)

  • Jang, Hyun Gyu;Kim, Won Keun;Oh, Min Suk;Kwon, Soon-Hyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.4
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    • pp.286-290
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    • 2020
  • The formation of inorganic thin films in low-temperature solution processes is necessary for a wide range of commercial applications of organic electronic devices. Aluminum oxide thin films can be utilized as barrier films that prevent the deterioration of an electronic device due to moisture and oxygen in the air. In addition, they can be used as the gate insulating layers of a thin film transistor. In this study, aluminum oxide thin film were formed using two methods simultaneously, a thermal process and the DUV process, and the properties of the thin films were compared. The result of converting aluminum nitrate hydrate to aluminum oxide through a hybrid process using a thermal treatment and DUV was confirmed by XPS measurements. A film-based a-IGZO TFT was fabricated using the formed inorganic thin film as a gate insulating film to confirm its properties.

Evaluation of Thermal Behavior of Oil-based Nanofluids using Ceramic Nanoparticles (세라믹 분말을 이용한 오일 기지 나노유체의 열적거동 평가)

  • Choi, Cheol;Yoo, Hyun-Sung;Oh, Je-Myung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.7
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    • pp.587-593
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    • 2007
  • Oil-based nanofluids were prepared by dispersing spherical and fiber shaped $Al_2O_3$ and AlN nanoparticles in transformer oil. Two hydrophobic surface modification processes using oleic acid (OA) and polyoxyethylene alkyl acid ester (PAAE) were compared in this study. The dispersion stability, viscosity and breakdown voltage of the nanofluids were also characterized. $(Al_2O_3+AlN)$ mixed nanofluid was prepared to take an advantage of the excellent thermal conductivity of AlN and a good convective heat transfer property of fiber shaped $Al_2O_3$. For $(Al_2O_3+AlN)$ particles with 1 % volume fraction in oil, the enhancement of thermal conductivity and convective heat transfer coefficient was nearly 11 % and 30 %, respectively, compared to pure transformer oil. The nanofluid, containing $Al_2O_3+AlN$, successfully lowered the temperature of the heating element and oil itself during a natural convection test using a prototype transformer.

Curtailment of Water use Through the Integration of Process Waste Waters at the Standard Thermal Power Plant (표준화력발전소의 발전폐수 통합을 이용한 용수 사용량 절감)

  • Mun, Gyeong-Seok;Jang, Heui-Su
    • Journal of Korean Society on Water Environment
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    • v.22 no.3
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    • pp.437-443
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    • 2006
  • The Water usage is relationship which is close with the administrative cost from industrial facility. It is not easy to reduce a water usage. This research is the optimization of the waste water quantity which process waste water integration of the standard thermal power plant in system operate time. The turbine rotates by force of the steam and it produces an electricity. Demineralization Water is manufacture purity manufacturing equipment and it is supplied in power plant channel. We knew a possibility of reducing from pure control process. When it is reduced the Back Washing time, Rinsing time of the gravity filter and the activated carbon filter. Also, It is possible even from regeneration phase in Condensate Polishing Demineralization System. In addition, There is also the water which the drain of the sampling water for watching the condition of power plant process will be able to use. Integrates these processes it will be able to reduce an annual 30,000 ton degree. The research is want to use the fundamental data for the water curtailment of the power plant.

Effect of SC-1 Cleaning to Prevent Al Diffusion for Ti Schottky Barrier Diode (Ti 쇼트키 배리어 다이오드의 Al 확산 방지를 위한 SC-1 세정 효과)

  • Choi, Jinseok;Choi, Yeo Jin;An, Sung Jin
    • Korean Journal of Materials Research
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    • v.31 no.2
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    • pp.97-100
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    • 2021
  • We report the effect of Standard Clean-1 (SC-1) cleaning to remove residual Ti layers after silicidation to prevent Al diffusion into Si wafer for Ti Schottky barrier diodes (Ti-SBD). Regardless of SC-1 cleaning, the presence of oxygen atoms is confirmed by Auger electron spectroscopy (AES) depth profile analysis between Al and Ti-silicide layers. Al atoms at the interface of Ti-silicide and Si wafer are detected, when the SC-1 cleaning is not conducted after rapid thermal annealing. On the other hand, Al atoms are not found at the interface of Ti-SBD after executing SC-1 cleaning. Al diffusion into the interface between Ti-silicide and Si wafer may be caused by thermal stress at the Ti-silicide layer. The difference of the thermal expansion coefficients of Ti and Ti-silicide gives rise to thermal stress at the interface during the Al layer deposition and sintering processes. Although a longer sintering time is conducted for Ti-SBD, the Al atoms do not diffuse into the surface of the Si wafer. Therefore, the removal of the Ti layer by the SC-1 cleaning can prevent Al diffusion for Ti-SBD.

Adsorptive removal of Ni(II) ions from aqueous solution by PVDF/Gemini-ATP hybrid membrane

  • Zhang, Guifang;Qin, Yingxi;Lv, Chao;Liu, Xingtian;Zhao, Yiping;Chen, Li
    • Membrane and Water Treatment
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    • v.7 no.3
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    • pp.209-221
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    • 2016
  • As a highly hydrophilic fibrillar mineral in nature, attapulgite (ATP) is a promising new additive for preparation of ultrafiltration (UF) hybrid membrane. In this work, ATP particles, which were grafted with a new Gemini surfactant of Ethyl Stearate-di(octadecyl dimethyl ammonium chloride) to detach the crystal bundles to single crystal and enhance the uniform dispersion in an organic polymer matrix, were incorporated into poly(vinylidene fluoride) (PVDF) matrix, and PVDF/Gemini-ATP hybrid membranes for adsorptive removal of Ni(II) ions from aqueous solution were prepared via a phase inversion method. Chemical composition, crystalization and morphology of the modified ATP were characterized by Fourier transform infrared spectroscopy (FTIR), Transmission electron microscope (TEM) and X-ray diffraction (XRD), respectively. The morphology of the hybrid membrane was characterized by Scanning electron microscopy (SEM), the performance of permeability, hydrophilicity and adsorption of Ni(II) ions were studied, and the adsorption kinetics of the PVDF/ATP hybrid membranes were particular concerned. The results showed that the hybrid membrane displayed a good thermal stability and hydrophilicity. Comparing with PVDF membrane, the hybrid membrane possessed good adsorption capacity for Ni(II) ions, and the adsorption kinetics fit well with Lagergren second-order equation.

Effect of Si Particle Size on the Thermal Properties of Hyper-eutectic Al-Si Alloys (과공정 Al-Si 합금의 열팽창 특성에 미치는 Si 입자 크기의 영향)

  • Kim, Chul-Hyun;Joo, Dae-Heon;Kim, Myung-Ho;Yoon, Eui- Pak;Yoon, Woo-Young;Kim, Kwon-Hee
    • Journal of Korea Foundry Society
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    • v.23 no.4
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    • pp.195-203
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    • 2003
  • Hyper-eutectic Al-Si alloy is used much to automatic parts and material for the electronic parts because of the low coefficient of thermal expansion, superior thermal stability and superior wear resistance. In this work, A390 alloy specimens were fabricated for control of the Si particle size by various processes, such as spray-casting, permanent mold-casting and squeeze-casting. To minimize the effect of microporosity of the specimens, hot extrusion was carried out under equal condition. Each specimens were evaluated tensile properties at room temperature and thermal expansion properties in the range from room temperature to 400$^{\circ}C$. Ultimate tensile strength and elongation of the spray-cast and extruded specimens which have fine and well distributed Si particles were improved greatly compare to the permanent mold-cast and extruded ones. Specimens which have finer Si particles showed higher ultimate tensile strength and elongation than those having large Si particle size, and coefficient of thermal expansion of the specimens increased linearly with Si particle size. In case of the repeated high temperature exposures, thermal expansion properties of the spray-cast and extruded specimens were found to be more stable than those of the others due to the effect of fine and well distributed Si particles.

Development of Thermal-Conductivity Measurement System Using Cryocooler (극저온 냉동기를 이용한 열전도도 측정 시스템 개발)

  • Shin, Dong-Won;Kim, Dong-Lak;Yang, Hyung-Suk;Choi, Yeon-Suk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.1
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    • pp.93-100
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    • 2011
  • The thermal property of insulation material is essential in developing a high-temperature superconductor (HTS) power cable to be operated at around liquid-nitrogen temperature. Unlike metallic materials, nonmetallic materials have a high thermal resistance; therefore, accurate estimate of the heat flow is difficult in the case of nonmetallic materials. The aim of this study is to develop an instrument for precisely measuring the thermal conductivity of insulating materials over a temperature range of 30 K to approximately the room temperature by using a cryocooler. The details of the thermal-conductivity measurement system, including the design and fabrication processes, are described in this paper. In addition, the design optimization to minimize unavoidable heat leakage from room temperature is discussed.

Experimental Study on Heating Performance Characteristic of 100 kW Heat Pump to Generate ℃ Steam (120℃ 스팀 생성을 위한 100 kW급 히트펌프의 실험적 연구)

  • Wang, Eunseok;Na, Sun-Ik;Lee, Gilbong;Baik, Young-Jin;Lee, Young-Soo;Lee, Beomjoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.30 no.2
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    • pp.100-106
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    • 2018
  • Recently, the development of a heat pump technology to recover process waste heat and to generate steam of $120^{\circ}C$ or higher required for industrial processes, has attracted attention. The research of conventional heat pump utilizing the available energy is used primarily for air conditioning, and the production temperature is about $60^{\circ}C$, so it is difficult to utilize it for industrial use. Therefore, in this study, we developed a steam heat pump (SGHP) which recovers the waste heat of process and generates steam at $120^{\circ}C$. The low-pressure refrigerant R245fa, considered to be an eco-friendly refrigerant, has been selected as the refrigerant for SGHP in this study since its Ozone Depletion Potential (ODP) is zero and the Global Warming Potential (GWP) is relatively low. A flash tank functioning as a phase separator was installed in the rear stage of the condenser, and the saturated water of high temperature was decompressed to generate steam. It was started at the initial temperature of $70^{\circ}C$, and it was confirmed that $120^{\circ}C$ steam was produced after the system stabilized. We have conducted experiments by modifying the system, and ultimately achieved a heating capacity of 101.4 kW and a COP of 3.05.

Simulation of thermal distribution with the effect of groundwater flow in an aquifer thermal energy storage (ATES) system model (대수층 축열 에너지(ATES) 시스템 모델에서 지하수 유동 영향에 의한 지반내 온도 분포 예측 시뮬레이션)

  • Shim, Byoung-Ohan
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.1 no.1
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    • pp.1-8
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    • 2005
  • Aquifer Thermal Energy Storage (ATES) can be a cost-effective and renewable geothermal energy source, depending on site-specific and thermohydraulic conditions. To design an effective ATES system having the effect of groundwater movement, understanding of thermohydraulic processes is necessary. The heat transfer phenomena for an aquifer heat storage are simulated by using FEFLOW with the scenario of heat pump operation with pumping and waste water reinjection in a two layered confined aquifer model. Temperature distribution of the aquifer model is generated, and hydraulic heads and temperature variations are monitored at the both wells during 365 days. The average groundwater velocities are determined with two hydraulic gradient sets according to boundary conditions, and the effect of groundwater flow are shown at the generated thermal distributions of three different depth slices. The generated temperature contour lines at the hydraulic gradient of 0.001 are shaped circular, and the center is moved less than 5 m to the direction of groundwater flow in 365 days simulation period. However at the hydraulic gradient of 0.01, the contour center of the temperature are moved to the end of east boundary at each slice and the largest movement is at bottom slice. By the analysis of thermal interference data between two wells the efficiency of the heat pump system model is validated, and the variation of heads is monitored at injection, pumping and no operation mode.

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Development of Adsorption Desalination System Utilizing Silica-gel (실리카겔을 이용한 흡착식 담수화 시스템 개발)

  • Hyun, Jun-Ho;Israr, Farrukh;Lee, Yoon-Joon;Chun, Won-Gee
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.364-369
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    • 2012
  • The development of solar thermal energy used adsorption desalination technology have been examined as a viable option for supplying clean energy. In this study, the modelling of the main devices for solar thermal energy used and adsorption desalination system was introduced. Silica gel type adsorption desalination system is considered to be a promising low-temperature heat utilization system. The design is divided into three parts. First, the evaporator for the vaporization of the tap water is designed, and then the reactor for the adsorption and release of the steam is designed, followed by the condenser for the condensation of the fresh water is designed. In addition, new features based on the energy balance are also included to design absorption desalination system. In this basic research, One-bed(reactor) adsorption desalination plant that employ a low-temperature solar thermal energy was proposed and experimentally studied. The specific water yield is measured experimentally with respect to the time controlling parameters such as heat source temperatures, coolant temperatures, system switching and half-cycle operational times. Desalination is processes that permeate our daily lives, but It requires substantial energy input, powered either from electricity or from thermal input. From the environmental and sustainability perspecives, innovative thermodynamic cycles are needed to produce the above-mentioned useful effects at a lower specific energy input. This article describes the development of adsorption cycles for the production of desalting effects. We want that this adsorption system can be driven by low temperature heat sources at 60 to $80^{\circ}C$, such as renewable, solar thermal energy.

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