• 한국세라믹학회지
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• 제43권1호
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• pp.1-3
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• 2006

Well-shaped NaA zeolite cubic crystals of a large size of $5-7{\mu}m$ were synthesized by a hydrothermal method in a mother solution having a $3.55Na_2O:Al_2O_3:1.6SiO_2:593\~2000H_2O$ composition. Thermal treatment of NaA zeolite crystals resulted in the formation of a crystalline phase of $NaAlSiO_4-Camegeite$ between 800 and $900^{\circ}C$. Even at $1000^{\circ}C,\;NaAlSiO_4$ phase was found as a major product. Environmental Scanning Electron Microscopy (ESEM), High Resolution Transmission Electron Microscopy (HRTEM), X-Ray powder Diffraction (XRD), Fourier Transform Infrared (FT-IR) spectroscopy, and DTA/TGA and BET analyses were used to characterize the initial materials and the obtained products after various heat treatments.

• Journal of Photoscience
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• 제8권1호
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• pp.9-12
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• 2001

The photoisomerization behavior of benzylideneacetophenones, known as chalcones, was studied. We synthesized the chalcone derivatives that have ether groups at 4 and 4＇ positions. Due to the electron donating ability of the ether oxygen, the bond order of the single bond between two phenyl ring of the chalcone strengthened, which eventually increased the rotational barrier of the single bond. The rotational barrier of the single bond is about 20-22 kcal/mole. Thermal recovery of this process took about 1 min. The UV-visible spectra of these chromophores exhibit two characteristic absorption peaks at 276 nm and 340 nm. The relative intensity of the peaks varies depending on the alkyl chain length of the substituent. Photo-irradiation with the 365 nm light monotonously decreases the 340 nm peak. However, the photo-irradiation with 254 nm light induce two competing processes and produced rather complicated absorption profile.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집A
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• pp.730-735
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• 2000

The finite element analysis by the computer program SYSWELD in consideration of phase transformation was carried out to simulate the multi-pass welding process of SA106 Gr. C which is used for the main steam pipe in nuclear power plant. All the numerical results such as temperatures, the size of heat affected zone and the residual stresses were compared to the experimental results.

• 한국표면공학회지
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• 제30권1호
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• pp.63-68
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• 1997

The effects of the post-deposition annealing on the structural optical properties of sputtered $TiO_2$ thin films were studied; annealing was carried out in air up to $1000^{\circ}C$ for different duration. The results of the X-ray diffraction and the raman spectroscopy showed the annealing-condition dependent structural transformation of $TiO_2$ films from the as-deposited amorphous phase to the anatase and rutil phases. The spectroscopic elliposometry was used to investigate the deposition-condition dependence of the as-deposted films optical constants and also the evolution of the optical constants correlated with the annealing-induced structural transformation.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2009년도 춘계학술대회 논문집
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• pp.337-340
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• 2009

In hot press forming process, the desired high strength can be obtained through quenching process after cold forming of product. The quenching process, however, accompanies undesired distortion due to the volume change during the phase transformation as well as by thermal contraction. In this study the numerical simulation with DEFORM3D-Microstructure is used to predict the deformed shape during the quenching for the quenching fixture design.

• Journal of Magnetics
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• 제21권3호
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• pp.468-475
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• 2016

In this article, entropy generation on MHD Williamson nanofluid over a porous shrinking sheet has been analyzed. Nonlinear thermal radiation and chemical reaction effects are also taken into account with the help of energy and concentration equation. The fluid is electrically conducting by an external applied magnetic field while the induced magnetic field is assumed to be negligible due to small magnetic Reynolds number. The governing equations are first converted into the dimensionless expression with the help of similarity transformation variables. The solution of the highly nonlinear coupled ordinary differential equation has been obtained with the combination of Successive linearization method (SLM) and Chebyshev spectral collocation method. Influence of all the emerging parameters on entropy profile, temperature profile and concentration profile are plotted and discussed. Nusselt number and Sherwood number are also computed and analyzed. It is observed that entropy profile increases for all the physical parameters. Moreover, it is found that when the fluid depicts non-Newtonian (Williamson fluid) behavior then it causes reduction in the velocity of fluid, however, non-Newtonian behavior enhances the temperature and nanoparticle concentration profile.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2004년도 추계학술대회 논문집
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• pp.29-33
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• 2004

This paper presents ESPI system for the measurement of thermal expansion coefficient of STS430 up to 1,000$^{\circ}C$. Existing methods, strain gauge and moire have the limitation of contact to object and do not supply the coefficient up to 800$^{\circ}C$. There needs to measure the data up to 800$^{\circ}C$, because heat resistant materials have high melting temperature up to 1,000$^{\circ}C$. In previous studies related to thermal strain analysis, the quantitative results are not reported by ESPI at high temperature, yet. In-plane ESPI and vacuum chamber for the reduction of air turbulence and oxidation are designed for the measurement of the coefficient up to 1,000$^{\circ}C$and speckle correlation fringe pattern images are processed by commercial image filtering tool-smoothing, thinning and enhancement- to obtain quantitative results, which is compared with references data. The comparison shows two data are agreed within 4.1％ blow 600$^{\circ}C$ however, there is some difference up to 600$^{\circ}C$. Also, the incremental ratio of the coefficient is changed up to 800$^{\circ}C$. The reason is the phase transformation of STS430 probably begins at 800$^{\circ}C$.

• 한국세라믹학회지
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• 제35권1호
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• pp.88-96
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• 1998

The structural and electrical properties of titanium dioxide(TiO2) thin films deposited on p-type (100) si and 4$^{\circ}$off(100) Si substartes by metalorganic chemical vapor deposition (MOCVD) have been studied with post rapid thermal annealing. TiO2 thin films of anatase phase were grown at 300-500$^{\circ}C$ using titanium post rapid thermal annealing at a temperature of 800$^{\circ}C$ for 30sec. rutile phase was observed in the condition of the deposition temperature over 350$^{\circ}C$ in the ambient air atmosphere and at 500$^{\circ}C$ in cacuu,. SEM and AFM study show-ed surface roughness were increased slightly from 40${\AA}$to 55${\AA}$ after annealing due to grain growth and phase transformation. From capacitane-voltage measurement of Al/TiO2./p-Si structure after annealing we obtained ideal capacitance-voltage characteristics of MOS structure with dielectric constant of 16-22 in case of (100) Si and about 30- in case of 4$^{\circ}$off(100) Si but showed the higher leakage current.

• 한국표면공학회지
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• 제48권1호
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• pp.23-26
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• 2015

What causes the transformation of a solar cell is the behavior difference of thermal expansion occurred between the substrate and the layer of semiconductor used in the solar cell. Therefore, the substrate has to possess a behavior of thermal expansion that is similar with that of semiconductor layer. This study employed electroforming to manufacture Fe-Ni alloy materials of different compositions. To verify the result from a finite element analysis, a two-dimensional Mo substrate was calculated and its verification experiment was conducted. The absolute values from the finite element analysis of Mo/substrate structure and its verification experiment showed a difference. However, the size of residual stress of individual substrate compositions had a similar tendency. Two-dimensional CIGS/Mo/$SiO_2$/substrate was modeled. Looking into the residual stress of CIGS layer occurred while the temperature declined from $550^{\circ}C$ to room temperature, the smallest residual stress was found with the use of Fe-52 wt%Ni substrate material.

• 한국재료학회지
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• 제15권7호
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• pp.435-438
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• 2005

Single phase $Zn_4Sb_3$ with $98.5\%$ of theoretical density was successfully produced by direct hot pressing of elemental powders containing $1.2 at\%$ excess Zn for compensating the evaporation during the process. Temperature dependences of thermoelectric properties were investigated from 4 K to 300 K. Seebeck coefficient, electrical conductivity, thermal conductivity as well as thermoelectric figure of merit showed the discontinuity in variation at 242K, indicating the $\alpha-\beta$, phase transformation. Interestingly, it was found that lattice thermal conductivity by phonons is dominant in total thermal conductivity of $\alpha-\beta$. Therefore, it is expected that thermoelectric properties can be improved by reduction of lattice thermal conductivity inducing lattice scattering centers by doping and solid solution.