• Journal of Energy Engineering
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• v.11 no.1
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• pp.1-9
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• 2002

The purpose of this study is to maintain high efficiency and reasonable use of cool thermal storage systems operated in the domestic building sector. As the result of efficiency test from the five types of operated cool storage systems on the condition that COP ranges are 2.6 to 3.4 during the day time and 2.1 to 3.0 during the night time and it decreased by more than 30% of rated COP given 3.8 to 3.0. The Analysis of cool storage rate shows that only 3 (21.4%) systems out of 15 buildings hold to over 40% capacity for its total capacity. To prevent the decrease in operating efficiency, it should correct the malfunction of 3-way valve and expansion valve and the mistake of control values for schedule program and increase cooling tower capacity. In order to improve piping line, it needs bypass brine line off refrigerator, separation of chilled water line with Ice Slurry system at day and night time and speed control of chilled and warm water pumps. This study does require the more studies on improving difficulty of increasing cooling load with Ice on Coil system, waterproofing with Ice Ball system, COP drop during the night time with Ice Lens, low operating temperature during the day time with Ice Slurry and increasing of Power loss due to hot gas de-icing with Ice Harvest in the future.

• Economic and Environmental Geology
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• v.45 no.2
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• pp.79-88
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• 2012

The increased brightness and focused X-ray beams now available from laboratory X-ray sources facilitates a variety of powder diffraction experiments not practical using conventional in-house sources. Furthermore, the increased availability of 2-dimensional area detectors, along with implementation of improved software and customized sample environmental cells, makes possible new classes of in-situ and time-resolved diffraction experiments. These include phase transitions under variable pressure- and temperature conditions and ion-exchange reactions. Examples of in-situ and time-resolved studies which are presented here include: (1) time-resolved data to evaluate the kinetics and mechanism of ion exchange in mineral natrolite; (2) in-situ dehydration and thermal expansion behaviors of ion-exchanged natrolite; and (3) observations of the phases forming under controlled hydrostatic pressure conditions in ion-exchanged natrolite. Both the quantity and quality of the in-situ diffraction data are such to allow evaluation of the reaction pathway and Rietveld analysis on selected dataset. These laboratory-based in-situ studies will increase the predictability of the follow-up experiments at more specialized beamlines at the synchrotron.

• Journal of the Mineralogical Society of Korea
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• v.15 no.4
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• pp.315-327
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• 2002

Al-pillared clay was synthesized by constructing pillars of aluminum oxides at the interlayer of montmorillonite in bentonite. XRD, DTA and chemical analyses of Al-pillared clay were performed to examine mineralogical properties. Batch adsorption experiments were also conducted to determine the adsorption properties of this synthesized clay for phosphate ions. XRD analyses showed that the interlayer space of Al-pillared clay expanded to 18.03 $\AA$ at room temperature and shifted to $17 \AA$ after heating to $550^{\circ}C$. A small change in interlayer space after heating indicates high thermal stability. The interlayer expansion by glycerol was also very small. From DTA analyses, pillared clay showed the characteristic endothermic peaks at 270 and $420^{\circ}C$ , which might be caused by dehydration in framework of pillars between interlayers. Adsorption experiment revealed that Al-pillared clay had an excellent adsorption capacity to the phosphate ions, whereas montmorillonite had very low adsorption capacity to phosphate ions. In phosphate solution concentration up to 300 mg/L, 2 g of pillared clay could uptake almost 100% of phosphate ions from 20 mL of solution. After heat treatment of the phosphate adsorbed pillared clay at 50$0^{\circ}C$ to remove phosphate, the calcined pillared clay could adsorb phosphate ions with a little decreased adsorption efficiency. This fact indicates that Al-pillared clay can be recycled for the adsorption of phosphate ions.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.15 no.1
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• pp.26-34
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• 1982

The East China Sea and the Yellow Sea are abundant in nutritions because of river inflows and are important as the nursery and spawning grounds of demersal and pelagic fishes. The remarkable thermal front between the Yellow Sea Bottom Cold Water and the Tsushima Warm Current is formed in this region, and the fluctuation of this front may affect the variation of the yellow croaker fishing ground. To investigate the mechanism of the yellow croaker fishing ground, the distribution ana seasonal change of the fishing ground are examined by using catch of stow net fishery (Fisheries Research and Development Agency, 1970-1979) and the water temperature data (Japan Hydrographic Association, 1978). The main fishing ground of yellow croaker was nine sea areas (rectangle of 30' latitude by 30' longitude) located at 40-150 nautical miles west and southwest of Jeju Island, the area of which occupies no more than $11\%$ of all fishing grounds, and it appeared that about $70\%$ of total catch of ten years was concentrated in this area. The main fishing periods were from March to May and September to October. The coefficients of variation of the catch for the main fishing ground were from 0.8 to 2.1 and the condition of all fishing grounds was generally unstable. The mean CPUE was 27kg/haul at the main fishing ground, while it was the largest on boundary area of the Yellow Sea Bottom Cold Water. It was found that the seasonal movement of fishing ground is related to the expansion and reduction of the Yellow Sea Bottom Cold Water ($10^{\circ}C$).

• Transactions of the Korean Society of Mechanical Engineers A
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• v.38 no.3
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• pp.275-282
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• 2014

Particle-reinforced metal matrix composites exhibit a strengthening effect due to the particle size-dependent length scale that arises from the strain gradient, and thus from the geometrically necessary dislocations between the particles and matrix that result from their CTE(Coefficient of Thermal Expansion) and elastic-plastic mismatches. In this study, the influence of the size-dependent length scale on the particle-matrix interface failure and ductile failure in the matrix was examined using finite-element punch zone modeling whereby an augmented strength was assigned around the particle. The failure behavior was observed by a parametric study, while varying the interface failure properties such as the interface strength and debonding energy with different particle sizes and volume fractions. It is shown that the two failure modes (interface failure and ductile failure in the matrix) interact with each other and are closely related to the particle size-dependent length scale; in other words, the composite with the smaller particles, which is surrounded by a denser dislocation than that with the larger particles, retards the initiation and growth of the interface and matrix failures, and also leads to a smaller amount of decrease in the flow stress during failure.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.5
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• pp.431-439
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• 2013

A cooling system is adopted to control the thermal load from the avionic equipments in an aircraft for stable operation. In this study, an avionic cooling system was designed and manufactured by adopting a vapor compression cycle with a closed-loop air-circulation system to investigate the operating characteristics of an alternative refrigerant. The performance characteristics of a cooling system adopting R236fa as an alternative refrigerant were experimentally determined by varying the refrigerant charging amount, expansion valve opening, and compressor rotation speed. The experimental results were analyzed and compared with those of a cooling system adopting R124 as a refrigerant. The possibility of the adoption of R236fa as an alternative refrigerant was verified, and design solutions were suggested to improve the system efficiency.

• Journal of Energy Engineering
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• v.19 no.2
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• pp.73-80
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• 2010

A solid oxide fuel cells(SOFC) is a clean energy technology which directly converts chemical energy to electric energy. When the SOFC is used in cogeneration then the efficiency can reach higher than 80%. Also, it has flexibility in using various fuels like natural gases and bio gases, so it has an advantage over polymer electrolyte membrane fuel cells in terms of fuel selection. A typical cathode material of the SOFC in conjunction with yttria stabilized zirconia(YSZ) electrolyte is still Sr-doped $LaMnO_3$(LSM). Recently, application of mixed electronic and ionic conducting perovskites such as Sr-doped $LaCoO_3$(LSCo), $LaFeO_3$(LSF), and $LaFe_{0.8}Co_{0.2}O_3$(LSCF) has drawn much attention because these materials exhibit lower electrode impedance than LSM. However, chemical reaction occurs at the manufacturing temperature of the cathode when these materials directly contact with YSZ. In addition, thermal expansion coefficient(TEC) mismatch with YSZ is also a significant issue. It is important, therefore, to develop cathode materials with good chemical stability and matched TEC with the SOFC electrolyte, as well as with high electrochemical activity.

• Journal of the Korean Vacuum Society
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• v.11 no.1
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• pp.50-58
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• 2002

The growth of GaN films on Si substrate has many advantages in that Si is less expensive than sapphire substrate and that integration of GaN-based devices with Si substrate is easier The difference of lattice constant and thermal expansion coefficient between GaN and Si is larger than those between GaN and sapphire. However, which results in many defects into the grown GaN. In order to obtain high duality GaN films on Si substrate, we need to reduce defects using the buffer layer such as AlN. In this study, we prepared three types of AlN buffer layer with various crystallinity on Si (111) substrate using MOCVD, Sputtering and MOMBE methods. GaN was grown by MOCVD on three types of AlN/Si substrate. Using TEM and XRD, we carried out comparative investigation of growth and properties of GaN deposited on the various AlN buffers by characterizing lattice coherency, crystallinity, growth orientation and defects formed (voids, stacking faults, dislocations, etc). It is found that the crystallinity of AlN buffer layer has strong effects on growth of GaN. The AlN buffer layers grown by MOCVD and MOMBE showed the reduction of out-of-plane misorientation of GaN at the initial growth stage.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.1
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• pp.37-43
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• 2013

Conductivity of LSGMC materials were affected by secondary phase segregation, composition and synthetic route. $La_{0.8}Sr_{0.2}Ga_{0.8}Mg_{0.1}Co_{0.1}O_{3-{\delta}}$ (LSGMC) powders were prepared using the glycine nitrate process to produce high surface area and compositionally homogeneous powders. The powders were synthesized with different 0.5, 1, 1.5, 2, 2.5 of glycine/cation molar ratios. A single perovskite phase from the synthesized powders was characterized with X-ray diffraction patterns. The obtained sintered pellets showed the dense grain microstructure. In case of 1.5 molar ratio, its density was higher than the others. The electrical conductivity measured at $800^{\circ}C$ was observed to be 0.131 $Scm^{-1}$. In addition, the linear thermal expansion behavior was indicated between $25^{\circ}C$ and $800^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.41 no.4
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• pp.334-339
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• 2004

Microstructures and mechanical properties of SPSed monolithic HAp, HAp-Ag, and HAp-ZrO$_2$sintered bodies were investigated by the XRD, SEM, and TEM techniques. The nano-sized HAp powders were successfully synthesized by precipitation of Ca(NO$_3$)$_2$4$H_2O$ and (NH$_4$)HPO$_4$solution. In the HAp-Ag composite, the shrinkage cavities were observed at the interfaces between HAp and large sized Ag particles due to the mismatch of their thermal expansion coefficients. However, no found the defect at the interfaces between HAp and fine-sized Ag particles. In the HAp-ZrO$_2$composite. nano-sized ZrO$_2$particles were almost dispersed at the grain boundaries of HAp phase. The fracture toughness of HAp-Ag and HAp-ZrO$_2$ composites were increased due to the plastic deformation and phase transformation mechanisms of the dispersed fine Ag and ZrO$_2$phase in the HAp matrix, respectively.