• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.169-174
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• 2004

The NOx emission characteristics with oxygen enrichment in nonpremixed counterflow and coflow jet flame of $CH_4$ fuel have been investigated numerically. A small amount of nitrogen is included in oxygen-enriched combustion, in order to consider the inevitable $N_2$ contamination by air infiltration. The results show that the initial increase of NO with increasing oxygen enrichment is due to increasing temperature and residence time, while its subsequent decrease above 75% oxygen is due to decreasing the consumption rate of nitrogen. When oxygen addition exceeds 30%, Thermal NO gradually becomes the dominant production pathway and Prompt NO becomes negative pathway for net NO production rate. It is also seen that Thermal NO plays an important role in NO reduction when strain rate increase in oxygen-enriched combustion. Finally, the results of EINOx with oxygen enrichment in coflow jet flame show the similar profile with those of conterflow flame. It is confirmed that, with leakage of 1% nitrogen in the oxidizer stream, the corresponding EINOx is eight times of that emitted from regular $CH_4$/Air flame.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.737-744
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• 2011

The success of continuous aluminum powder combustion with steam plasma is different from hydrocarbon ignition source. Ignition characteristics of aluminum powder with high temperature thermal plasma is studied with oxidizer-free environment. Experiment with argon plasma has same temperature conditions at 4500 K and particle feeding condition for previous combustion test with steam plasma and swirl combustor. The temperature of the plasma was measured using Optical Emission Spectroscopy method. Ignition characteristics were analyzed by SEM image and EDS. Aluminum powder with plasma has rapid evaporation mechanism contrast to hydrocarbon ignition source. It enhances to aluminum powder effective ignition characteristics.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.804-809
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• 2008

In this study, the cooling performance of a C/C composite material structure with metallic cooling tubes fixed by elastic force without chemical bonding was evaluated experimentally using combustion gas in a rocket combustor. The C/C composite chamber was covered by a stainless steel outer shell to maintain its airtightness. Gaseous hydrogen as a fuel and gaseous oxygen as an oxidizer were used for the heating test. The surface of these C/C composites was maintained below 1500 K when the combustion gas temperature was about 2900 K and heat flux to the combustion chamber wall was about 9 $MW/m^2$. No thermal damage was observed on the stainless steel tubes which were in contact with the C/C composite materials. Results of the heating test showed that such a metallic-tube-cooled C/C composite structure is able to control the surface temperature as a cooling structure(also as a heat exchanger), as well as indicating the possibility of reducing the amount of the coolant even if the thermal load to the engine is high. Thus, application of the metallic-tube-cooled C/C composite structure to reusable engines such as a rocket-ramjet combined cycle engine is expected.

• Journal of Advanced Navigation Technology
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• v.22 no.2
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• pp.90-95
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• 2018

In the solid rocket motor (SRM), a thrust of rocket is generated by a nozzle so it is very important device. The nozzle of SRM is a condition of high temperature and high pressure so occurs the erosion by combustion gas. The liquid rocket propulsion systems (LRPSs) cools the nozzle by the fuel and oxidizer but SRM does not cool the nozzle. This paper deal with the development of the oxy-acetylene torch tester and investigate the thermochemical erosion properties for the thermal insulation materials of the graphite rocket nozzle throat through the experiment. The results of experiments are compared with the results of Theoretical model and identify the key factors affecting of erosion. The results is in good agreement with the experimental data.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.5
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• pp.742-749
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• 2002

Numerical Study with detailed chemistry has been conducted to investigate the flame structure and NOx formation characteristics in oxygen -enhanced(CH$_4$/O$_2$-$N_2$) and oxygen-enhanced-EGR(CH$_4$/O$_2$-$CO_2$) counter diffusion flame with various strain rates. A small amount of $N_2$is included in oxygen-enhanced-EGR combustion, in order to consider the inevitable $N_2$contamination by $O_2$production process or air infiltration. The results are as follows : In CH$_4$/O$_2$-$CO_2$flame it is very important to adopt a radiation effect precisely because the effect of radiation changes flame structure significantly. In CH$_4$/O$_2$-$N_2$flame special strategy to minimize NO emission is needed because it is very sensitive to a small amount of $N_2$. Special attention is needed on CO emission by flame quenching, because of increased CO concentration. Spatial NO production rate of oxygen-enhanced combustion is different from that of air and oxygen-enhanced-EGR combustion in that thermal mechanism plays a role of destruction as well as production. In case CH$_4$/O$_2$-$CO_2$flame contains more than 40% $CO_2$it is possible to maintain the same EINO as that of CH$_4$/Air flame with accomplishing higher temperature than that of CH$_4$/Air flame. EINO decreases with increasing strain rate, and those effects are augmented in CH$_4$/O$_2$flame.

• Proceedings of the KSME Conference
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• 2001.11b
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• pp.185-190
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• 2001

Numerical Study with detailed chemistry has been conducted to investigate the flame structure and NOx formation characteristics in oxygen-enhanced$(CH_4/O_2-N_2)$ and oxygen-enhanced-EGR$(CH_4/O_2-CO_2)$ counter diffusion flame with various strain rates. A small amount of $N_2$ is included in oxygen-enhanced-EGR combustion, in order to consider the inevitable $N_2$ contamination by $O_2$ production process or air infiltration. The results are as follows : In $CH_4/O_2-CO_2$ flame it is very important to adopt a radiation effect precisely because the effect of radiation changes flame structure significantly. In $CH_4/O_2-N_2$ flame special strategy to minimize NO emission is needed because it is very sensitive to a small amount of $N_2$. Special attention is needed on CO emission by flame quenching, because of increased CO concentration. Spatial NO production rate of oxygen-enhanced combustion is different from that of air and oxygen-enhanced-EGR combustion in that thermal mechanism plays a role of destruction as well as production. In case $CH_4/O_2-CO_2$ flame contains more than 40% $CO_2$ it is possible to maintain the same EINO as that of $CH_4/Air$ flame with accomplishing higher temperature than that of $CH_4/Air$ flame. EINO decreases with increasing strain rate, and those effects are augmented in $CH_4/O_2$ flame. Complementary study is needed with extending the range of strain rate variation.

• Fire Science and Engineering
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• v.13 no.3
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• pp.3-17
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• 1999

Smoldering is a non-flaming combustion mode, characterized by thermal degradation and c charring of the virgin material, evolution of smoke and emission of visible glow. A big fire may @ occur even in a confined environment having a limited amount of oxygen, due to smoldering c combustion through a porous solid material. This paper presents a theoretical analysis on the effect of smoldering combustion on fire occurrence based on a report about fire investigation of a real f fire accident. It is assumed that the propagation of the smolder wave is one-dimensional, d downward, opposing an upward forced flow and steady in a frame of reference moving with the s smolder wave. Smoldering combustion is modeled by a one-step reaction mechanism, without c considering pyrolysis. It is found that dominant parameters controlling smoldering combustion i include mass flux of oxidizer entering the reaction zone and void fraction of solid fuel. It is also found that the mechanism of transition to flaming is critically influenced by these two parameters.

• Journal of the Korean Applied Science and Technology
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• v.31 no.3
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• pp.345-351
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• 2014

Dinitramide ($N(NO_2)_2$) salts are one of plausible oxidizing agents for a high efficient propellant. Guanidine dinitramide (GDN) is an organic salt improving its stability against moisture, so that enables massive production and long term storage. Several types of GDN (GDN-1,2,3,4,5) were synthesized using some types of starting materials such as guanidine acetate, chloride, carbonate, nitrate and sulfate. As a result of the experimental work, synthesized GDN from the carbonate salt appeared fairly pure relatively higher yield (99%) than the other samples. The absorption wave length of all prepared GDNs by FTIR were found at 3452, 3402, 3354, 3278, 3208, 1642, 1570, 1492, 1416, 1337, 1179 and $1000cm^{-1}$. DSC analysis found a thermal phase change at $130^{\circ}C$, and indicated exothermic reaction at about $150^{\circ}C$ to $160^{\circ}C$.

• Journal of the Korean Society of Propulsion Engineers
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• v.8 no.1
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• pp.1-7
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• 2004

The precipitation of ultra fine ammonium perchlorate(UFAP) crystals from the N-methyl pyrrolidone(NMP) solutions of ammonium perchlorate(AP) was studied. The characteristics of the precipitated crystals were investigated by means of scanning electron micrograph(SEM), X-ray diffraction(XRD), and thermogravimetric analysis(TGA). When chloroform, methylene chloride and toluene were the precipitants, the product crystals had a mean particle size less than 2$\mu\textrm{m}$. The crystallographical property and thermal decomposition behavior of the prepared UFAP were almost the same as those of the commercial AP.

• 한국연소학회:학술대회논문집
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• 2002.11a
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• pp.41-47
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• 2002

Oxygen has been used extensively in various industries for many years. Despite earlier successful attempts to use oxygen in industrial combustion furnaces, its full theoretical researches have only recently begun to be realized. The aim of this study is to investigate the effect of oxygen enriched combustion. This paper analyzes the characteristics of oxygen enriched combustion, and deals with the experimental investigation of the flame temperature and NOx concentration in exhaust gas. The flame temperature, concentration of exhaust gas were measured and flame configurations were photographed according to the variation of oxygen concentrations in oxidizer.