• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.609-617
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• 2017

Lignocellulosic biomass is a renewable resource for production of biofuels and biochemicals. Furfural (FF) is an important platform chemical catalytically derived from the hemicellulose fraction of biomass. Tetrahydrofurfuryl alcohol (THFA) is a FF derivative and can be used as an eco-friendly solvent with thermal and chemical stability. Despite large numbers of experimental studies for catalytic conversion of FF to THFA, few research have conducted on the economic feasibility for large-scale THFA production from FF. At the stage of assessment of the potential for commercialization of conversion technology, a large-scale process study is required to identify technological bottleneck and to obtain information for solving scale-up problems. In this study, process simulation and technoeconomic evaluation for catalytic conversion of FF to THFA are performed, as the following three steps: integrated process design, heat integration, and economic evaluation. First, a large-scale process including conversion and separation processes is designed based on experimental results. When the FF processing rate is 255 tonnes per day, the FF-to-THFA yields are 63.2~67.9 mol%. After heat integration, the heating requirements are reduced by 14.4~16.4%. Finally, we analyze the cost drivers and calculate minimum selling price of THFA by economic evaluation. The minimum selling price of THFA for the developed process are $2,120~2,340 per tonne, which are close to the current THFA market price.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.77-77
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• 2016

Thin films synthesized by plasma processes have been widely applied in a variety of industrial sectors. The structure control of thin film is one of prime factor in most of these applications. It is well known that the structure of this film is closely associated with plasma parameters and species of plasma which are electrons, ions, radical and neutrals in plasma processes. However the precise control of structure by plasma process is still limited due to inherent complexity, reproducibility and control problems in practical implementation of plasma processing. Therefore the study on the fundamental physical properties that govern the plasmas becomes more crucial for molecular scale control of film structure and corresponding properties for new generation nano scale film materials development and application. The thin films are formed through nucleation and growth stages during thin film depostion. Such stages involve adsorption, surface diffusion, chemical binding and other atomic processes at surfaces. This requires identification, determination and quantification of the surface activity of the species in the plasma. Specifically, the ions and neutrals have kinetic energies ranging from ~ thermal up to tens of eV, which are generated by electron impact of the polyatomic precursor, gas phase reaction, and interactions with the substrate and reactor walls. The present work highlights these aspects for the controlled and low-temperature plasma enhanced chemical vapour disposition (PECVD) of Si-based films like crystalline Si (c-Si), Si-quantum dot, and sputtered crystalline C by the design and control of radicals, plasmas and the deposition energy. Additionally, there is growing demand on the low-temperature deposition process with low hydrogen content by PECVD. The deposition temperature can be reduced significantly by utilizing alternative plasma concepts to lower the reaction activation energy. Evolution in this area continues and has recently produced solutions by increasing the plasma excitation frequency from radio frequency to ultra high frequency (UHF) and in the range of microwave. In this sense, the necessity of dedicated experimental studies, diagnostics and computer modelling of process plasmas to quantify the effect of the unique chemistry and structure of the growing film by radical and plasma control is realized. Different low-temperature PECVD processes using RF, UHF, and RF/UHF hybrid plasmas along with magnetron sputtering plasmas are investigated using numerous diagnostics and film analysis tools. The broad outlook of this work also outlines some of the 'Grand Scientific Challenges' to which significant contributions from plasma nanoscience-related research can be foreseen.

• Journal of Hydrogen and New Energy
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• v.25 no.6
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• pp.648-655
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• 2014

This paper describes the continuing effort to develope a single acting free-piston Stirling engine/alternator combination for use of the household cogeneration. Free piston Stirling engines(FPSE) use variations of working gas pressure to drive mechanically unconstrained reciprocating elements. Stirling cycle free-piston engines are driven by the Stirling thermodynamic cycle which is characterized by an externally heated device containing working gas that is continuously re-used in a regenerative, reversible cycle. The ideal cycle is described by two isothermal process connected by two constant volume processes. Heat removed during the constant volume cooling process is internally transferred to the constant volume heating process by mutual use of a thermal storage medium called the regenerator. Since the ideal cycle is reversible, the ideal efficiency is that of Carnot. Free-piston Stirling engine is have no crank and rotating parts to generate lateral forces and require lubrication. The FPSE is typically comprised of two oscillating pistons contained in a common cylinder. The temperature difference across the displacer maintains the oscillations, and the FPSE operate at natural frequency of the mass-spring system. The power is generated from a linear alternator. The purpose of this paper is to describe the design process of the single acting free-piston Stirling engine/alternator. Electrical output of the single acting free-piston Stirling engine/alternator is about 0.95 kW.

• Magazine of the Korea Concrete Institute
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• v.6 no.2
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• pp.97-107
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• 1994

The objective of this study is to develop polymer-impregnated concrete(PIC), which is a newly developed composite material made by impregnating polymer impregnanls into hardened normal concrete, and to develop analytical techniques for its proper applications. Crystalline methyl methacrylate(MMA) is chosen as a monomer of polymer impregnants. The corrlpositions of polymer impregnants and producing processes are developed by analyzing the effects of penetration, polymerization, thermal safety, and strengthening characteristics. On t he basis of experimental results of this study, various strength characteristics and stress strain constitutive relations are formulated in terms of the compressive strength of normal concrete and the polymer loadings, which can be applied for analysis and design of PIC members. In order to provide a model for fracture analysis of flexural members, fracture toughness, fracture energy, critical crack width, and tension softening relations near crack tip are also formulated in terms of member depth, initial notch depth, and the flexural strength of normal concrete. The structural analysis procedure and the finite element computer program developed in the study are applicable to evaluate elastic behavior, ultimate strength, and tension softening behavior of MMA type PIC structural members subject to various loading conditions. The accuracy and effectiveness of the developed computer program is examined by comparing the anal ytical results with the experimental results. Therefore, it is concluded that the developed structural analysis procedure and the finite element computer program are applicable to analysis and design of in-situ and precast PIC structural members.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.42 no.7
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• pp.586-593
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• 2014

The CNUSAIL-1 project aims to develop and operate a 3U-sized cube satellite with solar sail mechanism. The primary mission is to successfully deploy the solar sail in a low earth orbit, and the secondary mission is to collect the scientific data for the effect of the solar sail deployment and operation on orbit maneuver and attitude change of the cube satellite. For this, the bus system will collect and transmit the dynamic data of the satellite and the visual images of the solar sail operation. This paper describes solar sail mission and conceptual design of CNUSAIL-1. The actuation/operation of the solar sail and the bus system are preliminarily designed in terms of attitude control system, communication system, electrical power system, command and data handling system, structure and thermal control system is designed.

• Journal of Bio-Environment Control
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• v.24 no.3
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• pp.147-152
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• 2015

In order to develop the cooling load estimation method in the greenhouse, the cooling load calculation formula based on the heat balance method was constructed and verified by the actual cooling load measured in the fog cooling greenhouse. To examine the ventilation heat transfer in the cooling load calculation formula, we measured ventilation rates in the experimental greenhouse which a cooling system was not operated. The ventilation heat transfer by a heat balance method showed a relatively good agreement. Evaporation efficiencies of the two-fluid fogging system were a range of 0.3 to 0.94, average 0.67, and it showed that they increased as the ventilation rate increased. We measured thermal environments in a fog cooling greenhouse, and calculated cooling load by heat balance equation. Also we calculated evaporative cooling energy by measuring the sprayed amount in the fogging system. And by comparing those two results, we could verify that the calculated and the measured cooling load showed a relatively similar trend. When the cooling load was low, the measured value was slightly larger than calculated, when the cooling load was high, it has been found to be smaller than calculated. In designing the greenhouse cooling system, the capacity of cooling equipment is determined by the maximum cooling load. We have to consider the safety factor when installed capacity is estimated, so a cooling load calculation method presented in this study could be applied to the greenhouse environmental design.

• Resources Recycling
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• v.24 no.5
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• pp.15-21
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• 2015

Waste plastic differs in its speed of combustion owing to its variety in composition as well as kinds of plastic. This study is aimed at examining the thermal weight analysis and determination of its kinetics in order to derive the design element in pyrolysis of RPF (Refused Plastic Fuel) as the plastic solid fuel. Based on the result of TGA (Thermogravimetric analysis), kinetic characteristics were analyzed by using Kissinger method which are the most common method for obtaining activation energy, and experimental conditions of TGA were set as follows: in a nitrogen atmosphere, gas flow rate of 20 ml/min, heating rate of $5{\sim}50^{\circ}C/min$, and maximum hottest temperature of $800^{\circ}C$. The method used for determining the property of waste plastic when thermally decomposed was thought feasible as the basic data in deciding the performance, design, and optimal operating condition of the reactor in the actual reactor.

• Nuclear Engineering and Technology
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• v.52 no.7
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• pp.1386-1395
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• 2020

High fidelity nuclear reactor fuel assembly simulation using CFD method is an effective way for the structure design and optimization. The validated models and user practice guidelines play critical roles in achieving reliable results in CFD simulations. In this paper, the international benchmark MATiS-H is studied carefully and the best user practice guideline is achieved for the rod bundles simulation. Then a 5 × 5 rod bundles model in the advanced pressurized water reactor (PWR) is established and the detailed three-dimensional thermal-hydraulic characteristics are investigated. The influence of spacer grids and mixing vanes on the flow and hear transfer in rod bundles is revealed. As the coolant flows through the spacer grids and mixing vanes in the rod bundles, the drastic lateral flow would be induced and the pressure drop increases significantly. In addition, the heat transfer is enhanced remarkably due to the strong mixing effects. The calculation results could provide meaningful guidelines for the design of advanced PWR fuel assembly.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.891-894
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• 2008

This study was performed to investigate how to design, where to construct, why to degrade, what plan to use systematically the underground structures such as underpass, underground passageways. About 50% of the underground structures are located on Seoul, Kyungi-Do. In design of the underground structures such as underpass, underground passageways, the required conditions are defined. And also in construction stage, the conditions of soil, required structure depth, site characteristics, reasonable construction method, are investigated. In the selection of details for underground structure, the items mainly considered, are the wall and column type, the sidewalk type, anchoring-system type, the water-proofing method, entranc shape. The reason and the adequate measures for the degradation of concrete structure are also investigated. The initial cracking properties due to the thermal characteristic are considered. The state of the art report on the new technologies are reviewed. The recent project for the systematically application to the underground structures is reviewed.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.8
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• pp.1119-1127
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• 2010

In this paper, the design and nonlinear simulation of a multistable electromagnetic microactuator, which provides four stable equilibrium positions within its operating range, have been discussed. Quadstable actuator motion has been made possible by using both X- and Y-directional bistable structures with snapping curved beams. Two pairs of the curved beams are attached to an inner frame in both X- and Y-directions to realize independent bistable behavior in each direction. For the actuation of the actuator at the micrometer scale, an electromagnetic actuation method in which Lorentz force is taken into consideration was used. By using this method, micrometer-stroke quadstability in a plane parallel to a substrate was possible. The feasibility of designing an actuator that can realize quadstable motion by using the electromagnetic actuation method has been thoroughly clarified by performing nonlinear static and dynamic analyses and electrothermal coupled-field analysis of the multistable microactuator.