• Bulletin of the Korean Chemical Society
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• 제29권8호
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• pp.1510-1518
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• 2008

Results of intrinsic and extrinsic fluorescence studies on choline oxidase revealed that the enzyme at high alkaline pH values has more accessible hydrophobic patches relative to acidic pH. Fluorescence quenching studies with acrylamide confirm these changes. The quenching constants were also determined at different pH(s) by using the Stern-Volmer equation. CD studies showed that at higher pH a transition from $\alpha$-helix to $\beta$- structure was appeared while at lower pH the content of $\alpha$-helix structure was increased. Furthermore, analysis of the spectral data using chemometric method gave evidence for existence of intermediate components at very high pH(s). Results of thermal denaturation evaluated that the enzyme has the most instability at higher pH(s). Altogether low and high pH values caused significant alteration on secondary and tertiary structures of choline oxidase via inducing of an intermediate.

• 대한전자공학회논문지
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• 제26권3호
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• pp.130-136
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• 1989

보론이 도우핑된 수소화된 비정질 실리콘을 이용한 박막 트랜지스터를 플라즈마 CVD 방법으로 제작하여 트랜지스터의 특성 및 준안정성에 관한 연구를 수행하였다. 보론이 도우핑된 비정질 실리콘 ambipolar 트랜지스터를 열평형 온도 이상에서 급냉하면, active dopants가 증가하고 경계면 상태밀도가 감소하여 정공채널에 의한 드레인 전류가 증가하고 전자채널의 드레인 전류는 급냉 온도에 따라 증가하다 감소되는 현상을 측정하였다. 이런 급냉 효과는 실리콘내에 있는 수소의 운동과 밀접한 관계가 있고 active dopants, 댕글링 본드 및 경계면 상태밀도의 변화로 해석된다.

• 한국정밀공학회지
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• 제21권2호
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• pp.122-129
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• 2004

There is an increasing need for large flat panel display devices. PDP (Plasma Display Panel) is one of the most promising candidates for this need. Thermal shock failure of PDP glass during manufacturing process is a critical issue in PDP industry since it is closely related to the product yield and the production speed. In this study, thermal shock resistance of PDP glass is measured by water quenching test and an analysis scheme is described for estimating transient temperature and stress distributions during thermal shock. Based on the experimental data and the analysis results, a simple procedure for predicting the thermal shock failure of PDP glass is proposed. The fast cooling process for heated glass plates can accelerate the speed of PDP production, but often leads to thermal shock failure of the glass plates. Therefore, a design guideline for preventing the failure is presented from a viewpoint of high speed PDP manufacturing process. This design guideline can be used for PDP process design and thermal -shock failure prevention.

• 한국세라믹학회지
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• 제35권10호
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• pp.1094-1100
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• 1998

The thermal fatigue behavior of alumina ceramics was investigated by water quenching method. Single-quench thermal shock tests were performed to decide the critical thermal shock temperature difference ($\Delta$Tc) which was found to be 225$^{\circ}C$ Cyclic thermal shock fatigue tests were performed at temperature diff-erences of 175$^{\circ}C$, 187$^{\circ}C$ and 200$^{\circ}C$ respectively. After cyclic thermal shock fatigue test the distributions of retained strength and crack were observed. Retained strength was measured by four point bending method and crack observation method bydye penetration. In terms of the retained strength distribution the critical number of thermal shock cycles(Nc) were 7 for $\Delta$T=200$^{\circ}C$, 35 for $\Delta$T=187$^{\circ}C$ and 180for $\Delta$T=175$^{\circ}C$ respec-tively. In terms of the crack observation the critical number of thermal shock cycles were 5 for $\Delta$T==200$^{\circ}C$ 20 for $\Delta$T==187$^{\circ}C$ and 150 for $\Delta$T=175$^{\circ}C$ respectively. The difference of Nc investigated by two different methods is due to the formation of the longitudinal cracks which had no effect on the four point bending strength. Therefore the thermal fatigue behavior of alumina ceramics could be more accurately described by the crack observation method than the retained strength measurement method.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2004년도 하계학술대회 논문집 C
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• pp.1667-1669
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• 2004

In this paper, the elastic epoxy added elastomer having viscoelasticity to existing epoxy was measured thermal, structural properties by DSC (Differential Scanning Calorimetry) and FESEM (Field Emission Scanning Electron Microscope). Specimens were made of dumbbell forms by the ratio of 5, 10, 15, and 20[phr] by regulation with elastomer contents. The measurement temperature dimensions of DSC were -20[$^{\circ}C$] to 150[$^{\circ}C$] and rising temperature was 4[$^{\circ}C$/min]. Also we observed structure through FESEM at the magnification of 1000 times with the voltage of 15[kV] after breaking by quenching specimens. As experimental results, we could know that thermal and structural properties were improved quantity according to decrease of elastomer contents. Namely, it increased glass transition temperature, high temperature, and matrix structure. In general, thermal, structural properties of 15[phr] was excellent among the specimens.

• 한국재료학회지
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• 제16권3호
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• pp.183-187
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• 2006

We present the effects of rapid thermal annealing (RTA) temperature on the structural and optical properties of self-assembled InAs quantum dot (QD) structures grown on GaAs substrates by molecular beam epitaxy (MBE). The photoluminescence (PL) measurements are performed in a closed-cycle refrigerator as a function of temperature for the unannealed and annealed samples. RTA at higher temperature results in the increase in island size, the corresponding decrease in the density of islands, and the redshift in the PL emission from the islands. The temperature dependence of the PL peak energy for the InAs QDs is well expressed by the Varshni equation. The thermal quenching activation energies for the samples unannealed and annealed at $600^{\circ}C$ are found to be $25{\pm}5meV$ and $47{\pm}5$ meV, respectively.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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• pp.562-563
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• 2005

In case of aged porcelain, the failure in basic performance tests happened in cool-heat tests. Based on this characteristic, we studied the method predicting failure phenomena through more severe accelerated cool-heat ageing and accelerating thermal mechanical performance tests. Test results indicated that the thermal stress by temperature gradient was more severe parameter than thermal stress by quenching cycles within a category of standard or accelerating methods. And there is no the deterioration of statistic strength, but the deterioration of strength according to accelerating tests is serious.

• 대한기계학회논문집B
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• 제40권12호
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• pp.815-824
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• 2016

가압경수로에 장전되는 핵연료집합체는 연료 봉 다발과 지지격자 및 상하단 고정체로 구성되어 있다. 고온 고압의 냉각수는 원자로 하부로 유입되어 연료 봉 사이로 형성된 부수로를 따라 노심 상부로 흐른다. 경수로핵연료의 주요 열수력 성능인자는 정상운전시 압력강하 및 임계열속이며 사고시에는 급랭 시간이다. 한국원자력연구원에서는 경수로핵연료의 성능을 향상시키고 국산화를 위해 고성능 경수로핵연료, 이중냉각 핵연료 및 사고저항성 핵연료를 개발하였다. 경수로핵연료의 열수력 핵심기술을 개발하기 위해 압력강하 실험, 난류 유동혼합/열전달 실험, 임계열속 및 급랭 시험을 수행하였으며 전산유체역학 방법도 활용하였다. 더불어 사용후핵연료의 임시저장을 위한 건식저장 용기의 열유동에 대한 전산유체해석을 수행하였다. 한편, 경수로핵연료의 열수력 기반기술을 개발하고 실용화를 위해 대학 및 산업체와 협력연구도 진행하였다.

• 한국세라믹학회지
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• 제29권9호
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• pp.681-688
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• 1992

Ultrafine Si3N4 and Si3N4+SiC mixed powders were synthesized through thermal plasma chemical vapor deposition(CVD) using a hybrid plasma, which was characterized by the supersposition of a radio-frequency plasma and arc jet. The reactant SiCl4 was injected into an arc jet and completely decomposed in a hybrid plasma, and the second reactant CH4 and/or NH3 mixed with H2 were injected into the tail flame through double stage ring slits. In the case of ultrafine Si3N4 powder synthesis, reaction efficiency increased significantly by double stage injection compared to single stage one, although crystallizing behaviors depended upon injection speed of reactive quenching gas (NH3+N2) and injection method. For the preparation of Si2N4+SiC mixed powders, N/C composition ratio could be controlled by regulating the injection speed of NH3 and/or CH4 reactant and H2 quenching gas mixtures as well as by adjusting the reaction space.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1996년도 추계학술대회 논문집
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• pp.964-968
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• 1996

The demands of size and quality of large steel shaft forgings for ship building, power plant, steel plant, etc. are rapidly increasing, and some of these productions are manufactured from ingot weighing more than 300 tons. For use as rotating components. shafts require toughness, strength and homogeneity, and therefore are produced through a variety of heat treatments. According to the increase of ingot size, micro- and macrosegregation and also mass effect of the product increase. Thus, special care should be paid to the heat treatment of such large shaft forgings. In this paper, the heat treatment of large shaft forgings such as rotor and back-up roll is calculated using the commercial finite element code SYSWELD. Calculated distributions of temperature and phase are compared with experimental data. The continuous cooling transformation diagram, thermal and mechanical properites of each phase are used. The phase proportion, hardness and residual stress during water quenching are discussed.